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| 1 | Methane dry reforming on Ni/La_2Zr_2O_7 treated by plasma in different atmospheres显示文摘A series of Ni/La2Zr2O7 pyrochlore catalysts prepared by impregnation method and treated by dielectric barrier discharge(DBD) plasma in different atmospheres and varied sequences were prepared and applied for dry reforming of methane(DRM). It is found that all of the plasma treated catalysts show evidently improved activity and coke resistance in comparison with the non-plasma treated one. The best performance is achieved on Ni/La2Zr2O7–H2P–C,a catalyst treated in H2 plasma before calcination. TGA-DSC and SEM demonstrate that carbon deposition is significantly suppressed on all of the plasma treated samples. Moreover,XRD and TEM results testify that both Ni O and Ni sizes on the calcined and reduced samples treated by plasma are also decreased,which results in higher Ni metal dispersion on the reduced and used catalysts and enhances the interactions between Ni sites and the support. It is believed that these are the inherent reasons accounting for the promotional effects of plasma treatment on the reaction performance of the Ni/La2Zr2O7 pyrochlore catalysts. | Honggen Peng Youhe Ma Wenming Liu Xianglan Xu Xiuzhong Fang Jie Lian Xiang Wang Changqing Li Wufeng Zhou Ping Yuan | 2015 | Journal of Energy Chemistry2015，24，4： | 4 |
| 2 | Confined Ni-In intermetallic alloy nanocatalyst with excellent coking resistance for methane dry reforming显示文摘Carbon dioxide and methane are two main greenhouse gases which are contributed to serious global warming.Fortunately,dry reforming of methane(DRM),a very important reaction developed decades ago,can convert these two major greenhouse gases into value-added syngas or hydrogen.The main problem retarding its industrialization is the seriously coking formation upon the nickel-based catalysts.Herein,a series of confined indium-nickel(In-Ni)intermetallic alloy nanocatalysts(In_(x)Ni@SiO_(2))have been prepared and displayed superior coking resistance for DRM reaction.The sample containing 0.5 wt.%of In loading(In_(0.5)Ni@SiO_(2))shows the best balance of carbon deposition resistance and DRM reactivity even after 430 h long term stability test.The boosted carbon resistance can be ascribed to the confinement of core–shell structure and to the transfer of electrons from Indium to Nickel in In-Ni intermetallic alloys due to the smaller electronegativity of In.Both the silica shell and the increase of electron cloud density on metallic Ni can weaken the ability of Ni to activate C–H bond and decrease the deep cracking process of methane.The reaction over the confined InNi intermetallic alloy nanocatalyst was conformed to the Langmuir-Hinshelwood(L-H)mechanism revealed by in situ diffuse reflectance infrared Fourier transform spectroscopy(in-situ DRIFTS).This work provides a guidance to design high performance coking resistance catalysts for methane dry reforming to efficiently utilize these two main greenhouse gases. | Wenming Liu Le Li Sixue Lin Yiwei Luo Zhenghong Bao Yiru Mao Kongzhai Li Daishe Wu Honggen Peng | 2022 | Journal of Energy Chemistry2022，31，2： | 3 |
| 3 | Fine mapping and cloning of MT1,a novel allele of D10显示文摘瑞斯是为谷物生产的一个重要决定因素到 ering 为止。调查机制到 ering 为止,我们描绘了一到从装饰用的梨树变化识别的 ering 异种(mt1 ) 为止多重, Zhonghua 11,与他们对待。展览推进了到 ering 开发为止并且与野类型的植物相比相形见绌的这异种。印射的基因分析和好基因显示 mt1 异种被后退的基因控制,住在染色体 1 的 AP003376 上的一扇 29-kb 窗户上。在这个区域的一通常认为的基因,编码类胡萝卜素劈开 dioxygenase 8 (CCD8 ) ,对 D10 突变而产生之遗传。mt1 异种显型被野类型的 MT1 的介绍补充,并且在模仿的野类型的米饭的 MT1 击倒变异的显型。实时 PCR 分析显示 MT1 基因在腋的芽,圆锥花序,叶子,和根在茎并且在底层高度被表示。另外, MT1 表示清楚地在反馈规定下面。 | Yong Zhou Jinyan Zhu Zhengyi Li Fei Gu Honggen Zhang Shuzhu Tang Minghong Gu Guohua Liang | 2009 | Progress in Natural Science:Materials International2009，19，12： | 3 |
| 4 | Generation of selectable marker-free soft transgenic rice with transparent kernels by downregulation of SSSⅡ-2显示文摘The amylose content(AC)of rice endosperm starch varies from 0 to 35%,and is associated with rice cooking and eating quality.Soft rice has low AC,generally between 6%and 15%,and its eating quality is high whether it is consumed hot or cold.However,the appearance quality of current soft rice cultivars needs to be improved,especially opaque endosperm.Conventional genetic engineering has improved some agronomic traits of soft rice varieties,but not endosperm appearance.In the present study,a RNAi construct of the soluble starch synthase II-2(SSSII-2)and the hygromycin phosphotransferase(HPT)gene were introduced into an elite japonica rice variety,Kangtiaowuyunjing(KWY8)by co-transformation.Several selectable marker-free(SMF)transgenic lines were obtained,and SSSII-2 expression was significantly downregulated in selected transgenic lines,resulting in lower AC of the endosperm.The physicochemical properties of the transgenic rice kernels,including gel consistency(GC)and rapid visco analyzer(RVA)profile,differed significantly from those of wild-type rice and were similar to those of a soft rice variety,Nanjing 46(NJ46).These findings indicate that the cooking,eating,and processing qualities of transgenic rice are comparable to those of NJ46.However,the transgenic rice endosperm retained a transparent appearance under low-moisture conditions.Thus,SMF SSSII-2 RNAi rice provides a resource for breeding soft rice with transparent endosperm. | Zhihao Xu Meimei Yu Youwei Yin Cenwen Zhu Wen Ji Changquan Zhang Qianfeng Li Honggen Zhang Shuzu Tang Hengxiu Yu Qiaoquan Liu | 2020 | The Crop Journal2020，8，1： | 2 |
| 5 | Free-space coupling of a light beam into a symmetrical metal-cladding optical waveguide 显示文摘 | LI Honggen CAO Zhuangqi LU Haifeng | 2003 | Applied Physics Letters(S0003-6951)2003，83，14： | 1 |
| 6 | Study of ultrahigh-order modes in a symmetrical metal-cladding optical waveguide显示文摘 | LU Haifeng CAO Zhuangqi LI Honggen | 2004 | AppliedPhysiesLetters(S0003-6951)2004，85，20： | 1 |
| 7 | Tunable delay slow-light in an active fiber Bragg grating显示文摘 | Qian Kai Zhan Li Li Honggen | 2009 | Optics Express2009，17，22： | 1 |
| 8 | Oscillating wave sensor based on the Goos-Hinchen effect 显示文摘 | WANG Yi LI Honggen CAO Zhuangqi | 2008 | Applied Physics Letters(SO003-6951)2008，92，06： | 1 |
| 9 | Synthesis of difluoromethylated benzylborons via rhodium(Ⅰ)-catalyzed fluorine-retainable hydroboration of gem-difluoroalkenes显示文摘The synthesis of bo rylated orga nofluorines is of great interest due to their potential values as synthons in modular construction of fluorine-containing molecules.Reported herein is a rhodium-catalyzed hydrobo ration of arylgem-difluoroalkenes leading to a series of α-difluoromethylated benzylborons.The use of cationic rhodium catalyst and a biphosphine ligand with large bite angle was crucial for reactivity by offering good regioselectivity and diminishing the undesired β-F elimination.Preliminary derivatizations of the products were conducted to showcase the utility of this protocol. | Yuanhong Cai Donghang Tan Qiqi Zhang Wenxin Lv Qingjiang Li Honggen Wang | 2021 | Chinese Chemical Letters2021，32，1： | 1 |
| 10 | Free-space coupling of a light beam into a symmetrical metal-cladding optical waveguide显示文摘 | Li Honggen Cao Zhuangqi Lu Haifeng | | 0，，14： | 1 |
| 11 | Study of ultrahigh-order modes in a symmetrical metal-cladding optical waveguide显示文摘 | Haifeng Lu Zhuangqi Cao Honggen Li | | 0，，20： | 1 |
| 12 | Free-space coupling of a light beam into a symmetrical metal-cladding optical waveguide 显示文摘 | Li Honggen Cao Zhuangqi Lu Haifeng | 2003 | Appl Phys Lett2003，83，14： | 1 |
| 13 | Study of ul- trahigh-order modes in a symmetrical metal-cladding waveguide 显示文摘 | Lu Haifeng Cao Zhuangqi Li Honggen | 2004 | Appl Phys Lett2004，85，20： | 1 |
| 14 | Study of ul- trahigh-order modes in a symmetrical metal-claddigu waveguide 显示文摘 | Lu Haifeng Cao Zhuangqi Li Honggen | 2004 | Appl Phys Lett2004，85，20： | 1 |
| 15 | Tunable delay slow- light in an active fiber Bragg grating 显示文摘 | QIAN Kai ZHAN Li LI Honggen | 2009 | Optics Express2009，17，22： | 1 |
| 16 | Tunable delay slow- light in an active fiber Bragg grating 显示文摘 | Kai Qian Li Zhan Honggen Li | 2009 | Opt Exp2009，17，22： | 1 |
| 17 | Oscillating wave displacement sensor using the enhanced Goos- Hanchen effect in a symmetrical metal-cladding optical wavegudie 显示文摘 | Yu Tianyi Li Honggen Cao Zhuangqi | 2008 | Opt Lett2008，33，9： | 1 |
| 18 | Polarization- independent and tunable comb filter based on a free-space coupling technique 显示文摘 | Lu Haifeng Cao Zhuangqi Li Honggen | 2006 | Opt Lett2006，31，3： | 1 |
| 19 | Free-spacecoupling of a li^U into a symmetrical metal-cladding opti-cal waveguide 显示文摘 | Li Honggen Cao Zhuangqi Lu Haifeng’ | 2003 | Applied Physics Letters2003，83，14： | 1 |
| 20 | Accuracy Analysis for 6-DOF PKM with Sobol Sequence Based Quasi Monte Carlo Method显示文摘To improve the precisions of pose error analysis for 6-dof parallel kinematic mechanism( PKM)during assembly quality control,a Sobol sequence based on Quasi Monte Carlo( QMC) method is introduced and implemented in pose accuracy analysis for the PKM in this paper. The Sobol sequence based on Quasi Monte Carlo with the regularity and uniformity of samples in high dimensions,can prevail traditional Monte Carlo method with up to 98. 59% and 98. 25% enhancement for computational precision of pose error statistics.Then a PKM tolerance design system integrating this method is developed and with it pose error distributions of the PKM within a prescribed workspace are finally obtained and analyzed. | Jianguang Li Jian Ding Lijie Guo Yingxue Yao Zhaohong Yi Huaijing Jing Honggen Fang | 2015 | Journal of Harbin Institute of Technology(New Series)2015，22，5： | 1 |
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