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1篇 您的检索式:作者名="Deyang Ning"
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1Molten salt synthesis of Z-scheme CeO_(2)/C_(3)N_(4) photocatalysts with excellent properties for removal of organic pollutants:Characterization,kinetics and mechanisms显示文摘In this work,we firstly synthesized a CeO_(2)/C_(3)N_(4) photocatalyst with Z-scheme heterojunction by a facile LiC-KCI molten salt method.The synthesized catalyst has an excellent quality for removing organic pollution of dyes and antibiotics in wastewater.As an example,the CeCN-1:5 prepared with a mass ratio of Ce_(2)(CO_(3))_(3)·xH_(2)O:C_(3)H_(3)N_(6)=1:5 exhibits a methylene blue(MB)removal capacity of 100%within 90 min and tetracycline(TC)removal capacity of 94.6%.After 4 cycles,the CeCN-1:5 keeps a removal efficiency of nearly 100%in 150 min for MB and 85.7%for TC.The kinetics study reveals that the MB removal process with the CeCN-1:5 fits the modified Elovich model with strong adsorption while TC removal fits the first-order model.The large surface area(238 m^(2)/g)and negative zeta potential(-39.3 mV)of CeCN-1:5 contribute to superior adsorption capacity to MB.However,the adsorption of TC is restricted due to the positive surface/pore potential in acidic solution.CeCN-1:5has combined Z-scheme heterojunction and exhibits a low recombination rate of electrons(e^(-))/holes(h^(+))and the photo-generated active radicals of·OH/·O_(2)^(-)that promotes the photocatalytic performance.This novel CeO_(2)/C_(3)N_(4) photocatalyst with an excellent photocatalysis removal activity has an enormous potential for photocatalytic applications.Deyang Ning Junqi Li Yuanpei Lan Hong Yong Sohn Jian Yang Chaoyi Chen Zhiyao Chu Xisong Mao 2023Journal of Rare Earths2023,41,8:0
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