| 7 | Photocatalytic generation of 1,4-disubstituted 1,2,3-triazoles under metal, oxidant and azide-free conditions显示文摘Available online A mild and efficient photocatalytic-induced radical method has been developed for[4+1]cycloaddition reaction of 1,4-disubstituted 1,2,3-triazoles with N-tosylhydrazides and primary amines.The reaction is catalyzed by 20 mol%of I2 under metal,azide and oxidant-free conditions.The method is based upon the photocatalytic generation of allyl-type radicals,followed by the iodine-catalyzed production of azoalkenes,which react rapidly with various anilines. | Changhong Liu Dilshat Abdukerem Wenli Zhu Kun Xia Zechuan Mao Ablimit Abdukader | 2024 | Green Synthesis and Catalysis2024，5，1： | 0 |
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