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1Study on the Metallogenetism of Sub-mantle Plume and Mantle Branches in the Gold Mineralization Concentration Area of Northwest Jiaodong Peninsula显示文摘The northwest of Jiaodong peninsula is characterized by its greatest gold concentration area, enormous gold reserves and limited time interval(115±5Ma) of gold mineralization in China. Studies show that the east area of north China began its mantle plume evolution since the Yanshanian movement, and the Laiyang sub-mantle plume and its surrounding mantle branches such as those in Guojiadian, Aishan and Panshidian were formed in the mineralization concentration area of northwestern Jiaodong peninsula. With the development of mantle plume → sub-mantle plume → mantle branch → favorable expending structures, the deep-derived hydrothermal fluid moved up to the favorable places, such as brittle-ductile or ductile-brittle shearing zones, the internal and external contact zones of intrusions, dense fracturing zones and the contact zones between dikes and countryrocks, and concentrated into deposits. Then the gold mineralization concentration zones that are centralized on mantle branches were formed. This study takes Guojiadian mantle branch as an example to discuss their metallogenetism and conclude the metallogenetic mode.NIU Shuyin CHENG Guangsuo ZHANG Jianzhen SUN Aiqun MA Baojun ZHANG Fuxiang WANG Baode XU Meng WU Jichun ZHAO Rongxin WANG Shanfei 2014Acta Geologica Sinica(English Edition)2014,88,5:4
2Opposed multi-burner gasification technology:Recent process of fundamental research and industrial application显示文摘Opposed multi-burner(OMB)gasification technology is the first large-scale gasification technology developed in China with completely independent intellectual property rights.It has been widely used around the world,involving synthetic ammonia,methanol,ethylene glycol,coal liquefaction,hydrogen production and other fields.This paper summarizes the research and development process of OMB gasification technology from the perspective of the cold model experiment and process simulation,pilotscale study and industrial demonstration.The latest progress of fundamental research in nozzle atomization and dispersion,mixing enhancement of impinging flow,multiscale reaction of different carbonaceous feedstocks,spectral characteristic of impinging flame and particle characteristics inside gasifier,and comprehensive gasification model are reviewed.The latest industrial application progress of ultralarge-scale OMB gasifier and radiant syngas cooler(RSC)combined with quenching chamber OMB gasifier are introduced,and the prospects for the future technical development are proposed as well.Fuchen Wang Guangsuo Yu Haifeng Liu Weifeng Li Qinghua Guo Jianliang Xu Yan Gong Hui Zhao Haifeng Lu Zhongjie Shen 2021Chinese Journal of Chemical Engineering2021,34,7:2
3Study on co-pyrolysis characteristics of rice straw and Shenfu bituminous coal blends in a fixed bed reactor显示文摘Shuaidan Li Xueli Chen Aibin Liu Li Wang Guangsuo Yu 2014Bioresource Technology2014,,:1
4Numerical and experimental investigations on gas-particle flow in the Opposed Multi-burner Gasifier 显示文摘Jianjun Ni Qinfeng Liang Zhijie Zhou Zhenghua Dai Guangsuo Yu 2009Energy Conversion and Management2009,50,12:1
5Experimental studying and stochastic modeling of residence time distribu- tion in jet-entrained gasifier 显示文摘Yu Guangsuo Zhou Zhijie Qu Qiang 2002Chemical Engineering and Processing: Process Intensification2002,41,7:1
6Exploring influence of MgO/CaO on crystallization characteristics to understand fluidity of synthetic coal slags显示文摘The crystallization has significant influence on fluidity of slag and slag discharge of entrained-flow-bed(EFB) gasifier. The crystallization characteristics and fluidity of five synthetic slags with different MgO/CaO ratios prepared on the basis of the range of oxide contents of Zhundong coal ash were investigated in this study. The results show that with the MgO/CaO ratio increase, the initial crystallization temperature increases, and the main temperature range of crystallization ratio growth moves to higher temperature range gradually which causes Tp25(Tp25is the temperature corresponding to the viscosity of 25 Pa·s)to increase. Mg-rich crystals are formed preferentially than Ca-rich crystals when adding the same amount of MgO and CaO during cooling. The effective slagging operating temperature range decrease from 217 ℃ for the slag with a 0:4 MgO/CaO ratio to 44 ℃ for the slag with a 4:0 MgO/CaO ratio with the MgO/CaO ratio increase. The slags with 2:2 and 1:3 MgO/CaO ratios show similar effective slagging operating temperature range, Tp25and the temperature corresponding to the viscosity of 2 Pa·s.However, compared with the slag with a 1:3 MgO/CaO ratio, the crystallization ratio and rate of slag with a 2:2 MgO/CaO ratio are lower within lower temperature range(1300–1200 ℃), causing its lower critical viscosity temperature and wider actual operating temperature range. Of the five slags, the widest effective slagging operating temperature range and the lowest Tp25of the slag with a 0:4 MgO/CaO ratio due to its low crystallization ratio, and wider actual operating temperature range of the slag with a 2:2 MgO/CaO ratio make the two slags suitable for slag discharge of EFB gasifier.Meng Li Jianliang Xu Huixia Xiao Xia Liu Guangsuo Yu Xueli Chen 2023Chinese Journal of Chemical Engineering2023,53,1:1
7Molten slag flow and phase transformation behaviors in a slagging en-trained-flow coal gasifier显示文摘NI Jianjun ZHOU Zhijie YU Guangsuo 2010Industrial&Engineering Chemistry Research2010,49,12:1
8Numeri-cal modeling for non-steady thermal stress analysis of slag layer in a membrane wall entrained-flow gasifier显示文摘LIN Weining LIANG Qingfeng YU Guangsuo 2011Fu-el2011,90,7:1
9The investigations of temperature distributions in an op- posed multi-burner gasifier显示文摘Yu Guangsuo Yan Zhuoyong Liang Qinfeng 2011Energy Conversion and Management2011,52,5:1
10Residence time distribution and modeling of the liquid phase in an impinging stream reactor显示文摘Based on some experimental investigations of liquid phase residence time distribution(RTD)in an impinging stream reactor,a two-dimensional plug-flow dispersion model for predicting the liquid phase RTD in the reactor was proposed.The calculation results of the model can be in good agreement with the experimental RTD under different operating conditions.The axial liquid dispersion coefficient increases monotonously with the increasing liquid flux,but is almost independent of gas flux.As the liquid flux and the gas flux increase,the liquid dispersion coefficient of center-to-wall decreases.The axial liquid dispersion coefficient is much larger than that of center-to-wall,which indicates that the liquid RTD is dominated mainly by axial liquid dispersion in the impinging stream reactor.Xingjun WANG Xianhui HU Lishun HU Guangsuo YU Fuchen WANG 2010Frontiers of Chemical Science and Engineering2010,4,3:1
11Slag properties of blending coal in an industrial OMB coal water slurry entrained-flow gasifier显示文摘Qinghua Guo Zhijie Zhou Fuchen Wang Guangsuo Yu 2014Energy Conversion and Management2014,,:1
12Effects of alkaline metal on coal gasification at pyrolysis and gasification phases显示文摘Xu Shenqi Zhou Zhijie Xiong Jie Yu Guangsuo Wang Fuchen 2011Fuel2011,,5:1
13Effects of alkaline metal on coal gasification at pyrolysis and gasification phases 显示文摘Xu Shenqi Zhou Zhijie Xiong Jie Yu Guangsuo Wang Fuchen 2011Fuel2011,90,:1
14The physicochemical properties of different biomass ashes at different ashing temperature显示文摘Ruirui Xiao Xueli Chen Fuchen Wang Guangsuo Yu 2010Renewable Energy2010,,1:1
15Molten slag flow and phase transformation behaviors in a slagging entrained-flow coal gasifier显示文摘NI Jianjun ZHOU Zhijie YU Guangsuo 2010Industrial and Engineer- ing Chemistry Research2010,49,12:1
16In-situ study on structure evolution and gasification reactivity of biomass char with K and Ca catalysts at carbon dioxide atmosphere显示文摘The structural evolution and gasification reactivity of biochar prepared from the pyrolysis of wheat straw were investigated by in-situ Raman spectroscopy and thermogravimetric analysis.The Raman spectra consisted of a combination of four Lorentzian bands(D1,D2,D4,G)and one Gaussian band(D3)in the first-order region.The experimental results showed that the addition of catalysts or the presence of ash could improve the CO_(2) gasification reactivity of biochar and result in a larger ID1/IG ratio and a lower IG/IALL ratio,meaning that the carbon structure was less ordered,and there were also more active sites such as amorphous carbon and cross-linked structures;Ca-based catalysts and K-based catalysts changed the evolution of biochar structure in a different way in CO_(2) atmosphere,the ID3/ID1 of Ca-based biochar was close to the value of non-catalyst biochar and decreased slowly,indicating that the Ca-based catalysts can stabilize the aromatic rings,while the IG/IALL of K-based biochar decreases significantly and the ID3/ID1 increased significantly,indicating the increase of carbon structure defects and the cracking of large aromatic rings in bio-char into small ones;a scheme of K and Ca reaction with biochar in CO_(2) gasification process was proposed.Xingjun Wang Qian Chen Huaili Zhu Xueli Chen Guangsuo Yu 2023Carbon Resources Conversion2023,6,1:0
17Effect of carbon dioxide on oxy-fuel combustion of hydrogen sulfide:An experimental and kinetic modeling显示文摘CO_(2) is an important component in the acid gas and it is necessary to study the effect of CO_(2) presence on the oxy-fuel combustion of H_(2)S with particular focus on the formation of carbonyl sulfide(COS).The oxyfuel combustion of acid gas was conducted in a coaxial jet double channel burner.The distribution of flame temperature and products under stoichiometric condition along axial(R=0.0)and radial at about 3.0 mm(R=0.75)were analyzed,respectively.The Chemkin-Pro software was used to analyze the rate of production(ROP)for gas products and the reaction pathway of acid gas combustion.Both experimental and simulation results showed that acid gas combustion experienced the H2S chemical decomposition,H_(2)S oxidation and accompanied by H_(2) oxidation.The CO_(2) presence reduced the peak flame temperature and triggered the formation of COS in the flame area.COS formation at R=0.0 was mainly through the reaction of CO_(2) and CO with sulfur species,whereas at R=0.75 it was through the reaction of CO with sulfur species.The ROP results indicated that H_(2) was mainly from H_(2)O decomposition in the H_(2)S oxidation stage,and COS was formed by the reaction of CO_(2) with H_(2)S.ROP and other detailed analysis further revealed the role of H,OH and SH radicals in each stage of H_(2)S conversion.This study revealed the COS formation mechanisms with CO_(2) presence in the oxy-fuel combustion of H_(2)S and could offer important insights for pollutant control.Xun Tao Fan Zhou Xinlei Yu Songling Guo Yunfei Gao Lu Ding Guangsuo Yu Zhenghua Dai Fuchen Wang 2023Chinese Journal of Chemical Engineering2023,59,7:0
18Crystallization and viscosity-temperature characteristics during co-gasification of industrial sludge and coal显示文摘Co-gasification of industrial sludge(IS)and coal was an effective approach to achieve harmless and sustainable utilization of IS.The long-term and stable operation of a co-gasification largely depends on fluidity of coal-ash slag.Herein,the effects of IS addition on the crystallization and viscosity of Shuangmazao(SMZ)coal were investigated by means of high temperature stage coupled with an optical microscope(HTSOM),a scanning electron microscopy coupled with an energy dispersive Xray spectrometry(SEM-EDS),X-ray diffraction(XRD),a Fourier transform infrared spectrometer(FTIR),and FactSage software.The results showed that when the proportion of IS was less than 60%,with the addition of IS,the slag existed in an amorphous form.This was due to the high content of SiO_(2) and Al_(2)O_(3) in SMZ ash and blended ash,which had a high glass-forming ability(GFA).The slag formed at a high temperature had a higher polymerization degree and viscosity,which led to a decrease in the migration ability between ions,and ultimately made the slag difficult to crystallize during the cooling.When the proportion of IS was higher than 60%,the addition of IS increased the CaO and FeO content in the system.As network modifiers,CaO and FeO could provide O^(2−)at a high temperature,which reacted with silicate network structure and continuously destroyed the complexity of network structure,thus reducing the polymerization degree and viscosity of slag.At this time,the migration ability between ions was enhanced,and needle-shaped/rod-shaped crystals were precipitated during the cooling process.Finally,the viscosity calculated by simulation and Einstein-Roscoe empirical formula demonstrated that the addition of IS could significantly improve the fluidity of coal ash and meet the requirements of the liquid slag-tapping gasifier.The purpose of this work was to provide theoretical support for slag flow mechanisms during the gasifier slagging-tapping process and the resource treatment of industrial solid waste.Linmin ZHANG Bin LIU Juntao WEI Xudong SONG Yonghui BAI Jiaofei WANG Ying ZHOU Huijun YANG Guangsuo YU 2022Frontiers in Energy2022,16,6:0
19Effect of slag composition on corrosion resistance of high chromia refractory bricks for industrial entrained-flow gasifier显示文摘The slag composition corresponding to different coals varies significantly,which directly affects the operation of industrial entrained-flow gasifier and the service life of refractory bricks.In this study,the corrosion resistance of several typical coal slags for gasification on high chromia refractory bricks was comparatively investigated by static laboratory crucible tests and thermodynamic simulations.The results demonstrated that the corrosion degree of high chromia refractory bricks by different coal slags was high-Ca/Na slag>high-Fe slag>high-Si/Al slag.The surface structure of the refractory was relatively flat after corrosion by high-Si/Al slag,and the primary corrosion reaction was the partial dissolution of the matrix by the slag.High-Fe slag was prone to the precipitation of iron phases as well as the formation of(Mg,Fe)(Al,Cr)_(2)O_(4)composite spinel layer at the slag/refractory interface.The high-Ca/Na slag was susceptible to react with the refractory to yield a low melting point phase,which led to the destruction of the matrix structure of the refractory and an isolated distribution of particles.In addition,the monoclinic ZrO_(2) in the refractory reacted with CaO in the slag to formed calcium zirconate,which loosened its phase toughening effect,was the primary factor that aggravated the refractory corrosion.Jinghong Gao Weiguang Su Xudong Song Peng Lv Jun Yang Guangsuo Yu 2023Chinese Journal of Chemical Engineering2023,62,10:0
20Special issue on coal gasification: science and technology显示文摘Coal,one of the fossil fuels which is burned for heat,contributes a quarter of the world’s primary energy and two-fifths of its electricity.According to the World Energy Model(WEM)provided by the International Energy Agency(IEA),the total primary energy demand from coal reached 3750 Mtoe in 2017,and its growth rate will decrease a lot in the future 10–20 years.Nevertheless,coal will remain as the main primary energy in the next few decades.Lu Ding Juntao Wei Guangsuo Yu 2020International Journal of Coal Science & Technology2020,7,3:0
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