| 6 | Correlation between the surface characteristics of carbon supports and their electrochemical stability and performance in fuel cell cathodes显示文摘In this paper,an extensive characterisation of a range of carbon blacks(CB)with similar surface area but different surface chemistry is carried out by flow calorimetry,Raman spectroscopy,dynamic water vapour sorption,instrumental gas analysis,nitrogen adsorption/desorption and high potential chronoamperometry.Using these carbon materials as supports,Pt/CB electrocatalysts are prepared by microwave-assisted polyol-mediated synthesis in gram scale.Structural,morphological and electrochemical properties of the prepared electrocatalysts are evaluated by X-ray diffraction,transmission electron microscopy,rotating disc electrode and in situ fuel cell characterisation of the corresponding membrane-electrode assemblies.The obtained results allow to establish a relationship between surface chemistry and electrochemical properties useful for the design of Pt/C catalyst layers with high performance and stability. | Ignacio Jiménez-Morales Alvaro Reyes-Carmona Marc Dupont Sara Cavaliere Marlene Rodlert Flavio Mornaghini Mikkel J.Larsen Madeleine Odgaard Jerzy Zajac Deborah J.Jones Jacques Rozière | 2021 | Carbon Energy2021，3，4： | 0 |
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