Modeling assessment for ammonium nitrogen recovery from wastewater by chemical precipitation

查看全文 作　　者：Tao [1]Zhang;Qiucheng [1]Li;Lili [1]Ding;Hongqiang [1]Ren;Ke [1]Xu;Yonggang [1]Wu;Dong [2]Sheng

机构地区：[1]State Key Laboratory of Pollution Control and Resource Reuse, School of the Environment, Nanjing University, Nanjing 210093, China;[2]Modern Analysis Center, Nanjing University, Nanjing 210093, China

出　　处：《Journal of Environmental Sciences》索引2011年第23卷第6期,共10页

基　　金：supported by the National High Technology Research and Development Program(863) of China(No.2009AA033003);the National Water Pollution Control and Management Science and Technology Breakthrough Program(No.2009ZX07106-004);the Scientific Research Foundation of Graduate School of Jiangsu Province(No.CX09B 013Z);the Key Technology Research and Development Program of Jiangsu Province (No.BE2008668);the Ph.D Candidate Academic Foundation of Ministry of Education of China 摘　　要：Chemical precipitation to form magnesium ammonium phosphate(MAP) is an effective technology for recovering ammonium nitrogen(NH4+-N).In the present research,we investigated the thermodynamic modeling of the PHREEQC program for NH4+-N recovery to evaluate the effect of reaction factors on MAP precipitation.The case study of NH4+-N recovery from coking wastewater was conducted to provide a comparison.Response surface methodology(RSM) was applied to assist in understanding the relative significance of reaction factors and the interactive effects of solution conditions.Thermodynamic modeling indicated that the saturation index(SI) of MAP followed a polynomial function of pH.The SI of MAP increased logarithmically with the Mg2+/NH4+ molar ratio(Mg/N) and the initial NH4+-N concentration(CN),respectively,while it decreased with an increase in Ca2+/NH4+ and CO32?/NH4+ molar ratios(Ca/N and CO32?/N),respectively.The trends for NH4+-N removal at different pH and Mg/N levels were similar to the thermodynamic modeling predictions.The RSM analysis indicated that the factors including pH,Mg/N,CN,Ca/N,(Mg/N)×(CO32?/N),(pH)2,(Mg/N)2,and(CN)2 were significant.Response surface plots were useful for understanding the interaction effects on NH4+-N recovery. 关键词：化学沉淀法磷酸铵镁焦化废水氮回收率热力学模型响应面方法评估建模

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Modeling assessment for ammonium nitrogen recovery from wastewater by chemical precipitation

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