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| 1 | Formation of Fe-oxyhydroxides from the East Pacific Rise near latitude 13°N:Evidence from mineralogical and geochemical data显示文摘The mineralogical and geochemical characteristics of Fe-oxyhydroxide samples from one dredge station (long. 103°54.48'W, lat. 12°42.30'N, water depth 2655 m) on the East Pacific Rise near lat 13°N were analyzed by XRD, ICP-AES, and ICP-MS. Most Fe-oxyhydroxides are amorphous, with a few sphalerite microlites. In comparison with Fe-oxyhydroxides from other fields, the variable ranges in the chemical composition of Fe-oxyhydroxide samples are very narrow; their Fe, Si, and Mn contents were 39.90%, 8.92%, and 1.59%, respectively; they have high Cu (0.88%―1.85%) and Co (65×10?6―704×10?6) contents, and contain Co+Cu+Zn+Ni> 1.01%. The trace-element (As, Co, Ni, Cu, Zn, Ba, Sr) and major-element (Fe, Ca, Al, Mg) contents of these samples are in the range of hydrothermal sulfide from the East Pacific Rise near 13°N, reflecting that this type of Fe-oxyhydroxide constitutes a secondary oxidation product of hydrothermal sulfide. The Fe-oxyhydroxide samples from one dredge station on the East Pacific Rise near 13°N are lower in ΣREE (5.44×10?6―17.01×10?6), with a distinct negative Ce anomaly (0.12 ― 0.28). The Fe-oxyhydroxide samples have similar chondrite-normalized rare-earth-element (REE) patterns to that of seawater, and they are very different from the REE composition characteristics of hydrothermal plume particles and hydrothermal fluids, showing that the REEs of Fe-oxyhydroxide are a major constituent of seawater and that the Fe-oxyhydroxides can become a sink of REE from seawater. The quick settling of hydrothermal plume particles resulted in the lower REE content and higher Mn content of these Fe-oxyhydroxides, which are captured in part of the V and P from seawater by adsorption. The Fe-oxyhydroxides from one dredge station on the East Pacific Rise near 13°N were formed by secondary oxidation in a low temperature, oxygenated environment. In comparison with the elemental (Zn, Cd, Pb, Fe, Co, Cu) average content of hydrothermal sulfide samples from the East Pacific Rise near 13°N, the Zn, Cd, and Pb contents of the Fe-oxyhydroxides are lower, and their Fe, Co, and Cu contents are higher. | ZENG ZhiGang WANG XiaoYuan ZHANG GuoLiang YIN XueBo CHEN DaiGeng WANG XiaoMei | 2008 | Science China Earth Sciences2008，51，2： | 12 |
| 2 | Deep Fractionation of Clinopyroxene in the East Pacific Rise 13°N:Evidence from High MgO MORB and Melt Inclusions显示文摘从东方太平洋的海中央山脉暗岩(MORB ) 升起(EPR ) 13 ° N 为专业和踪迹元素被分析,哪个表演一个连续演变趋势。积极姆戈·艾尔 2 O 3 和否定 MgO Sc 关系表明斜长石和橄榄石的 cotectic 结晶化,它与斜长石和橄榄石斑晶和 clinopyroxene 斑晶的缺席的存在存在。然而, clinopyroxene 的分别被 MgO 和 CaO 的积极关联证明。因此, MORB 样品被相信显示出“ clinopyroxene 悖论”。最高忍受镁的 MORB 样品 E13 3B (MgO =9.52%) 在不同压力与 COMAGMAT 为等压的结晶化被建模。观察 CaO/Al 2 O 3 比率能在压力 >4 ± 1 kbar 仅仅由部分结晶化从 E13 3B 被导出,它要求 clinopyroxene 结晶化并且不与加在岩浆房间的斜长石的橄榄石的 cotectic 结晶化一致(在压力 ∼1 kbar ) 。melt 包括的起始的作文,能代表潜在的父母岩浆,被为陷阱以后的结晶化(PEC ) 改正重建。模仿的结晶化起始融化包括也生产观察 CaO/Al 2 仅仅在 >4 ± 1 kbar, clinopyroxene 在参加结晶化的 O 3 比率。MORB 岩浆在更低的外壳中经历了 clinopyroxene 分别,这被建议,在并且在莫霍转变地区下面。MORB 岩浆在 >4 ± 1 kbar 从 clinopyroxene+plagioclase+olivine 结晶化经历了转变到主要在 <1 kbar 的 olivine+plagioclase 结晶化,它贡献“ clinopyroxene 悖论”的解释。 | ZHANG Guoliang ZENG Zhigang YIN Xuebo WANG Xiaoyuan CHEN Daigeng | 2009 | Acta Geologica Sinica(English Edition)2009，83，2： | 7 |
| 3 | Element enrichment and U-series isotopic characteristics of the hydrothermal sulfides at Jade site in the Okinawa Trough显示文摘The geochemical and U-series isotopic characteristics of hydrothermal sulfide samples from the Jade site (127°04.5′E, 27°15′N, water depth 1300-1450 m) at Jade site in the Okinawa Trough were analyzed. In the hydrothermal sulfide samples bearing sulfate (samples HOK1 and HOK2), the LREEs are relatively enriched. All the hydrothermal sulfide samples except HOK1 belong to Zn-rich hydrothermal sulfide. In comparison with Zn-rich hydrothermal sulfides from other fields, the contents of Zn, Pb, Ag, Cd, Au and Hg are higher, the contents of Fe, Al, Cr, Co, Ni, Sr, Te, Cs, Ti and U lower, and the 210Pb radioactivity ratios and 210Pb/Pb ratios very low. In the hydrothermal sulfide mainly composed of sphalerite, the correlations between rare elements Hf and U, and Hf and Mn as well as that between dispersive elements Ga and Zn, are strongly positive; also the contents of Au and Ag are related to Fe-sulfide, because the low temperature promotes enrichment of Au and Ag. Meanwhile, the positive correlations between Fe and Bi and between Zn and Cd are not affected by the change of mineral assemblage. Based on the 210Pb/Pb ratios of hydrothermal sulfide samples (3.99×10-5-5.42×10?5), their U isotopic composition (238U content 1.15-2.53 ppm, 238U activity 1.07-1.87 dpm/g, 234U activity 1.15-2.09 dpm/g and 234U/238U ratio 1.07-1.14) and their 232Th and 230Th contents are at base level, and the chronological age of hydrothermal sulfide at Jade site in the Okinawa Trough is between 200 and 2000 yr. | ZENG ZhiGangYU ShaoXiong YIN XueBo WANG XiaoYuan ZHANG GuoLiang WANG XiaoMei CHEN DaiGeng | 2009 | Science China Earth Sciences2009，52，7： | 6 |
| 4 | Periodical mixing of MORB magmas near East Pacific Rise 13°N: Evidence from modeling and zoned plagioclase phenocrysts显示文摘Thirty-six basalt samples from near East Pacific Rise 13°N are analyzed for major and trace elements. Different types of zoned plagioclase phenocrysts in basalts are also backscatter imaged, and major element profiles scanned and analyzed for microprobe. Basalts dredged from a restricted area have evolved to different extents (MgO=9.38wt%—6.76wt%). High MgO basalts are modeled for crystalliza-tion to MgO of about 7wt%, and resulted in the Ni contents (≈28 ppm) that are generally lower than that in observed basalts (>60 ppm). It suggests that low MgO basalts may have experienced more intensive magma mixing. High MgO (9.38wt%) basalt is modeled for self-'mixing-crystallization', and the high Ni contents in low MgO basalts can be generated in small scale and periodical self-mixing of new magma (high MgO). 'Mixing-crystallization' processes that low MgO magmas experienced accord with recent 226Ra/230Th disequilibria studies for magma residence time, in which low MgO magmas have experi-enced more circles of 'mixing-crystallization' in relatively longer residence time. Magma mixing is not homogeneous in magma chamber, however, low MgO magmas are closer to stable composition pro-duced by periodical 'mixing-crystallization', which is also an important reason for magma diversity in East Pacific Rise. Zoned plagioclase phenocrysts can be divided into two types: with and without high An# cores, both of which have multiple reversed An# zones, suggesting periodical mixing of their host magmas. Cores of zoned plagioclase in low MgO (7.45wt%) basalt differ significantly with their mantle in An#, but are similar in An# with microlite cores (products of equilibrium crystallization) in high MgO (9.38wt%) basalt, which further shows that plagioclase phenocryst cores in low MgO basalts may have formed in their parental magmas before entering into the magma chamber. | ZHANG GuoLiang ZENG ZhiGang YIN XueBo CHEN DaiGeng WANG XiaoYuan WANG XiaoMei | 2008 | Science China Earth Sciences2008，51，12： | 4 |
| 5 | Magma mixing in upper mantle: Evidence from high Mg~# olivine hosted melt inclusions in MORBs near East Pacific Rise 13°N显示文摘在 MORB 的进化期间,岩浆通常招待的早形成的 high-Mg# 橄榄石斑晶融化包括,它关于岩浆的早阶段的进化记录重要信息。从近的东方太平洋的五件 MORB 样品升起(EPR ) | ZHANG GuoLiang JIANG ShaoQing OUYANG HeGen CHEN DaiGeng YIN XueBo WANG XiaoYuan WANG XiaoMei ZENG ZhiGang | 2010 | Chinese Science Bulletin2010，55，16： | 2 |
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