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| 1 | EXPERIMENTAL INVESTIGATION AND THERMODYNAMIC CALCULATION ON PHASE PRECIPITATION OF INCONEL 740显示文摘A novel nickel-based superalloy INCONEL 740 was under development for application in ultra-supercritical superheater tubers above 750℃. The precipitation behaviors of η phase and γ’ particles of the alloy were investigated through experimental study and phase computation. Experimental results showed that η phase formed a Widmanst?tten pattern structure following long-term exposure at elevated temperatures and that the coarsening of γ’ particle follows a cube rate law:r-3 ∝ t. Thermodynamic calculation results showed that Al and Ti had an important effect on the precipitation behavior of γ’ andη phases. Two suggested novel modified alloys, wherein the Al and Ti contents were modified, were designed and melted for the experimental study. The preliminary results indicated that the modified alloys exhibited higher structural stability following long-term exposure at 750℃ till 5000h. | S.Q. Zhao* Department of Physics, Ningxia University, Yinchuan 750021, China Y. Jiang Department of Materials Science, The Northwest Second Nationalities Institute, Yinchuan 750021, China J.X. Dong and X.S. Xie High Temperature Materials Research Laboratories, University of Science and Technology Beijing, Beijing 100083, China | 2006 | Acta Metallurgica Sinica(English Letters)2006，19，6： | 11 |
| 2 | Thermodynamic calculation on the smelting slag of direct recycling of electric arc furnace stainless steelmaking dust显示文摘Thermodynamic calculation on the smelting slag of direct recycling of electric arc furnace stainless steelmaking dust was presented. An induction furnace was used to simulate electric arc furnace smelting to recover the metals from the dust. The elements of iron, chromium and nickel in the ingot and the components of metal oxides in the slag were analyzed. The thermodynamic model for FeO Cr 2O 3 MgO SiO 2 slag was set up and the active concentrations of substances in the slag at 1 550 ℃ were determined by thermodynamic calculation according to the experimental data. The results show that the apparent equilibrium constant and quantitative distribution of chromium between slag and steel are unstable and affected by the mass ratios of pellets to start iron and metal reducing agent to the pellets. In order to get satisfactory chromium recovery from the direct recycling of electric arc furnace stainless steelmaking dust, it is important to ensure the mass ratio of pellets to the steel below 0.20 and the mass ratio of metal reducing agent to pellets over 0.18 in practical smelting runs. | 彭兵 彭及 Janusz A.Kozinski Jonathan Lobel 柴立元 张传福 陈为亮 | 2003 | Journal of Central South University of Technology2003，10，1： | 6 |
| 3 | Reaction between Lanthanum and Phosphorus in Steel显示文摘Using Miedema binary heat formation model, it was confirmed thermodynamically that the fixation of P by La is possible. The reaction between La and P was studied by means of SEM and TEM. The result of electron diffraction shows that the compound between La and P is LaP. Therefore, the possibility of reducing detrimental effect of P in low oxygen and sulfur steels by addition of rare earth metals is clarified. | 沙爱学 王福明 吴承建 董履仁 李尚诣 陈亚贤 朱立新 | 2000 | Journal of Rare Earths2000，18，1： | 5 |
| 4 | STUDY ON THERMODYNAMIC MODEL OF A COMPRESSOR WITH ARTIFICIAL NEURAL NETWORKS显示文摘0INTRODUCTIONCompressorsarewidelyusedinindustrialfields,suchasairconditioning,refrigerationetc..Itisoftenneededtoassestheperf... | Ding Guoliang Li Hao Zhang Chunlu Department of Refrigeration and Cryogenics Engineering, Shanghai Jiaotong University | 1999 | Chinese Journal of Mechanical Engineering1999，12，1： | 5 |
| 5 | Thermodynamic Calculation on Calcium Treatment for 26CrMo4S/2 Steel显示文摘Because CaSi core wire was not fed in external refining process for 26CrMo4S/2 steel making, it was found that the molar ratio of calcium versus alumina was very low and subsequently resulted in generation of much more non-metallic inclusions. Hence, it was reasonable to sugguest feeding appropriate amount of Ca core wire. Before the performance, the thermodynamic calculation had been carried out to obtain the theoretical amount of Ca wire to be fed. According to the practical data from steel plant and the thermodynamic data, it was calculated that only when 5 2/34.97 10 [%Al]T-≥×4 2/31.38 10 [%Al] [%Ca]T T-×≥≥in molten steel the Al2O3 inclusions could be properly modified. | Guo-dong SUN Ya-fei SUI Can-guo WANG Min GUO Mei ZHANG | 2014 | Journal of Iron and Steel Research(International)2014，21，S1： | 2 |
| 6 | Precipitates in an isothermally aged Fe-18Cr-12Mn-0.04C-0.48N high-nitrogen austenitic stainless steel显示文摘Vertical section of Fe-18Cr-12Mn-0.04C-N system phase diagram varying with nitrogen content at 1×105 Pa was calculated using Thermo-Calc software and thermodynamic database.The morphology and crystallography information of precipitates in Fe-18Cr-12Mn-0.04C-0.48N high-nitrogen austenitic stainless steel during isothermal aging at 800 ℃ after austenization was investigated using optical microscopy(OM),and transmission electron microscopy(TEM) with energy distribution spectrum(EDS).The experimental results show that three precipitates,(Cr,Fe,Mn)2(N,C),(Cr,Fe,Mn)23(C,N)6 and σ phase exist in this steel,which is consistent with the thermodynamic calculation,indicating that thermodynamic calculation can provide instructions for alloy composition design,heat treatment and prediction of precipitation sequence in Fe-18Cr-12Mn-0.04C-N system. | SHI Feng,WANG Lijun,CUI Wenfang,REN Yuping,LI Hongxiao,and LIU Chunming School of Materials & Metallurgy,Northeastern University,Shenyang 110004,China | 2007 | Rare Metals2007，26，S1： | 1 |
| 7 | 垃圾焚烧过程中吸附剂对Cu迁移转化的影响(英文)显示文摘Oxides of silicon, aluminium and calcium are normally dominant minerals during municipal solid waste(MSW)combustion. In flue gas, Si O2, Al2O3 and Ca O all act as sorbents capturing heavy metals(and semi-volatile organics). To further understand the effect of sorbents during MSW combustion, the effects of Si O2, Al2O3 and Ca O on Cu partitioning were experimentally investigated by the combustion of synthetic MSW in a tubular furnace and their effects on Cu speciation were studied by thermodynamic equilibrium calculations using Chem Kin software. The experiments show that Ca O has the highest Cu sorption efficiency at 900 °C, followed by Al2O3 and Si O2. Thermodynamic equilibrium calculations show that for Cu the addition of Si O2 and Al2O3reduces the amount of liquid Cu Cl, which is more volatile. However, the addition of Ca O has little influence on chemical sorption of Cu, indicating that the sorption of Ca O is resulted from physical sorption. | 周会 孙进 蒙爱红 李清海 张衍国 | 2014 | Chinese Journal of Chemical Engineering2014，22，Z1： | 1 |
| 8 | VARIATIONAL CALCULATION OF THERMODYNAMIC PROPERTIES OF SUPERCOOLED LIQUID METALS显示文摘By means of Gibbs-Bogoliubov (GB) thermodynamic variational calculation,thethermodynamic properties of the supercooled liquid metals,such as the 3rd family elementsAl,Ga and Tl and transition metal Ti were calculated using the hard-sphere (HS) system asreference.The values of mean atomic volume,Helmholtz free energy,internal energy andentropy as well as specific heat at constant volume,isothermal bulk modulus,thermal expan-sion coefficient and specfic heat under constant pressure were evaluated.The glass transitiontemperature,T_g,is easily obtained from the C_p-T plot.The glass forming ability for metalcan be predicted from T_g/T_m,which is in agreement with the experimental results. | SHEN Tao WANG Jingtang Institute of Metal Research,Academia Sinica National Laboratory of Rapidly Solidified Non-equilibrium Alloys,Shenyang,China | 1990 | Acta Metallurgica Sinica(English Letters)1990，3，12： | 0 |
| 9 | Re-assessment and Optimization of the Ga-M (M=In, Sb,Pb) Systems with Chemsage显示文摘The thermodynamic properties and the phase diagrams of the systems Ga-M (M = In, Sb, Ph) were critically re-assessed and optimized employing the software package ChemSage for the calculation of thermodynamicequilibria. The Redlich-Kister/Margules formalism was employed for all solution phases and sets of self-consistentthermodynamic parameters were obtained. The results of re-assessment and optimization are compared with previous work, they are in excellent agreement with most experimental data. | Xianran Xing Thiyu Qiao Herbert IPser( Institute of Inorganic Chemistry, University of vienna,A-1090wien,Austria)( Applied Science School, University of Science and Technology Beijing, Beijing 100083, China) | 1998 | International Journal of Minerals,Metallurgy and Materials1998，12，4： | 0 |
| 10 | Thermodynamic Assessment of Reactions between Yttrium and Tramp Elements in Petroleum Pipe Steel显示文摘In the thermodynamic evaluation Y was selected as a typical heavy rare earth metal for reducing the detrmental effects of tramp elements in the petroleum pipe steel. The possibilities of reactions between Y and trampelements such as Sn, Sb, As, etc. after deoxidation and desulphurization were estimated by calculating the Gibbsfree energies of formation. The equilibrium content of Y for eliminating the detrimental effects of tramp elements inthe steel was recommended from the results of thermodynamic calculation. | Aixue Sha Luren Dong Shangyi Li( Metallurgy School, University of Science and Technology Beijing, Beijing 1 00083, China)(Science and Technology Department, Metallurgical Industry Bureau of China, Beijing 100711, China) | 1998 | International Journal of Minerals,Metallurgy and Materials1998，12，4： | 0 |
| 11 | Development of materials design tool and its application in Pb-free micro-solders in electronic package显示文摘A materials design tool for developing Pb-free soldering alloys in electronic package was developed based on comprehensive experimental data of phase equilibria and thermodynamic properties data accumulated with the CALPHAD (calculation of phase diagrams) method and contains 10 elements,namely,Ag,Au,Bi,Cu,In,Ni,Sb,Sn,Zn and Pb.It can handle the calculation of phase diagrams in all combinations of these elements and all composition ranges.In addition,based on this tool,the liquidus,solidus,phase fractions and constitutions,equilibrium and non-equilibrium solidification behavior,surface tension and viscosity of liquid,diffusion reactions and microstructural evolution,etc.can be predicted.Typical examples of the calculation and application of this tool are presented.The design tool is expected to be a powerful tool for the development of Pb-free solders,as well as for promoting the understanding of the interfacial phenomena between Cu substrate and Pb-free solders in electronic packaging technology. | OHNUMA Ikuo KAINUMA Ryosuke ISHIDA Kiyohito CHANG Austin Y. | 2010 | Science China(Technological Sciences)2010，53，6： | 0 |
| 12 | Thermodynamic calculation on metallic thermoreduction during preparation of aluminum-rare master alloys显示文摘A thermodynamic calculation method on metallic thermoreduction during preparation of aluminum rare metal alloys was presented. Taking preparation of aluminum scandium master alloys using aluminum and magnesium thermoreduction of scandiumchloride as an example, this method was applied and the results were testified by experiment. [ | 姜锋 李汉广 尹志民 | 2001 | 中国有色金属学会会刊:英文版2001，11，1： | 0 |
| 13 | Stability of Phases in SiC and Si_3N_4 Whisker Formation显示文摘The stability of the phases in equilibrium is calculated and discussed in order to analyse and predict thereactions in SiC and Si3N4 whisker formation.Equilibria among SiC,Si3N4,Si2N2O,SiO2 and the gas phaseare evaluated at different C activity,N2 pressure,and temperature.According to the phase stabilitydiagrams,Si3N4 whisker was formed with the increase of N2 pressure and decrease of C activity;SiC whiskerwas stable with the increase of C activity and decrease of N2 pressure.In order to control the impure phasesduring the whisker formation,O2 partial pressure is the most important factor. | 陈声崎 周延春 夏非 | 1992 | Journal of Materials Science & Technology1992，8，2： | 0 |
| 14 | Macrosegregation and the underlying mechanism in Ti-6.5Al-1.0Cr-0.5Fe-6.0Mo-3.0Sn-4.0Zr alloy显示文摘A novel method for the analysis of composition distribution of titanium alloys over a large area(64 mm × 72 mm) was investigated by exploring the original position statistic distribution based on spark spectrum(OPA-SS) in Ti-6.5 Al-1.0 Cr-0.5 Fe-6.0 Mo-3.0-Sn-4.0 Zr titanium alloy. The results showed that OPA-SS could characterize the distribution of elements in different positions on the titanium alloy. The macrosegregation of Sn was the most pronounced, with a statistic segregation degree higher than 18%;the macrosegregation of Mo followed with a statistic segregation degree of 10%;the macrosegregation of Al and Fe was relatively milder,lower than 8%. The main reason for the macrosegregation state of the as-cast Ti-6.5 Al-1.0 Cr-0.5 Fe-6.0 Mo-3.0 Sn-4.0 Zr alloy can be the solute redistribution during liquid solidification and the diffusion rate of each element in the solid phase. | Xin Liu Guang Feng Yu Zhou Qunbo Fan | 2019 | Progress in Natural Science:Materials International2019，29，2： | 0 |
| 15 | Study on Transformation of CaO-Al_2O_3-SiO_2-MgO System Inclusions in ZG06Cr13Ni4Mo Stainless Steel显示文摘This paper aims at generally studying on the inclusions of ZGG06Cr13Ni4Mo ultra-low carbon stainless steel used for large scale hydraulic turbine sets. On the basis of analysis the industrial test samples, thermodynamic software FactSage is used to study inclusions transformation process in CaO-SiO2-Al2O3-MgO system while stainless steel is been smelting. The results illustrate the inclusions melting points and plasticity variation law. The reasonable inclusions plasticity controlling area is found out in low melting point. The melting point is up to 1280℃ While MgO weight concentration is 10% in CaO-SiO2-Al2O3-MgO system, SiO2, Al2O3 and CaO in inclusions are in weight concentration range of 50-70%, 10-20% and 10-40%, respectively. For purpose of gaining low melting point inclusions, silicon alumina radio in deoxidant should be controlled between 2-5 for ultra-low carbon stainless steel refining in industry. | LIU Jian-hui1,3, DONG Han1,3, ZHU Rong2, LI Shi-qi2 (1. Institute for Structural Materials,Central Iron and Steel Research Institute, Beijing 100081,China 2. School of Metallurgical and Ecological Engineering,University of Science and Technology Beijing, Beijing 100083,China 3. National Engineering Research Center of Advanced Steel Technology, Beijing 100081,China) | 2011 | Journal of Iron and Steel Research(International)2011，18，S2： | 0 |
| 16 | Phase diagram optimization and calculation of the systems containing rare earth chlorides' | 乔芝郁 邢献然 王明生 庄卫东 桂玮珍 段淑贞 郑朝贵 叶于浦 | 1995 | Progress in Natural Science:Materials International1995，5，4： | 0 |
| 17 | THERMODYNAMIC CALCULATION WITH MODELS FOR LIQUID COPPER显示文摘THERMODYNAMICCALCULATIONWITHMODELSFORLIQUIDCOPPERDing,Xueyong;Wang,Wenzhong;Gou,DenTHERMODYNAMICCALCULATIONWITHMODELSFORLIQUI... | Ding,Xueyong Wang,Wenzhong Gou,Den(Department of Ferrous Metallurgy, Northeastern University, Shenyang 110006)Han,Qiyong(Department of Physical Chemistry, University of Science & Technology Beijing,Beijing 100083) | 1994 | 中国有色金属学会会刊:英文版1994，4，2： | 0 |
| 18 | Thermodynamic Calculation Method for Formation of Rare Earth Inclusions in Conductive Copper显示文摘The thermodynamic calculation method for the formation of rare earth inclusions in conductive copper was discussed. After the formation sequence was calculated, the thermodynamic condition for the interchange between RE inclusions was further calculated. As an example, thermodynamic law of the formation for all kinds of cerium inclusions was discussed in conductive copper alloyed by cerium. The theoretical results are shown to be in good agreement with the experimental results. | 公茂秀 王福明 李文超 杜雪岩 郭宇艳 王玉集 | 1999 | Rare Metals1999，18，4： | 0 |
| 19 | A simple method of synthesizing multi-wall carbon nanotubes/SnO core/shell nanostructure显示文摘Multi-wall carbon nanotubes(MWNTs)/SnO core/shell nanosturcture was synthesized by a simple solution-based method,in which SnCl2 was solved in distilled water containing dispersed MWNTs,then stired,filtered and washed in ambient atmosphere,finally dryed in air at 90 ℃ for 6 h.The MWNTs/SnO core/shell nanostructure was characterized by X-ray diffraction(XRD),transmission electron microscopy(TEM).It is found that surface defects of MWNTs are necessary for the deposition of SnO.The mechanism of the SnO nanocoating formation through the hydrolysis of SnCl2 in water(4SnCl2+2H2OSn4(OH)2Cl6+2HCl) was presented. | SUN Xue1),CHU Yi2),WANG Dawei3),DU Jinhong3),ZHANG Baoyou2),and WANG Fuping1)1) School of Science,Harbin Institute of Technology,Harbin 150001,China 2) School of Materials Science and Engineering,Harbin Institute of Technology,Harbin 150001,China 3) Shenyang National Laboratory for Materials Science,Institute of Metal Research,Chinese Academy of Sciences,Shenyang 110016,China | 2007 | Rare Metals2007，26，S1： | 0 |
| 20 | Reaction mechanisms between molten CaF2-based slags and molten 9CrMoCoB steel显示文摘Investigating the reaction mechanism between slag and 9CrMoCoB steel is important to develop the proper slag and produce qualified ingots in the electroslag remelting(ESR) process. Equilibrium reaction experiments between molten 9CrMoCoB steel and the slags of 55 wt%CaF2–20 wt%CaO–3 wt%MgO–22 wt%Al2O3–xwt%B2O3(x = 0.0, 0.5, 1.0, 1.5, 2.0, 3.0) were conducted. The reaction mechanisms between molten 9 CrMoCoB steel and the slags with different B2O3 contents were deduced based on the composition of the steel and slag samples at different reaction times. Results show that B content in the steel can be controlled within the target range when the B2O3 content is 0.5 wt% and the FeO content ranges from 0.18 wt% to 0.22 wt% in the slag. When the B2O3 content is ≥1 wt%, the reaction between Si and B2O3 leads to the increase of the B content of steel. The additions of SiO2 and B2O3 to the slag should accord to the mass ratio of [B]/[Si] in the electrode, and SiO2 addition inhibits the reaction between Si and Al2O3. | Lei-zhen Peng Zhou-hua Jiang Xin Geng | 2020 | International Journal of Minerals,Metallurgy and Materials2020，27，5： | 0 |
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