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| 1 | Preparation and anisotropic properties of textured structural ceramics: A review显示文摘Ceramics are usually composed of randomly oriented grains and intergranular phases, so their properties are the statistical average along each direction and show isotropy corresponding to the uniform microstructures. Some methods have been developed to achieve directional grain arrangement and preferred orientation growth during ceramic preparation, and then textured ceramics with anisotropic properties are obtained. Texture microstructures give particular properties to ceramics along specific directions, which can effectively expand their application fields. In this review, typical texturing techniques suitable for ceramic materials, such as hot working, magnetic alignment, and templated grain growth(TGG), are discussed. Several typical textured structural ceramics including α-Al2O3 and related nacre bioinspired ceramics, Si3N4 and SiAlON, h-BN, MB2 matrix ultra-high temperature ceramics, MAX phases and their anisotropic properties are presented. | Zhuo ZHANG Xiaoming DUAN Baofu QIU Zhihua YANG Delong CAI Peigang HE Dechang JIA Yu ZHOU | 2019 | Journal of Advanced Ceramics2019，8，3： | 14 |
| 2 | Necroptosis of tumor cells leads to tumor necrosis and promotes tumor metastasis显示文摘 | Delong Jiao Zhenyu Cai Swati Choksi Dan Ma Moran Choe Hyung-Joon Kwon Jin Young Balk Brian G. Rowan Chengyu Liu Zheng-gang Liu | 2018 | Cell Research2018，28，8： | 9 |
| 3 | NOD2 和 TLR2 ligands 由在遗传性过敏症的像皮炎的皮肤发炎与真皮的成纤维细胞交往触发 basophils 和嗜曙红血球的激活显示文摘有遗传性过敏症的皮炎(广告) 的病人的皮肤由葡萄球菌 aureus 为殖民有唯一的倾向(S。aureus ) ,它贡献发炎和广告的冷酷的预后。尽管位于 S 下面的机制。不清楚的、最近的研究在在 S 调整煽动性的回答为模式识别受体发现了一个枢轴的角色的广告遗体的导致 aureus 的恶化。aureus 感染。在现在的学习,我们使用了像广告的皮肤发炎的一个典型老鼠模型并且发现了那 S。联系 aureus 的核苷酸绑定 oligomerization 包含域的蛋白质 2 (NOD2 ) 并且像使用费的受体 2 (TLR2 ) ligands 加重了像广告的症状,它进一步被败坏由在里面 basophils 和嗜曙红血球的 vivo 扩大。随后的组织学的分析表明真皮的成纤维细胞在像广告的皮肤损害是弥漫的。有 basophils 和嗜曙红血球的人的真皮的成纤维细胞的合作文化在真皮的成纤维细胞上导致了对 NOD2/TLR2 ligands 和细胞间的粘附 molecule-1 的提高的表示的精力旺盛的 cytokine/chemokine 回答。Basophils 和嗜曙红血球为在合作文化的广告相关的 cytokine/chemokine 表示主要负责。直接细胞间的接触为在 basophils 和真皮的成纤维细胞之间的串音是必要的,当可溶的调停人是足够的调停时嗜曙红血球成纤维细胞相互作用。而且,细胞内部的 p38 激活 mitogen 的蛋白质 kinase,细胞外的调整信号的 kinase,和表明小径的原子 factor-kappa B 为在广告相关的发炎的 basophils,嗜曙红血球,和真皮的成纤维细胞的 NOD2/TLR2 调停 ligand 的激活是必要的。这研究通过天生的有免疫力的房间的激活提供广告的 NOD2/TLR2-mediated 恶化的证据因此使一条新奇机械学的小径由清楚些哪个 S。aureus 贡献广告的 pathophysiology。 | Delong Jiao Chun-Kwok Wong Huai-Na Qiu Jie Dong Zhe Cai Man Chu Kam-Lun Hon Miranda Sin-Man Tsang Christopher Wai-Kei Lam | 2016 | Cellular & Molecular Immunology2016，13，4： | 8 |
| 4 | Simultaneous incorporation of PTH(1-34) and nano-hydroxyapatite into Chitosan/Alginate Hydrogels for efficient bone regeneration显示文摘Tissue regeneration based on the utilization of artificial soft materials is considered a promising treatment for bone-related diseases.Here,we report cranial bone regeneration promoted by hydrogels that contain parathyroid hormone(PTH)peptide PTH(1-34)and nano-hydroxyapatite(nHAP).A combination of the positively charged natural polymer chitosan(CS)and negatively charged sodium alginate led to the formation of hydrogels with porous structures,as shown by scanning electron microscopy.Rheological characterizations revealed that the mechanical properties of the hydrogels were almost maintained upon the addition of nHAP and PTH(1-34).In vitro experiments showed that the hydrogel containing nHAP and PTH(1-34)exhibited strong biocompatibility and facilitated osteogenic differentiation of rat bone marrow mesenchymal stem cells(rBMSCs)via the Notch signaling pathway,as shown by the upregulated expression of osteogenic-related proteins.We found that increasing the content of PTH(1-34)in the hydrogels resulted in enhanced osteogenic differentiation of BMSCs.Implantation of the complex hydrogel into a rat cranial defect model led to efficient bone regeneration compared to the rats treated with the hydrogel alone or with nHAP,indicating the simultaneous therapeutic effect of nHAP and PTH during the treatment process.Both the in vitro and in vivo results demonstrated that simultaneously incorporating nHAP and PTH into hydrogels shows promise for bone regeneration,suggesting a new strategy for tissue engineering and regeneration in the future. | Zhiyuan Zou Le Wang Zhifei Zhou Qing Sun Delong Liu Yan Chen Hao Hu Yu Cai Sixiong Lin Zhengran Yu Bizhi Tan Wei Guo Zemin Ling Xuenong Zou | 2021 | Bioactive Materials2021，6，6： | 7 |
| 5 | Microstructural evolution of h-BN matrix composite ceramics with La-Al-Si-O glass phase during hot-pressed sintering显示文摘BN/La-Al-Si-O composite ceramics were fabricated by hot-pressed sintering using hexagonal boron nitride(h-BN),lanthanum oxide(La_(2)O_(3)),aluminia(Al_(2)O_(3)),and amorphous silica(SiO_(2))as the raw materials.The effects of sintering temperature on microstructural evolution,bulk density,apparent porosity,and mechanical properties of the h-BN composite ceramics were investigated.The results indicated that La-Al-Si-O liquid phase was formed during sintering process,which provided an environment for the growth of h-BN grains.With increasing sintering temperature,the cristobalite phase precipitation and h-BN grain growth occurred at the same time,which had a significant influence on the densification and mechanical properties of h-BN composite ceramics.The best mechanical properties of BN/La-Al-Si-O composite ceramics were obtained under the sintering temperature of 1700℃.The elastic modulus,flexural strength,and fracture toughness were 80.5 GPa,266.4 MPa,and 3.25 MPa·m^(1/2),respectively. | Baofu QIU Xiaoming DUAN Zhuo ZHANG Chen ZHAO Bo NIU Peigang HE Delong CAI Lei CHEN Zhihua YANG Yujin WANG Dechang JIA Yu ZHOU | 2021 | Journal of Advanced Ceramics2021，10，3： | 2 |
| 6 | Dietary compounds that induce cancer priventive phase 2 enzymes activate apoptosis at comparable doses in HT-29 colon carcinoma cells 显示文摘 | Kirlin WG Cai J Delong MJ | 1999 | J Nutr1999，129，： | 1 |
| 7 | Microstructural evolution and mechanical properties of in situ nano Ta_(4)HfC_(5) reinforced SiBCN composite ceramics显示文摘The in situ nano Ta_(4)HfC_(5) reinforced SiBCN-Ta_(4)HfC_(5) composite ceramics were prepared by a combination of two-step mechanical alloying and reactive hot-pressing sintering.The microstructural evolution and mechanical properties of the resulting SiBCN-Ta_(4)HfC_(5) were studied.After the first-step milling of 30 h,the raw materials of TaC and HfC underwent crushing,cold sintering,and short-range interdiffusion to finally obtain the high pure nano Ta_(4)HfC_(5).A hybrid structure of amorphous SiBCN and nano Ta_(4)HfC_(5) was obtained by adopting a second-step ball-milling.After reactive hot-pressing sintering,amorphous SiBCN has crystallized to 3C-SiC,6H-SiC,and turbostratic BN(C)phases and Ta_(4)HfC_(5) retained the form of the nanostructure.With the in situ generations of 2.5 wt% Ta_(4)HfC_(5),Ta_(4)HfC_(5) is preferentially distributed within the turbostratic BN(C);however,as Ta_(4)HfC_(5) content further raised to 10 wt%,it mainly distributed in the grain-boundary of BN(C) and SiC.The introduction of Ta_(4)HfC_(5) nanocrystals can effectively improve the flexural strength and fracture toughness of SiBCN ceramics,reaching to 344.1 MPa and 4.52 MPa·m^(1/2),respectively.This work has solved the problems of uneven distribution of ultra-high temperature phases in the ceramic matrix,which is beneficial to the real applications of SiBCN ceramics. | Bingzhu WANG Daxin LI Zhihua YANG Dechang JIA Jingyi GUAN Hao PENG Delong CAI Peigang HE Xiaoming DUAN Yu ZHOU Tao ZHANG Chenguang GAO | 2020 | Journal of Advanced Ceramics2020，9，6： | 0 |
| 8 | Boundless Prospect of Silicon Fertilizers显示文摘Silicon fertilizers are series of mineral fertil-izers mainly containing calcium silicate orsodium silicate and other silicates.In the1970s some people thought that soil in north-ern China did not | By Cai Delong,Henan Silicon Fertilizer R & D Center | 2008 | China Chemical Reporter2008，，32： | 0 |
| 9 | Texture and anisotropy of hot-pressed h-BN matrix composite ceramics with in situ formed YAG显示文摘Textured hexagonal boron nitride(h-BN)matrix composite ceramics were prepared by hotpressing using different contents of 3Y_(2)O_(3)–5Al_(2)O_(3)(molar ratio of 3:5)as the sintering additive.During hot-pressing,the liquid Y_(3)Al_(5)O_(12)(YAG)phase showing good wettability to h-BN grains was in situ formed through the reaction between Y_(2)O_(3) and Al_(2)O_(3),and a coherent relationship between h-BN and YAG was observed with[010]_(h-BN)//[111]_(YAG) and(002)_(h-BN)//(321)_(YAG).In the YAG liquid phase environment formed during hot-pressing,plate-like h-BN grains were rotated under the uniaxial sintering pressure and preferentially oriented with their basal surfaces perpendicular to the sintering pressure direction,forming textured microstructures with the c-axis of h-BN grains oriented parallel to the sintering pressure direction,which give these composite ceramics anisotropy in their mechanical and thermal properties.The highest texture degree was found in the specimen with 30 wt%YAG,which also possesses the highest anisotropy degree in thermal conductivity.The aggregation of YAG phase was observed in the specimen with 40 wt%YAG,which resulted in the buckling of h-BN plates and significantly reduced the texture degree. | Zhuo ZHANG Xiaoming DUAN Zhuo TIAN Yujin WANG Lan WANG Lei CHEN Baofu QIU Delong CAI Peigang HE Dechang JIA Yu ZHOU | 2022 | Journal of Advanced Ceramics2022，11，4： | 0 |
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