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Functional-template directed self-assembly(FTDSA) of mesostructured organic-inorganic hybrid materials

查看全文 作  者:LI [1]LeLe;SUN [1]LingDong;ZHANG YaWen m YAN [1]ChunHua 高影响力作者 机构地区:[1]Beijing National Laboratory for Molecular Sciences,State Key Laboratory of Rare Earth Materials Chemistry and Applications&PKU-HKU Joint Lab in Rare Earth Materials and Bioinorganic Chemistry,College of Chemistry and Molecular Engineering,Peking University,Beijing 100871,China高影响力机构 出  处:《Science China Chemistry》索引2009年第52卷第11期,共10页高影响力期刊 基  金:Supported by the National Natural Science Foundation of China (Grant Nos. 20821091 and 20771009) 摘  要:Since the discovery of a surfactant directed self-assembly approach for the fabrication of mesoporous silica in 1992,increasing attention has been focused on the design and synthesis of mesostructured functional materials.Organic functionalization is becoming a major topic in this research field,since highly ordered mesostructured organic-inorganic hybrids offer novel functionalities and enhanced performance over their individual components.We begin with a brief overview of the three fundamental methods(post-synthetic grafting technique,co-condensation method,and preparation of periodic mesoporous organosilicas) for the preparation of organically functionalized mesostructured silica,and focus on one of the most promising approaches,which herein was named as functional-template directed self-assembly(FTDSA) approach,and in the eyes of the authors it has a special position in the preparation of this class of hybrid materials.A comprehensive overview of the state of research in the area of FTDSA and its potential applications will be given. 关 键 词:MESOPOROUS materials SELF-ASSEMBLY ORGANIC-INORGANIC HYBRIDS
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