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| 1 | 思林水库荧光溶解性有机质的特征、来源及其转化动力学显示文摘利用三维荧光光谱(EEM)结合平行因子分析(PARAFAC),研究了思林水库冬季(1月)、春季(4月)、夏季(6月)和秋季(10月)上游入库水体、库区表层水(0 m)、库区深层水(20 m)、出库水体的荧光溶解性有机质(FDOM)不同组分的特征、来源及其转化动力学.结果表明,思林水库的溶解性有机质由3种荧光组分组成,分别是:陆源类腐殖质(C类,C1)、浮游植物源的微生物类腐殖质(M类,C2)和浮游植物源的类蛋白或类色氨酸或类酪氨酸(C3).其中陆源类腐殖质的荧光强度随着入库水、库区表层水、库区深层水和出库水逐渐减少,这表明由于光化学作用、微生物作用、大坝拦截效应等环境因素的影响,类腐殖质随着水体由入库向出库的流动而逐渐降解.相反,微生物类腐殖质(M类)的荧光强度结果表明,在入库-出库过程中,微生物类腐殖质处于产生及部分或完全降解的波动中,这表明微生物类腐殖质是浮游植物的原生产物,并且对于光化学作用、微生物作用和大坝拦截效应有很强的不稳定性.类蛋白或类色氨酸或类酪氨酸主要新产生于夏季和秋季的表层水体中,在冬季和春季表层和深层水体中也有产生;并在出库过程中逐渐减少.这表明类蛋白或类色氨酸或类酪氨酸是浮游植物的原生产物;并且它们受到光化学作用、微生物作用和大坝拦截效应的共同影响,在表层和深层水中生成和降解.因此,这些结果意味着通过平行因子分析确定的荧光溶解性有机质组分的方法,对于更好地理解溶解性有机质在水库水体的转化动力学机制至关重要. | 劳心宇 原杰 刘瑜 Khan M.G.Mostofa | 2019 | 环境科学2019，40，3： | 5 |
| 2 | Simultaneous photoinduced generation of Fe^(2+) and H_2O_2 in rivers:An indicator for photo-Fenton reaction显示文摘The photo-Fenton reaction is a key source of the highly reactive hydroxyl radical(HOU) that is produced by the reaction of simultaneous photo-induced generation of Fe^(2+)-dissolved organic matter(DOM) with H_2O_2 in sunlit surface waters as well as in the treatment of organic pollutants in the advanced oxidation processes(AOPs).Concentrations of both H_2O_2 and Fe^(2+)-DOM were dependent on time and total solar intensity flux,and their levels were highest in the diurnal samples collected at noon compared with the samples collected during the period before sunrise and after sunset.H_2O_2 and Fe^(2+)-DOM concentrations during monthly readings were also found higher in comparison with the diurnal samples,shortly before sunrise or after sunset.A π-electron bonding system is formed between Fe and the functional groups in DOM(Fe-DOM),through electron donation from the functional groups of DOM to an empty d-orbital of Fe.The π-electron is loosely bound and is highly susceptible to a rapid excitation upon light exposure that will provide better understanding of the formation of aqueous electrons,superoxide radical anions,H_2O_2 and finally,photo-Fenton reactions,too.Our results imply that simultaneous generation of H_2O_2 and Fe^(2+)-DOM upon sunlight exposure during the daytime is most likely to be the key photo-Fenton reaction pathway,taking place in surface waters. | Khan M.G.Mostofa Hiroshi Sakugawa | 2016 | Journal of Environmental Sciences2016，28，9： | 4 |
| 3 | Detection of tyrosine,trace metals and nutrients in cow dung:the environmental significance in soil and water environments显示文摘This study examined the dissolved organic matter(DOM) components of cow dung using a combination of fluorescence(excitation–emission matrix,EEM)spectroscopy and parallel factor(PARAFAC) modelling along with eleven trace metals using ICP-MS and nutrients(NH_4^+ and NO_3^-) using an AA3 auto analyser. EEM–PARAFAC analysis demonstrated that cow dung predominantly contained only one fluorescent DOM component with two fluorescence peaks(Ex/Em=275/311 nm and Ex/Em=220/311 nm),which could be denoted as tyrosine by comparison with its standard. Occurrence of tyrosine can be further confirmed by the FTIR spectra. Trace metals analysis revealed that Na,K and Mg were significantly higher than Ca,Fe,Mn,Zn Sr,Cu,Ni and Co. The NH_4^+ concentrations were substantially higher than NO_3^-.These results thus indicate that the dissolved components of the cow dung could be useful for better understanding its future uses in various important purposes. | Khan M.G.Mostofa Longlong Li Congqiang Liu | 2018 | Acta Geochimica2018，37，4： | 3 |
| 4 | 青藏高原中东部表土轻组碳氮含量分布及其影响因素显示文摘土壤轻组(LF)能够反映因人为活动或环境变化引起的土壤微弱改变。为探究青藏高原土壤LF含量分布及其影响因素,分析了青藏高原中东部不同植被类型下表土LF、重组(HF)及其碳氮含量和碳氮比(C/N),讨论了LF碳氮含量及C/N与环境因子的相互关系。结果表明:青藏高原中东部表土LF占土壤总有机质的比例很小(2.11%),不同植被类型表土LF含量排序为:林地>高寒草甸>高山草原>荒漠。表土轻组有机碳(LFOC)、重组有机碳(HFOC)平均含量分别为27.23%和2.39%,以林地最高(31.73%,2.64%),荒漠LFOC和高寒草甸HFOC含量最低,分别为24.63%和2.30%。轻组总氮(LFTN)、重组总氮(HFTN)平均含量分别为1.22%和0.12%,以高寒草甸最高(1.28%,0.12%),林地最低(1.14%,0.10%)。轻重组C/N均值分别为27.67和11.59,以林地最高(36.95,15.15),高寒草甸轻组C/N和高山草原重组C/N最低,分别为25.45和10.03,表明林地腐殖化程度较高,有效氮含量较低,而高寒草甸和高山草地与之相反。青藏高原中东部表土LF含量及分布受植被类型影响明显,土壤pH值是影响LF碳氮含量最重要的环境因子。 | 杨雪梅 杨安 邢文聪 王小霞 刘小龙 Khan M.G.Mostofa 李军 | 2020 | 生态学杂志2020，39，8： | 1 |
| 5 | The mechanism behind the DOM effects on methylmercury photodegradation显示文摘Methyl mercury(CH3Hg+),a neurotoxin,is the most toxic form of mercury that occurs in natural waters[1–4].It is a cause of concern because of increasing worldwide pollution by mercury in both water and atmosphere[3,5].Photodegradation of CH3Hg+is one of the main removal pathways from surface waters,and it has been shown | Khan M.G.Mostofa Cong-Qiang Liu Marco Minella Davide Vione | 2015 | Science Bulletin2015，60，13： | 1 |
| 6 | FeCl_(3)沉淀法在水溶液中去除药物抗生素的表现显示文摘药物抗生素(PA)残留物普遍存在于土壤和水环境中;因受去除效率及可产生致癌副产物的制约,目前的生物或光化学降解方法难以有效去除PA,且金属离子与PA的吸附/络合机制尚不清楚。本文用FeCl_(3)从水溶液中去除两种PA—盐酸左氧氟沙星(LH)和盐酸坦索罗辛(TH);发现pH=7.5~8.5时,铁以Fe-PA沉淀物(Fe-PAp)形式将PA从水溶液中分离;连续沉淀5次后,90.3%的LH和87.5%TH被去除;分析LH、TH和Fe-PAp的波峰特征,发现:1)LH和TH主要红外峰:3 433和3 329 cm^(-1)(羧酸OH和NH2)、1 676 cm^(-1)(-COO-)、1 467 cm^(-1)(脂肪族C-H)和1 022 cm^(-1)(-S=O),2)Fe-PAp中前述红外峰强度下降或完全消失。通过化学键分析表明:在Fe-PAp形成过程中,电子从PA内各种官能团转移到Fe3+的空d轨道,形成π-d电子键系统。FeCl_(3)应用广泛:1)作为一种高效且有应用前景的无机吸附剂,能够从水中去除PA,可实现大规模分离生活和工业废水中的有机污染物;2)Fe-PAp的形成表明金属-有机复合物可以在碱性土壤和水中长期稳定,解释了Fe-DOM复合物在环境中的长期稳定/固存机制。 | 张杰 Khan M.G.Mostofa Nicola Senesi Giorgio S.Senesi 李思亮 | 2023 | 地球与环境2023，51，1： | 0 |
| 7 | Spatiotemporal optical properties of dissolved organic matter in a sluice-controlled coastal plain river with both salinity and trophic gradients显示文摘Due to the combined effect of sluices and sea tide,the sluice-controlled coastal plain river would be characterized by both trophic state and salinity gradients,affecting the spatiotemporal optical properties of dissolved organicmatter(DOM).In this study,we investigated the spatiotemporal variation of water quality parameters and optical properties of DOM in the Haihe River,a representative sluice-controlled coastal plain river in Tianjin,China.A significant salinity gradient and four trophic states were observed in the water body of the Haihe River.Two humic-and one protein-like substances were identified from the DOM by the three-dimensional fluorescence spectra combined with the parallel factor(PARAFAC)analysis.Pearson’s correlation analysis and redundancy analysis(RDA)showed that the salinity significantly affected the abundance of chromophoric DOM(CDOM)but did not cause significant changes in the fluorescence optical characteristics.In addition,the effect of Trophic state index(TSI)on the CDOM abundance was greater than that on the fluorescence intensity of fluorescent dissolved organic matter(FDOM).In the water body with both salinity and trophic state gradients,TSI posed a greater influence than salinity on the CDOM abundance.Our results fill the research gap in spatiotemporal DOM characteristics and water quality variation in water bodies with both salinity and trophic state gradients.These results are beneficial for clarifying the joint influence of saline intrusion and sluices on the DOM characteristics and water quality in sluice-controlled coastal plain rivers. | Yu Liu Yucheng Hu Chengxun Yu Yuqi Gao Zhenying Liu Khan M.G.Mostofa Siliang Li Yumei Hu Guanghui Yu | 2023 | Journal of Environmental Sciences2023，，7： | 0 |
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