Lowing the energy loss of organic solar cells by molecular packing engineering via multiple molecular conjugation extension

查看全文 作　　者：Hongbin [1]Chen;Yalu [1]Zou;Huazhe [1]Liang;Tengfei [1,2]He;Xiaoyun [3]Xu;Yunxin [2]Zhang;Zaifei [3]Ma;Jing [4]Wang;Mingtao [1]Zhang;Quanwen [2]Li;Chenxi [1]Li;Guankui [2]Long;Xiangjian [1]Wan;Zhaoyang [1]Yao;Yongsheng [1]Chen

机构地区：[1]State Key Laboratory and Institute of Elemento-Organic Chemistry,Centre of Nanoscale Science and Technology and Key Laboratory of Functional Polymer Materials,Renewable Energy Conversion and Storage Center(RECAST),College of Chemistry,Nankai University,Tianjin 300071,China;[2]School of Materials Science and Engineering,National Institute for Advanced Materials,Renewable Energy Conversion and Storage Center(RECAST),Nankai University,Tianjin 300350,China;[3]State Key Laboratory for Modification of Chemical Fibers and Polymer Materials,Center for Advanced Low-dimension Materials,College of Materials Science and Engineering,Donghua University,Shanghai 201620,China;[4]School of Materials Science&Engineering,Tianjin University of Technology,Tianjin 300384,China

出　　处：《Science China Chemistry》索引2022年第65卷第7期,共12页

基　　金：supported by the National Natural Sciences Foundation of China (21935007, 52025033, 51873089);MoST of China (2019YFA0705900);Tianjin city (20JCZDJC00740);111 Project (B12015);the Opening Project of State Key Laboratory of Luminescent Materials and Devices (SCUT, 2021-skllmd-09)。 摘　　要：The central unit(benzo[c][1,2,5]thiadiazole) in Y6 series of molecules plays a determining role in their unique intermolecular packing for a three-dimensionally(3D) network, largely endowing their organic solar cells(OSCs) with so far the best power conversion efficiencies(PCEs) and also largely suppressed energy losses(Eloss). Despite its vital role in molecular packing, very few explorations for central unit have been conducted due to possibly the constructing challenge of central heterocyclic units.Herein, a highly efficient acceptor-donor-acceptor(A-D-A) type electron acceptor, CH17, has been designed and constructed,featured with a prominent π extension in both directions of the central and end units with respect to Y6 series. Such a multiple and much enhanced conjugation extension in CH17 enables a much more effective and compact 3D molecular packing compared with that of Y6 supported by X-ray single crystal and other analysis, mainly caused by a newly observed distinctive dual “end unit to central unit” packing mode. This much favorable molecular packing, also kept in its blends with donor materials, leads a larger electron and hole transfer integrals and hence much improved charge transport, and reduced energetic disorders in CH17blends. More importantly, the observed upshifted charge transfer(CT) state of CH17 blends compared with that of Y6, due to its increased molecular conjugation extension in both directions, further enhances the hybridization between its CT and local exciton(LE) states, resulting in higher luminescence efficiency, much suppressed non-radiative recombination loss and smaller Elosswith respect to that of Y6. Consequently, an excellent PCE of 17.84% is achieved with PM6 as the donor in a binary device compared with a PCE of 16.27% for the controlled Y6 device. Furthermore, a further improved PCE of 18.13% is achieved by CH17-based ternary single-junction OSCs along with a markedly reduced Elossof 0.49 e V and larger open-circuit voltage(Voc) of0.89 V, compared with that(16.27% of PCE, 0.85 V of Voc, and 0.53 e V of Eloss) of the control device using Y6. This significantly improved photovoltaic performance caused by molecular multiple conjugation extension, especially through the largely unexplored central unit, indicates that there is still much room to further enhance OSC performance by addressing the most important issue for OSC, i.e, the smaller Voccaused by larger Eloss, through engineering molecular packing by designing/tuning molecule more dedicatedly. 关键词：organic solar cells A-D-A electron acceptor reduced Eloss central unit multiple conjugation extension molecular packing

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Lowing the energy loss of organic solar cells by molecular packing engineering via multiple molecular conjugation extension

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