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| 1 | Electrochemical ageing study of mixed lanthanum/praseodymium nickelates La2-xPrxNiO4+δ as oxygen electrodes for solid oxide fuel or electrolysis cells显示文摘The chemical and electrochemical stability of lanthanide nickelates La2 NiO4+δ(LNO),Pr2 NiO4+δ(PNO)and their mixed compounds La(2-x)PrxNiO4+δ(LPNOs)with x=0.5,1 or 1.5 is reported.The aim is to promote these materials as efficient electrodes for solid oxide fuel cell(SOFC)and/or solid oxide electrolysis cell(SOEC).La2 NiO4+δand La1.5Pr0.5NiO4+δcompounds are chemically very stable as powders over one month in the temperature range 600-800℃,while the other materials rich in praseodymium progressively decompose into various perovskite-deriving components with additional Pr6 O11.Despite their uneven properties,all these materials are quite efficient and sustainable as electrodes on top of gadolinium doped ceria(GDCBL)//yttrium doped zirconia(8 YSZ)electrolyte,for one month at 700℃without polarization.Under polarization(300 mA·cm-2),the electrochemical performances of LNO,PNO and La1.5Pr0.5NiO4+δ(LP5 NO)quickly degrade in SOFC mode,i.e.for the oxygen reduction reaction,while they show durability in SOEC mode,i.e.for the oxide oxidation reaction. | Vaibhav Vibhu Aurélien Flura Aline Rougier Clément Nicollet Sébastien Fourcade Teresa Hungria Jean-Claude Grenier Jean-Marc Bassat | 2020 | Journal of Energy Chemistry2020，29，7： | 6 |
| 2 | 中温固体氧化物燃料电池阴极材料LaBiMn_2O_6的制备与性能显示文摘采用固相法合成了中温固体氧化物燃料电池(IT-SOFCs)阴极材料La Bi Mn2O6,并利用X射线衍射(XRD)和电化学阻抗谱(EIS)进行表征。结果表明该材料与电解质Ce0.7Bi0.3O1.85(CBO)在1 000℃烧结12 h不发生反应。交流阻抗和直流极化测试结果发现,阴极极化电阻随测试温度的增加而逐渐减小,700℃空气中的极化电阻为0.71Ω·cm2;氧分压测试结果显示,在600~700℃范围内,电极反应的速率控制步骤为电极上发生的电荷转移反应。电极过电位为85 m V时,700℃的阴极电流密度达到216 m A·cm-2,表明La Bi Mn2O6是一种潜在的中温固体氧化物燃料电池(IT-SOFCs)阴极材料。 | 肖辉 孙丽萍 赵辉 霍丽华 Jean-Marc Bassat Aline Rougier Sébastien Fourcade Jean-Claude Grenier | 2015 | 无机化学学报2015，31，6： | 5 |
| 3 | 钴掺杂Sr1.5La0.5MnO4的合成及高温电化学性能研究显示文摘采用EDTA-柠檬酸法合成了中温固体氧化物燃料电池阴极材料Sr_(1.5)La_(0.5)Mn_(1-x)Co_xO_4(SLMCOx),并利用粉末X射线衍射(XRD)、X射线光电子能谱(XPS)以及电化学交流阻抗谱(EIS)进行表征。结果表明,该材料与Ce0.9Gd0.1O1.95(CGO)在1 200℃烧结12 h不发生化学反应。随着Co掺入量的增加,氧化物中Mn^(3+)和Co^(2+)含量增多,晶格氧含量降低,晶格畸变率增大。交流阻抗谱(EIS)测试结果显示,钴的掺杂明显降低电极的极化电阻,其中Sr_(1.5)La_(0.5)Mn_(0.7)Co_(0.3)O_4阴极在700℃空气中的极化电阻为0.62Ω·cm^2,明显小于Sr_(1.5)La_(0.5)MnO_4阴极在750℃的极化电阻(1.5Ω·cm^2),表明钴掺杂的Sr_(1.5)La_(0.5)Mn_(1-x)CoxO_4是一种潜在的IT-SOFC阴极材料。 | 范宇航 孙丽萍 霍丽华 赵辉 Jean-Marc Bassat Aline Rougier Sebastien Fourcade Jean-Claude Grenier | 2016 | 无机化学学报2016，32，10： | 2 |
| 4 | Reduced rate of reti- nal detachment following silicone oil removal显示文摘 | Bassat I B Desatnik H Alhalel A | 2000 | Retina2000，20，6： | 1 |
| 5 | Procalcitonin and C-reactiveprotein for invasive bacterial pneumonia diagnosis among children inMozambique,a malaria-endemic area显示文摘 | Diez-Padrisa N Bassat Q Machevo S | 2010 | Plos One2010，5，13： | 1 |
| 6 | Oxygen transport properties of La2Ni1-xCuxO4+δ mixed conducting oxides 显示文摘 | BOEHM E BASSAT J -M STEIL M C | 2003 | Solid State Sci2003，5，： | 1 |
| 7 | Low antibod-ies against Plasmodium falciparum and imbalanced pro-inflam-matory cytokines are associated with severe malaria in Mozamb-ican children : a case-control study 显示文摘 | Rovira-Vallbona E Moncunill G Bassat Q | 2012 | Malar J2012，11，： | 1 |
| 8 | Oxygen transport properties of La2 Ni1-x Cux O4 +δ mixed conducting oxides 显示文摘 | Boehm E Mauvy F Bassat J M | 2003 | Solid State Science2003，5，： | 1 |
| 9 | Reduced rate of retinal detachment following silicone oil removal 显示文摘 | Bassat IB Desatnik H Alhalel A | 2000 | Retina2000，20，： | 1 |
| 10 | Similar efficacy and safety of artemether-lumefantrine (Coartem ) in Af- rican infants and children with uncomplicated falciparum malaria across different body weight ranges显示文摘 | Bassat Q Gonzalez R Machevo S | 2011 | Malar J2011，10，： | 1 |
| 11 | Hybrid acute leukaemia显示文摘 | Gale RP Bassat IB | 1987 | Br J Haematol1987，65，3： | 1 |
| 12 | Oxygen transport properties of La2 Ni1-x C uxO4 + δ mixed conducting oxides 显示文摘 | Boehm E Bassat J M Steil M C | | Solid State Sciences 200 30，，5： | 1 |
| 13 | The association of higher levels of within - normal - limits liver enzymes and the prevalence of the metabolic syndrome 显示文摘 | Steinvil A Shapira I Ben - Bassat OK | 2010 | Cardiovasc Diabetol2010，，9： | 1 |
| 14 | Procalcitonin and C-reactive protein for invasive bacterial pneumonia di- agnosis among children in Mozambique, a malaria-endemic area显示文摘 | Diez-Padrisa N Bassat Q Machevo S | 2010 | PLoS One2010，5，13： | 1 |
| 15 | Oxygen diffusion and transport properties in non-stoichiometrie Ln2-x NiO4 +δ oxides 显示文摘 | Boehm E Bassat J M Dordor P | 2005 | Solid State Ionics2005，176，： | 1 |
| 16 | Ergonomic Guidelines for Traffic Sign Design Increase Sign Comprehension显示文摘 | Ben - Bassat T Shinar D | 2006 | Human Factors2006，48，1： | 1 |
| 17 | Procalcitonin and C-reactive protein as predictors of blood culture positivity among hospitalised children with severe pneumonia in Mozambique显示文摘 | Díez-Padrisa N Bassat Q Morais L | 2012 | Trop Med Int Health2012，17，9： | 1 |
| 18 | Re-duced rate of retinal detachment following silicone oil removal显示文摘 | Bassat IB Desatnik H Alhalel A Treister G Moisseiev J | 2000 | Retina2000，20，6： | 1 |
| 19 | Closed - eruptionsurgical technique for impacted maxillary incisors: A pos- torthodontic periodontal evaluation显示文摘 | Becket A Brin I Ben- Bassat Y | 2002 | Am J Orthod Den- tofaeial Orthop2002，122，1： | 1 |
| 20 | Procalcitonin and C-reactive protein as predictors of blood culture positivity among hospitalised children with severe pneumonia in Mozambique显示文摘 | Díez-Padrisa N Bassat Q Morais L | 2012 | Trop Med Int Health2012，17，9： | 1 |
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