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| 1 | Non‑noble Metal Electrocatalysts for the Hydrogen Evolution Reaction in Water Electrolysis显示文摘Water electrolysis is a sustainable approach for hydrogen production by using electricity from clean energy sources.However,both the hydrogen evolution reaction(HER)and the oxygen evolution reaction(OER)associated with water electrolysis are kinetically sluggish,leading to low efficiency in corresponding electrolysis devices.In addition,current electrocatalysts that can catalyze both HER and OER to practical rates require noble metals such as platinum that are low in abundance and high in price,severely limiting commercialization.As a result,the development of high-performance and cost-effective non-noble metal electrocatalysts to replace noble ones has intensified.Based on this,this review will comprehensively present recent research in the design,synthesis,characterization and performance validation/optimization of non-noble metal HER electrocatalysts and analyze corresponding catalytic mechanisms.Moreover,several important types of non-noble metal electrocatalysts including zero-dimensional,one-dimensional,two-dimensional and three-dimensional materials are presented with an emphasis on morphology/structure,synergetic interaction between metal and support,catalytic property and HER activity/stability.Furthermore,existing technical challenges are summarized and corresponding research directions are proposed toward practical application. | Huimin Wu Chuanqi Feng Lei Zhang Jiujun Zhang David P.Wilkinson | 2021 | Electrochemical Energy Reviews2021，4，3： | 7 |
| 2 | Multi-terminal VSC HVDC for the European supergrid: Obstacles显示文摘 | Dirk Van Hertem Mehrdad Ghandhari | 2010 | Renewable and Sustainable Energy Reviews2010，，9： | 5 |
| 3 | Perovskite Cathode Materials for Low‑Temperature Solid Oxide Fuel Cells:Fundamentals to Optimization显示文摘Acceleration of the oxygen reduction reaction at the cathode is paramount in the development of low-temperature solid oxide fuel cells.At low operating temperatures between 450 and 600℃,the interactions between the surface and the bulk of the cathode materials greatly impact the electrode kinetics and consequently determine the overall efficacy and long-term stability of the fuel cells.This review will provide an overview of the recent progress in the understanding of surface-bulk interactions in perovskite oxides as well as their impact on cathode reactivity and stability.This review will also summarize current strategies in the development of cathode materials through bulk doping and surface functionalization.In addition,this review will highlight the roles of surface segregation in the mediation of surface and bulk interactions,which have profound impacts on the properties of cathode surfaces and the bulk and therefore overall cathode performance.Although trade-offs between reactivity and stability commonly exist in terms of catalyst design,opportunities also exist in attaining optimal cathode performance through the modulation of both cathode surfaces and bulk using combined strategies.This review will conclude with future research directions involving investigations into the role of oxygen vacancy and mobility in catalysis,the rational modulation of surface-bulk interactions and the use of advanced fabrication techniques,all of which can lead to optimized cathode performance. | Zhiheng Li Mengran Li Zhonghua Zhu | 2022 | Electrochemical Energy Reviews2022，5，2： | 4 |
| 4 | Recent Progress in Polyanionic Anode Materials for Li(Na)‑Ion Batteries显示文摘In recent years,rechargeable lithium-ion batteries(LIBs)have become widely used in everyday applications such as portable electronic devices,electric vehicles and energy storage systems.Despite this,the electrochemical performance of LIBs cannot meet the energy demands of rapidly growing technological evolutions.And although significant progress has been made in the development of corresponding anodes based primarily on carbon,oxide and silicon materials,these materials still possess shortcomings in current LIB applications.For example,graphite exhibits safety concerns due to an operating potential close to that of lithium(Li)metal plating whereas Li4Ti5O12 possesses low energy density for high operation potential and silicon experiences limited cyclability for large volume expansion during charging/discharging.Alternatively,polyanionic compounds such as(PO_(4))^(3–),(SiO_(4))^(4–),(SO_(4))^(2–)and(BO_(3))^(3−)as electrode materials have gained increasing attention in recent years due to their ability to stabilize structures,adjust redox couples and provide migration channels for'guest'ions,resulting in corresponding electrode materials with long-term cycling,high energy density and outstanding rate capability.Based on these advantages and combined with recent findings in terms of silicate anodes,this review will summarize the recent progress in the development of polyanion-based anode materials for LIBs and sodium-ion batteries.Furthermore,this review will present our latest research based on polyanion groups such as(GeO_(4))^(4–)to compensate for the lack of available studies and to provide our perspective on these materials. | Yao Liu Wei Li Yongyao Xia | 2021 | Electrochemical Energy Reviews2021，4，3： | 4 |
| 5 | Solid Oxide Electrolysis of H_(2)O and CO_(2) to Produce Hydrogen and Low‑Carbon Fuels显示文摘Solid oxide electrolysis cells(SOECs)including the oxygen ion-conducting SOEC(O-SOEC)and the proton-conducting SOEC(H-SOEC)have been actively investigated as next-generation electrolysis technologies that can provide high-energy conversion efficiencies for H_(2)O and CO_(2) electrolysis to sustainably produce hydrogen and low-carbon fuels,thus providing higher-temperature routes for energy storage and conversion.Current research has also focused on the promotion of SOEC critical components to accelerate wider practical implementation.Based on these investigations,this perspective will summarize the most recent progress in the optimization of electrolysis performance and long-term stability of SOECs,with an emphasis on material developments,technological approaches and improving strategies,such as nano-composing,surface/interface engineering,doping and in situ exsolution.Existing technical challenges are also analyzed,and future research directions are proposed to achieve SOEC technical maturity and economic feasibility for diverse conversion applications. | Yun Zheng Zhongwei Chen Jiujun Zhang | 2021 | Electrochemical Energy Reviews2021，4，3： | 4 |
| 6 | 3D Hierarchical Carbon‑Rich Micro‑/Nanomaterials for Energy Storage and Catalysis显示文摘Increasing concerns over climate change and energy shortage have driven the development of clean energy devices such as batteries,supercapacitors,fuel cells and solar water splitting in the past decades.And among potential device materials,3D hierarchical carbon-rich micro-/nanomaterials(3D HCMNs)have come under intense scrutiny because they can prevent the stacking and bundling of low-dimensional building blocks to not only shorten diffusion distances for matter and charge to achieve high-energy-high-power storage but also greatly expose active sites to achieve highly active,durable and efficient catalysis.Based on this,this review will summarize the synthetic strategies and formation mechanisms of 3D HCMNs,including 3D nanocarbons,polymers,COFs/MOFs,templated carbons and derived carbon-based hybrids with a focus on 3D superstructures such as urchins,flowers,hierarchical tubular structures as well as nanoarrays including nanotube,nanofiber and nanosheet arrays.This review will also discuss the application of 3D HCMNs in energy storage and catalysis systems,including batteries,supercapacitors,electrocatalysis and photo(electro)catalysis.Overall,this review will provide a comprehensive overview of the recent progress of 3D HCMNs in terms of preparation strategies,formation mechanisms,structural diversities and electrochemical applications to provide a guideline for the rational design and structure–function exploration of 3D hierarchical nanomaterials from different sources beyond carbon-based species. | Zhixiao Xu Wenjing Deng Xiaolei Wang | 2021 | Electrochemical Energy Reviews2021，4，2： | 3 |
| 7 | High‑Mass‑Loading Electrodes for Advanced Secondary Batteries and Supercapacitors显示文摘The growing demand for advanced electrochemical energy storage systems(EESSs)with high energy densities for electric vehicles and portable electronics is driving the electrode revolution,in which the development of high-mass-loading electrodes(HMLEs)is a promising route to improve the energy density of batteries packed in limited spaces through the optimal enlargement of active material loading ratios and reduction of inactive component ratios in overall cell devices.However,HMLEs face significant challenges including inferior charge kinetics,poor electrode structural stability,and complex and expensive production processes.Based on this,this review will provide a comprehensive summary of HMLEs,beginning with a basic presentation of factors influencing HMLE electrochemical properties,the understanding of which can guide optimal HMLE designs.Rational strategies to improve the electrochemical performance of HMLEs accompanied by corresponding advantages and bottlenecks are subsequently discussed in terms of various factors ranging from inactive component modification to active material design to structural engineering at the electrode scale.This review will also present the recent progress and approaches of HMLEs applied in various EESSs,including advanced secondary batteries(lithium-/sodium-/potassium-/aluminum-/calcium-ion batteries,lithium metal anodes,lithium-sulfur batteries,lithium-air batteries,zinc batteries,magnesium batteries)and supercapacitors.Finally,this review will examine the challenges and prospects of HMLE commercialization with a focus on thermal safety,performance evaluation,advanced characterization,and production cost assessment to guide future development. | Feng Wu Mingquan Liu Ying Li Xin Feng Kun Zhang Ying Bai Xinran Wang Chuan Wu | 2021 | Electrochemical Energy Reviews2021，4，2： | 3 |
| 8 | Distributed multi-generation: A comprehensive view显示文摘 | Gianfranco Chicco Pierluigi Mancarella | 2007 | Renewable and Sustainable Energy Reviews2007，，3： | 3 |
| 9 | Vertical axis wind turbine – A review of various configurations and design techniques显示文摘 | Muhammad Mahmood Aslam Bhutta Nasir Hayat Ahmed Uzair Farooq Zain Ali Sh. Rehan Jamil Zahid Hussain | 2011 | Renewable and Sustainable Energy Reviews2011，，4： | 3 |
| 10 | Single‑Atom Catalysts:Advances and Challenges in Metal‑Support Interactions for Enhanced Electrocatalysis显示文摘Single-atom catalysts(SACs),which contain a single metal atom supported on a well-confined substrate,are among the most promising heterogeneous catalysts owing to their unique advantages,such as high intrinsic activity and selectivity,tunable bonds and coordination,abundant metal-containing active sites,and atomic economy.Since metal-support interactions(MSIs)in SACs exert a substantial influence on the catalytic properties,gaining a profound understanding and recognition of catalytic reactions depends greatly on investigating MSIs both experimentally and computationally.Hence,the engineer-ing and modulation of MSIs are regarded as one of the most efficient methods to rationally design SACs with disruptively enhanced catalytic properties.In this review,we track the recent advances in SACs from an MSI perspective.We then discuss the existing MSIs in SACs and elucidate the significant role of strong MSIs in catalytic properties and mechanisms.The chal-lenges hindering the rational design of supported SACs with strong MSIs,which are currently still far from being completely understood and overcome,are described.In addition,the correlation between strong MSIs and electrocatalytic activities in SACs,including an outlook to increase our understanding of MSIs,is discussed.Finally,the present review provides some perspectives and an in-depth understanding of strong MSIs to advance high-performing SACs. | Yang Mu Tingting Wang Jian Zhang Changgong Meng Yifu Zhang Zongkui Kou | 2022 | Electrochemical Energy Reviews2022，5，1： | 3 |
| 11 | A brief status on condition monitoring and fault diagnosis in wind energy conversion systems显示文摘 | Y. Amirat M.E.H. Benbouzid E. Al-Ahmar B. Bensaker S. Turri | 2009 | Renewable and Sustainable Energy Reviews2009，，9： | 3 |
| 12 | Design Principle,Optimization Strategies,and Future Perspectives of Anode‑Free Configurations for High‑Energy Rechargeable Metal Batteries显示文摘Metal anodes(e.g.,lithium,sodium and zinc metal anodes)based on a unique plating/stripping mechanism have been well recognized as the most promising anodes for next-generation high-energy metal batteries owing to their superior theoretical specific capacities and low redox potentials.However,realizing full utilization and the theoretical capacity of metal anodes remains challenging because of their high reactivity,poor reversibility,and nonplanar metal evolution patterns,which lead to irreversible loss of active metals and the electrolyte.To minimize the above issues,excess metal sources and flooded electrolytes are generally used for laboratory-based studies.Despite the superior cycling performance achieved for these cells,the metal-anode-excess design deviates from practical applications due to the low anode utilization,highly inflated coulombic efficiency,and undesirable volumetric capacity.In contrast,anode-free configurations can overcome these draw-backs while reducing fabrication costs and improving cell safety.In this review,the significance of anode-free configurations is elaborated,and different types of anode-free cells are introduced,including reported designs and proposed feasible yet unexplored concepts.The optimization strategies for anode-free lithium,sodium,zinc,and aluminum metal batteries are summarized.Most importantly,the remaining challenges for extending the cycle life of anode-free cells are discussed,and the requirements for anode-free cells to reach practical applications are highlighted.This comprehensive review is expected to draw more attention to anode-free configurations and bring new inspiration to the design of high-energy metal batteries. | Wentao Yao Peichao Zou Min Wang Houchao Zhan Feiyu Kang Cheng Yang | 2021 | Electrochemical Energy Reviews2021，4，3： | 3 |
| 13 | Electrolyte/Electrode Interfaces in All‑Solid‑State Lithium Batteries:A Review显示文摘All-solid-state lithium batteries are promising next-generation energy storage devices that have gained increasing attention in the past decades due to their huge potential towards higher energy density and safety.As a key component,solid electrolytes have also attracted significant attention and have experienced major breakthroughs,especially in terms of Li-ion conductivity.However,the poor electrode compatibility of solid electrolytes can lead to the degradation of electrolyte/electrode interfaces,which is the major cause for failure in all-solid-state lithium batteries.To address this,this review will summarize the indepth understanding of physical and chemical interactions between electrolytes and electrodes with a focus on the contact,charge transfer and Li dendrite formation occurring at electrolyte/electrode interfaces.Based on mechanistic analyses,this review will also briefly present corresponding strategies to enhance electrolyte/electrode interfaces through compositional modifications and structural designs.Overall,the comprehensive insights into electrolyte/electrode interfaces provided by this review can guide the future investigation of all-solid-state lithium batteries. | Yuepeng Pang Jinyu Pan Junhe Yang Shiyou Zheng Chunsheng Wang | 2021 | Electrochemical Energy Reviews2021，4，2： | 3 |
| 14 | Application of Scanning Tunneling Microscopy in Electrocatalysis and Electrochemistry显示文摘Scanning tunneling microscopy(STM)has gained increasing attention in the field of electrocatalysis due to its ability to reveal electrocatalyst surface structures down to the atomic level in either ultra-high-vacuum(UHV)or harsh electrochemical conditions.The detailed knowledge of surface structures,surface electronic structures,surface active sites as well as the interaction between surface adsorbates and electrocatalysts is highly beneficial in the study of electrocatalytic mechanisms and for the rational design of electrocatalysts.Based on this,this review will discuss the application of STM in the characterization of electrocatalyst surfaces and the investigation of electrochemical interfaces between electrocatalyst surfaces and reactants.Based on different operating conditions,UHV-STM and STM in electrochemical environments(EC-STM)are discussed separately.This review will also present emerging techniques including high-speed EC-STM,scanning noise microscopy and tip-enhanced Raman spectroscopy. | Haifeng Feng Xun Xu Yi Du Shi Xue Dou | 2021 | Electrochemical Energy Reviews2021，4，2： | 2 |
| 15 | The reduction and control technology of tar during biomass gasification/pyrolysis: An overview显示文摘 | Jun Han Heejoon Kim | 2006 | Renewable and Sustainable Energy Reviews2006，，2： | 2 |
| 16 | A review on phase change materials integrated in building walls显示文摘 | Frédéric Kuznik Damien David Kevyn Johannes Jean-Jacques Roux | 2010 | Renewable and Sustainable Energy Reviews2010，，1： | 2 |
| 17 | Advanced Noncarbon Materials as Catalyst Supports and Non‑noble Electrocatalysts for Fuel Cells and Metal–Air Batteries显示文摘Electrochemical energy systems such as fuel cells and metal–air batteries can be used as clean power sources in the field of electric transportation and possess great potential in the reduction of various energy and environmental issues.In these systems,the oxygen reduction reaction(ORR)at the cathode is the rate-determining factor for overall system performance,and up to now,platinum group metals supported on carbon materials,especially Pt,remain the highest performing and the most practical ORR electrocatalysts.However,corresponding carbonaceous catalyst supports are extremely susceptible to corrosion under electrochemical operation,and therefore,the extensive exploration of alternative stable materials for ORR electrocatalysts with both high electrochemical stability and catalytic performance is essential.Here,noncarbon materials with high corrosion resistance have been explored to substitute traditional carbon supports or even act directly as low-cost non-noble metal electrocatalysts,and based on this,this review will present a comprehensive overview and deep analysis of the recent progress in noncarbon materials,including metals,oxides,nitrides,carbides,sulfides,and so on.Overall,general attributes associated with noncarbon materials include high corrosion resistance,strong metal–support interaction,and impressive porous structure retention.However,major drawbacks include low electrical conductivity,insufficient chemical stability in acidic or alkaline media,and poor electrochemical stability at ORR electrode potentials.To overcome these challenges,this review will also summarize efficient strategies such as combining with highly conductive materials,introducing dopants and forming vacancies to result in promising electrocatalytic ORR performances.Finally,this review will propose possible research directions to facilitate future research and development toward the practical application of noncarbon-based ORR electrocatalysts. | Shiming Zhang Menghui Chen Xiao Zhao Jialin Cai Wei Yan Joey Chung Yen Shengli Chen Yan Yu Jiujun Zhang | 2021 | Electrochemical Energy Reviews2021，4，2： | 2 |
| 18 | Bio-diesel as an alternative fuel for diesel engines—A review显示文摘 | A. Murugesan C. Umarani R. Subramanian N. Nedunchezhian | 2007 | Renewable and Sustainable Energy Reviews2007，，3： | 2 |
| 19 | Microalgae for biodiesel production and other applications: A review显示文摘 | Teresa M. Mata António A. Martins Nidia. S. Caetano | 2009 | Renewable and Sustainable Energy Reviews2009，，1： | 2 |
| 20 | Biofuels from microalgae—A review of technologies for production, processing, and extractions of biofuels and co-products显示文摘 | Liam Brennan Philip Owende | 2009 | Renewable and Sustainable Energy Reviews2009，，2： | 2 |
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