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| 1 | 机械化学法制备的Al/Ce复合氧化物负载NiMo催化剂的加氢脱硫活性(英文)显示文摘将Al和/或Ce的硝酸盐与NH_4HCO_3球磨混合,采用机械化学法制备了Al_2O_3-CeO_2载体(其中Ce含量为1-10 wt%),再以杂多钼酸盐(NH_4)_4NiMo_6O_(24)为活性金属Ni和Mo的前驱体,通过浸渍法制备NiMo_6/Al_2O_3-CeO_2催化剂,并将其用于1-苯并噻吩(BT)的加氢脱硫(HDS)反应中.运用化学分析、X射线衍射、N_2吸附-脱附法、H_2程序升温还原、NH_3程序升温脱附和X射线光电子能谱对催化剂的物化性质进行了表征.结果表明,催化剂的酸性随着载体中Ce含量的增加而下降.Ce修饰的Al_2O_3载体表面的NiS/MoS原子比下降了2倍.NiMo_6/Al_2O_3催化剂表现出最高的HDS活性(以单位重量催化剂计),其酸性和表面MoO_xS_y物种的浓度(Mo^(5+)浓度)也最高;当催化剂中Ce含量逐渐增加到10 wt%以上时,其活性逐渐将为0.与浸渍法制得的参比催化剂相比,前驱体和催化剂组成相同的情况下,采用机械化学法制得的所有催化剂活性明显提高. | Květa Jirátová Alla Spojakina Luděk Kaluza Radostina Palcheva Jana Balabánová Georgi Tyuliev | 2016 | Chinese Journal of Catalysis2016，37，2： | 6 |
| 2 | 镍钼杂多酸制备NiMo/γ-Al_2O_3催化剂及硼、钴或镍改性氧化铝的影响(英文)显示文摘A hydrotreating NiMo/γ-Al2O3 catalyst(12 wt% Mo and 1.1 wt% Ni) was prepared by impregnation of the support with the Anderson-type heteropolyoxomolybdate(NH4)4Ni(OH)6Mo6O18.Before impregnation of the support,it was modified with an aqueous solution of H3BO3,Co(NO3)2,or Ni(NO3)2.The catalysts were investigated using N2 adsorption,O2 chemisorption,X-ray diffraction,UV-Vis spectroscopy,Fourier transform infrared spectroscopy,temperature-programmed reduction,temperature-programmed desorption,and X-ray photoelectron spectroscopy.The addition of Co,Ni,or B influenced the Al2O3 phase composition and gave increased catalytic activity for 1-benzothiophene hydrodesulfurization(HDS).X-ray photoelectron spectroscopy confirmed that the prior loading of Ni,Co or B increased the degree of sulfidation of the NiMo/γ-Al2O3 catalysts.The highest HDS activity was observed with the NiMo/γ-Al2O3 catalyst with prior loaded Ni. | Radostina PALCHEVA Luděk KALUZA Alla SPOJAKINA Květue JIRTOV Georgi TYULIEV | 2012 | 催化学报2012，33，6： | 6 |
| 3 | Prolonged QTo intervaland torsades de pointes induced by citalopram 显示文摘 | Deshmukh A Ulveling K Alla V | 2012 | Tex Heart InstJ2012，39，1： | 1 |
| 4 | Omenn syndrome with mutation in RAG1 gene显示文摘 | Jaouad IC Ouldim K Ali Ou Alla S | 2008 | Indian J Pediatr2008，75，9： | 1 |
| 5 | Taylor expansion diagrams: acanonical representation fo r verification o f data flo w designs显示文摘 | Ciesielski M K alla P Askar S | 2006 | IEEE Transactions on Computers2006，55，9： | 1 |
| 6 | Lack of effects of trime tazidineon systemic hemody-namics in patients with coronary artery dis- eade: a placebo-onlrolled study 显示文摘 | Porin M Harpeyc K Alla J | 1994 | Clin Trials Metaanal1994，29，： | 1 |
| 7 | Differential roles of Tau class glutathione S-transferases in oxidative stress显示文摘 | KIMITI G K NELI A ALLA V | 2004 | The Journal of Biological Chemistry2004，279，23： | 1 |
| 8 | Biosorption of Cu( H ),CdC II ) and Pb( U ) byAcacia leucocephala bark powder: kinetics, equilibrium andthermodynamics 显示文摘 | Munagapati V S Yarramuthi V Nadavala S K Alla S R Abburi K | 2010 | Chemical Engineering Journal2010，157，： | 1 |
| 9 | Metabolic effects Of a growth hormone-releasing factor in patients with HIV 显示文摘 | Falutz J Allas S Blot K | 2007 | N Engl J Med2007，357，23： | 1 |
| 10 | A human myeloma cell line suitable for the generation of human monoclonal antibodies显示文摘 | Abraham K Alla D Barbara H | 2001 | Proc Natl Acad Sci USA2001，98，： | 1 |
| 11 | Energetically important C - H…F - C pseudohydrogen bonding in water: evidence and application to rational design of oligonucleotides with high binding affinity显示文摘 | Anzahaee M Y Watts J K Alla N R | 2011 | J Am Chem Soc2011，133，： | 1 |
| 12 | Local injection of a selective endothelin-b receptor agonist inhibits endothelin1-induced pain-like behavior and excitation of nociceptors in a naloxone -sensitive manner显示文摘 | Alla K Moin UF Alexander G | 2002 | The Journal of Neuroscience September 12002，22，17： | 1 |
| 13 | Infrared spectroscopic study of lignins显示文摘 | Alla M A Mohamend E I Samir M K | 1998 | Polymer Degradation and Stability1998，60，： | 1 |
| 14 | Add-on fluvoxamine improves primary negative symptoms:Evdence for specificity from response analysis of individual symptoms显示文摘 | NELSON A ALLA K | 2003 | Schizophrenia Bulletin2003，29，： | 1 |
| 15 | Heavy drugs draw heavy interest from pharma backers显示文摘 | Alla K | 2013 | Nature Medicine2013，19，6： | 1 |
| 16 | Phase Ⅱ clinical trial of intralesional administration of the oncolytic adenovirus ONYX-015 in patients with hepatobiliary tumors with correlative p53 studies显示文摘 | Della M Alla R Howard K | 2003 | Clinical Cancer Research2003，9，2： | 1 |
| 17 | Local and systemic effects of unpolymerised monomers 显示文摘 | GOSAVI S S GOSAVI S Y ALLA R K | 2010 | Dent Res J (Isfah- an)2010，7，2： | 1 |
| 18 | Cloning and expression of multiple integral membrane proteins from Mycobacterium tuberculosis in Escherichia coli显示文摘 | Alla K F P Gao Y Z Hua | | 0，，01： | 1 |
| 19 | Genome sequence and analysis of the soil cellulolytic actinomycete Thermobifidafusca YX 显示文摘 | Athanasios L Konstantinos M Natalia I lain A Miriam L Genevieve D Michele M Alla L Susan L Alex C Paul R David BW Nikos K | 2007 | J Bacteriol2007，189，6： | 1 |
| 20 | Phase Ⅱ clinical trial of intralesional administration of the oncolytic adenovirus ONYX-015 in patients with hepatobiliary tumors with correlative p53 studies显示文摘 | Della M Alla R Howard K | 2003 | Clinical Cancer Research2003，9，： | 1 |
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