| 3 | Tunable emission,energy transfer and thermal stability of Ce^(3+),Tb^(3+) co-doped Na_(2)BaCa(PO_(4))_(2) phosphors显示文摘A series of single Ce^(3+) doped and Ce^(3+) and Tb^(3+) co-doped Na_(2)BaCa(PO_(4))_(2)(NBCP) phosphors was synthesized by conventional solid-stated reaction method.The crystal structure,luminescence properties,thermal stability and energy transfer were carefully investigated.Ce^(3+) is inferred to substitute the Ba^(2+)site in NBCP lattice.The color-tunable emission from blue to green is observed by adjusting Tb^(3+) concentration among NBCP:0.03 Ce^(3+),yTb^(3+) phosphors.The energy transfer behavior from Ce^(3+) to Tb^(3+) ions is both illustrated by co-doped PL spectra and decay curves.The energy transfer efficiency is as high as 91.5%.The mechanism of energy transfer is resonance type of dipole-dipole transition.In this work,the optimal phosphor exhibits the excellent thermal stability which keeps at 94.9% of that initial value at room temperature when temperature reaches to 150℃.The Ce^(3+) and Tb^(3+) co-doped NBCP phosphor is a promising candidate for the application in the general lighting and display fields. | Jiamin Tang Jiayong Si Xiaoyi Fan Yijia Liu Guihua Li Gemei Cai | 2022 | Journal of Rare Earths2022，40，6： | 1 |
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