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| 1 | A new Eu-MOF for ratiometrically fluorescent detection toward quinolone antibiotics and selective detection toward tetracycline antibiotics显示文摘Development of new self-calibrating fluorescent sensing methods has been a popular research field with the aim of protecting the human health and environment sustainability. In this work, a novel Eu-based metal organic framework(MOF) Eu(2,6-NDC)(COO)(BUC-88) was developed by employing 2,6-NDC(2,6-naphthalenedicarboxylic acid) as bridging ligands. BUC-88 performed different sensing process toward quinolone antibiotics and tetracyclines antibiotics in terms of fluorescence intensity and color. BUC-88exhibited excellent selectivity and sensitivity detection property toward enrofloxacin(ENR), norfloxacin(NOR) and ciprofloxacin(CIP) over other Pharmaceutical and Personal Care Products(PPCPs), accomplishing the detection limit of 0.12 μmol/L, 0.52 μmol/L, 0.75 μmol/L, respectively. Notably, BUC-88 acted as an excellent fluorescence sensor for tetracyclines antibiotics with fast response time(less than 1 s), high selectivity and sensitivity(LODs = 0.08 μmol/L). The fluorescent detection method was successfully used for visual and ultrasensitive detection of ENR, NOR, CIP and tetracycline hydrochloride(TC) in lake water with satisfied recovery from 99.75% to 102.30%. Finally, the photoinduced electron transfer and the competitive absorption of ultraviolet light are the main mechanisms for sensitive detection toward quinolone antibiotics and tetracyclines antibiotics. | Chao-Yang Wang Chong-Chen Wang Xiu-Wu Zhang Xue-Ying Ren Baoyi Yu Peng Wang Zi-Xuan Zhao Huifen Fu | 2022 | Chinese Chemical Letters2022,33,3: | 7 |
| 2 | Ternary Ag/Ag3PO_(4)/MIL-125-NH2 Z-scheme heterojunction for boosted photocatalytic Cr(Ⅵ)cleanup under visible light显示文摘The binary Ag3 P04/MIL-125-NH2(AMN-X)composites were synthesized through ion exchange-solution method,and the ternary Ag/Ag3 PO_(4)/MIL-125-NH2(AAMN-X)Z-scheme heterojunctions were prepared via the photo chemical reduction deposition strategy.The photocatalytic hexavalent chromium(Cr(VI))sequestration over AMN-X and AAMN-X were investigated under visible light.AAMN-120 accomplished superior reduction performance due to that Ag nanoparticles(NPs)act as electrons transfer bridge to enhance the separation efficiency of photogenerated e-h+pairs,in which the reaction rates(k.value)were 2.77 and 124.2 fold higher than those of individual MIL-125-NH2 and Ag3 PO_(4),respectively.The influences of different pH values,small organic acids and coexisting ions on the photocatalytic perfo rmance of AAMN-120 were also investigated.In addition,the AAMN-120 heterojunction expressed great reusability and stability in cycling experiments.The mechanism of photocatalytic Cr(VI)was investigated and verified through photoluminescence(PL),electrochemistry,electron spin resonance(ESR),active species capture,and Pt element deposition experiments. | Yun-Cai Zhou Peng Wang Huifen Fu Chen Zhao Chong-Chen Wang | 2020 | Chinese Chemical Letters2020,31,10: | 3 |
| 3 | MOFs for water purification显示文摘Metal-organic frameworks (MOFs),as emerging porous crystalline materials,were constructed from metal ions or clusters as nodes and organic ligands as linkers.Due to the superior features like diverse structure,abundant functional groups,tunable pore channels,large specific surface area and so on,MOFs have received increasing attentions in various fields like gas separation&storage,catalysis/photocatalysis,adsorption,sensor,electrochemistry as well as biochemistry. | Huifen Fu Chong-Chen Wang Wen Liu | 2022 | Chinese Chemical Letters2022,33,4: | 2 |
| 4 | <ce:link locator='fx1'/> Increased Regulatory T Cells Correlate With CD8 T-Cell Impairment and Poor Survival in Hepatocellular Carcinoma Patients显示文摘 | Junliang Fu Dongping Xu Zhenwen Liu Ming Shi Ping Zhao Baoyun Fu Zheng Zhang Huiyin Yang Hui Zhang Chunbao Zhou Jinxia Yao Lei Jin Huifen Wang Yongping Yang Yang-Xing Fu Fu-Sheng Wang | 2007 | Gastroenterology2007,,7: | 1 |
| 5 | <ce:link locator='fx1'/> Increased Regulatory T Cells Correlate With CD8 T-Cell Impairment and Poor Survival in Hepatocellular Carcinoma Patients显示文摘 | Junliang Fu Dongping Xu Zhenwen Liu Ming Shi Ping Zhao Baoyun Fu Zheng Zhang Huiyin Yang Hui Zhang Chunbao Zhou Jinxia Yao Lei Jin Huifen Wang Yongping Yang Yang-Xing Fu Fu-Sheng Wang | 2007 | Gastroenterology2007,,7: | 1 |
| 6 | <ce:link locator='fx1'/> Increased Regulatory T Cells Correlate With CD8 T-Cell Impairment and Poor Survival in Hepatocellular Carcinoma Patients显示文摘 | Junliang Fu Dongping Xu Zhenwen Liu Ming Shi Ping Zhao Baoyun Fu Zheng Zhang Huiyin Yang Hui Zhang Chunbao Zhou Jinxia Yao Lei Jin Huifen Wang Yongping Yang Yang-Xing Fu Fu-Sheng Wang | 2007 | Gastroenterology2007,,7: | 1 |
| 7 | <ce:link locator='fx1'/> Increased Regulatory T Cells Correlate With CD8 T-Cell Impairment and Poor Survival in Hepatocellular Carcinoma Patients显示文摘 | Junliang Fu Dongping Xu Zhenwen Liu Ming Shi Ping Zhao Baoyun Fu Zheng Zhang Huiyin Yang Hui Zhang Chunbao Zhou Jinxia Yao Lei Jin Huifen Wang Yongping Yang Yang-Xing Fu Fu-Sheng Wang | 2007 | Gastroenterology2007,,7: | 1 |
| 8 | <ce:link locator='fx1'/> Increased Regulatory T Cells Correlate With CD8 T-Cell Impairment and Poor Survival in Hepatocellular Carcinoma Patients显示文摘 | Junliang Fu Dongping Xu Zhenwen Liu Ming Shi Ping Zhao Baoyun Fu Zheng Zhang Huiyin Yang Hui Zhang Chunbao Zhou Jinxia Yao Lei Jin Huifen Wang Yongping Yang Yang-Xing Fu Fu-Sheng Wang | 2007 | Gastroenterology2007,,7: | 1 |
| 9 | Increased Regulatory T Cells Correlate With CD8 T-Cell Impairment and Poor Survival in Hepatocellular Carcinoma Patients显示文摘 | Junliang Fu Dongping Xu Zhenwen Liu Ming Shi Ping Zhao Baoyun Fu Zheng Zhang Huiyin Yang Hui Zhang Chunbao Zhou Jinxia Yao Lei Jin Huifen Wang Yongping Yang Yang-Xing Fu Fu-Sheng Wang | 2007 | Gastroenterology2007,,: | 1 |
| 10 | Anodic treatment of acrylic fiber manufacturing wastewater with boron-doped diamond electrode: A statistical approach显示文摘 | Chunyong Zhang Jiale Wang Huifen Zhou Degang Fu Zhongze Gu | 2010 | Chemical Engineering Journal2010,,1: | 1 |
| 11 | Enhanced ethanol sensing performance of N-doped ZnO derived from ZIF-8显示文摘Metal oxides derived from metal-organic framework(MOF) have attracted considerable attention due to its excellent performance and unique structure. Doping is considered as an effective method to improve gas-sensing performance. However, nonmetal doped metal oxides derived from MOF as gas-sensing materials have not been reported. Within this work, N atoms were successfully doped into the lattice of ZnO nanoparticles using ZIF-8 as a self-sacrificial template through a thermal treatment process with the assistant of urea. The obtained N-ZnO exhibited competitive ethanol-sensing performance, in which the response value of N-ZnO-5 to 100 ppm ethanol reached 115 at 190 ℃ with a satisfactory selectivity. It was found that the N-doping in ZnO facilitated the formation of oxygen vacancy that promoted the generation of adsorbed oxygen species to achieve the enhanced gas-sensing performance. Besides, the larger specific surface area resulting from the size reduction during the urea-assisted pyrolysis process can also be responsible for the improving of the ethanol-sensing performance. | Huifen Fu Ziyue Feng Shan-Shan Liu Peng Wang Chen Zhao Chong-Chen Wang | 2023 | Chinese Chemical Letters2023,34,2: | 0 |
| 12 | Evaluation for Bone Regeneration Mierospheres显示文摘 | XU Fei YIN Miao DING Huifen SONG Fangfang FU Dongjie ZHANG Jiayin WANG Jiawei | 2014 | Journal of Wuhan University of Technology(Materials Science)2014,29,2: | 0 |