Polydentate-ligand-supported self-assembly of heterometallic T-shaped Co_4 Dy cluster showing slow magnetic relaxation

查看全文 作　　者：KE [1,2]HongShan;GUO [1]Yang;ZHAO [1]Lang;TANG [1]JinKui

机构地区：[1]State Key Laboratory of Rare Earth Resource Utilization,' Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China;[2]Graduate University of the Chinese Academy of Sciences, Beijing 100039, China

出　　处：《Science China Chemistry》索引2012年第55卷第6期,共4页

基　　金：supported by the National Natural Science Foundation of China (91022009, 20921002) 摘　　要：A novel mixed-valent heterometallic pentanuclear CoⅢ3 CoⅡ Dy Ⅲ cluster has been rationally assembled taking advantage of a bifunctional ligand with o-vanillin and tripodal tris(hydroxymethyl)aminomethane units. This unique heterometallic cluster represents a rare example of T-shaped molecules exhibiting slow magnetic relaxation. 关键词：多齿配体磁弛豫自组装集群 T形三(羟甲基)氨基甲烷显示邻香兰素

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Polydentate-ligand-supported self-assembly of heterometallic T-shaped Co_4 Dy cluster showing slow magnetic relaxation

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