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| 1 | Cd3(C3N3S3)2 coordination polymer/graphene nanoarchitectures for enhanced photocatalytic H2O2 production under visible light显示文摘For a long time, there has been global concern over the environment and energy problems. Recently, the problems, which have brought about serious effect on the global living condition, have been in the ‘‘spotlight' and given impetus to the universal's efforts to head for the same direction: stem the worst warming and strive for the renewable energy source. Hydrogen peroxide(H_2O_2) is undoubtedly a good choice,which holds the promise as a clean, efficient, safe and transferrable energy carrier. Octahedral coordination polymer, Cd_3(C_3N_3S_3)_2, was found to be a robust photocatalyst for H_2O_2 generation under visible light irradiation. To further improve the H_2O_2 generation efficiency, adhering the octahedron to reduced graphene(rGO) was applied as the strategy herein. The study shows that by adhering Cd_3(C_3N_3S_3)_2to rGO, the formation of H_2O_2 is 2.5-fold enhanced and its deformation is concurrently suppressed. This work not only demonstrates the effectiveness of adhering Cd_3(C_3N_3S_3)_2polymer to rGO for the improvement of the polymer's photocatalytic performance, but also proposes a general way for the fabrication of graphene/coordination compound hybrids for maximizing their synergy. | Jie Xu Zhenye Chen Hongwen Zhang Guibin Lin Huaxiang Lin Xuxu Wang Jinlin Long | 2017 | Science Bulletin2017，62，9： | 4 |
| 2 | Construction of ZnIn_(2)S_(4)-CdIn_(2)S_(4) Microspheres for Efficient Photo-catalytic Reduction of CO_(2) with Visible Light显示文摘ZnIn_(2)S_(4) has emerged in water splitting and degradation of dyes due to its good stability and light absorption properties.However,there are still few reports of CO_(2) photoreduction.Herein,we successfully synthesized ZnIn_(2)S_(4) and obtained a series of ZnIn_(2)S_(4)-CdIn_(2)S_(4) heterostructured microspheres through the ion exchange method,and first used them in photocatalytic CO_(2) reduction in noble-metal-free systems.The activity results showed that these ZnIn_(2)S_(4)-CdIn_(2)S_(4) photocatalysts exhibit excellent catalytic activity under visible light,and the best CO yield is as high as 33.57μmol・h^(-1) with a selectivity of 91%.Furthermore,the stability and reusability of ZnIn_(2)S_(4)-CdIn_(2)S_(4) was firmly confirmed by diverse characterizations,including X-ray diffraction(XRD),scanning electron microscopy(SEM),transmission electron microscopy(TEM),X-ray photoelectron spectroscopy(XPS),energy-dispersive X-ray spectroscopy(EDX)and N2 adsorption measurements. | Shitong Han Bifang Li Lijuan Huang Hailing Xi Zhengxin Ding Jinlin Long | 2022 | Chinese Journal of Structural Chemistry2022，41，1： | 2 |
| 3 | Controlled Preparation of In203, InOOH and In(OH)3 Via a One-pot Aqueous Solvothermal Route 显示文摘 | YAN Tingjiang WANG Xuxu LONG Jinlin | 2008 | NewJChem2008，32，： | 1 |
| 4 | Efficient photocatalytic degradation of volatile organic compounds by porous indium hydroxide nanocrystals 显示文摘 | Yan Tingjiang Long Jinlin Shi Xicheng | 2010 | Environ Sci Techn2010，44，4： | 1 |
| 5 | Nitrogen-doped grapbene nanosheets as metal-free catalysts for aerobic selective oxidation of benzylic alcohols 显示文摘 | Long Jinlin Xie Xiuqiang Xu Jie Gu Quan Chen Liming Wang Xuxu | 2012 | ACS Catalysis2012，2，4： | 1 |
| 6 | Nitrogen-DopedGraphene Nanosheets as Metal-Free Catalysts for AerobicSelective Oxidation of Benzylic Alcohols显示文摘 | Long Jinlin Xie Xiuqiang Xu Jie | 2012 | ACS Catal2012，2，4： | 1 |
| 7 | Sn2 + Dopantinduced visible-light activity of Sn02 nanoparticles for H2production显示文摘 | Long Jinlin Xue Weiwei Xie Xiuqiang | 2011 | Catalysis Communications2011，16，： | 1 |
| 8 | Photocatalytic and antibacterial properties of medical-grade PVC material coated With TiO2 film显示文摘 | Lin Huaxiang XZ Wang Xuxu Long Jinlin | 2008 | Journal of Biomedical Material Research part B:Applied Biomaterials2008，87，： | 1 |
| 9 | Effect and safety of Kanglaite injection combined with chemotherapy in the treatment of advanced colorectal cancer:a systematic review and meta-analysis显示文摘Objective:To evaluate the clinical efficacy and safety of Kanglaite injection combined with chemotherapy and chemotherapy alone in the treatment of advanced colorectal cancer.Methods:PubMed,Cochrane library,CNKI,VIP,Wanfang database were systematically searched by inputting keywords to explore the efficacy of Kanglaite injection combined with chemotherapy in the treatment of advanced colorectal cancer.A random-effects model was selected to evaluate the treatment outcomes.The screening of literature,the extraction of data and the assessment of methodology were independently undertaken by two reviewers.Meta analysis was performed using Revman5.3 software and stata15.0 software.Results:A total of 12 RCTs were included,with 792 cases.Compared with chemotherapy alone,Metaanalysis suggested that Kanglaite injection combined with chemotherapy can improve clinical efficiency(RR=1.45,95%CI:1.21-1.74,P<0.0001)and improve patients'quality of life(RR=1.55,95%CI:1.32-1.82,P<0.00001),improve the patient's immune function(CD3+cells:SWD=1.42,95%CI:1.11-1.73;CD4+/CD8+cell ratio:SWD=0.95,95%CI:0.66-1.25;NK cell activity:SWD=3.24,95%CI:2.81-3.66,P<0.00001);Leukopenia rate(RR=0.63,95%CI:0.54-0.74,P<0.0001),incidence of gastrointestinal adverse reactions(RR=0.56,95%CI:0.48-0.66,P<0.00001),incidence of peripheral neurotoxicity(RR=0.79,95%CI:0.65-0.96,P=0.02)were lower than the chemotherapy alone group,the difference was statistically significant.In improving the hand-foot syndrome and oral mucositis after chemotherapy,there was some difference between the Kanglaite injection combined with chemotherapy group and the chemotherapy alone group,but the difference was not significant.Puber bias detection and sensitivity analysis were performed with clinically effective relative risk(RR)as indicators.The results suggested that the publication bias was not obvious.The results of this study are stable.Conclusion:Compared with chemotherapy alone group in the treatment of advanced colorectal cancer,Kanglaite injection combined with chemotherapy can improve the effective rate,quality of life,immune function of patients and reduce the incidence of leukopenia after chemotherapy,gastrointestinal adverse reactions and peripheral neurotoxicity. | Jinlin Wu Zhu Yang Fengxi Long Bing Yang Xun Liu Xianman Wei Dongxin Tang | 2019 | Asian Toxicology Tesearch2019，1，1： | 1 |
| 10 | Photochemical synthesis of submicron- and nano-scale Cu 2 O particles显示文摘 | Jinlin Long Jingguo Dong Xuxu Wang Zhengxin Ding Zizhong Zhang Ling Wu Zhaohui Li Xianzhi Fu | 2009 | Journal of Colloid And Interface Science2009，，2： | 1 |
| 11 | Astragalus injection as an adjuvant treatment for colorectal cancer:a meta-analysis显示文摘Background:The combination of Chinese patent medicine Astragalus injection and Western medicine has achieved a certain clinical effect in colorectal cancer patients.However,due to the uneven basic conditions and research indicators of these clinical trials,it is difficult to comprehensively evaluate the effect of Astragalus injection in the adjuvant treatment of colorectal cancer.This study aimed to systematically evaluate the efficacy and safety of Astragalus injection as an adjuvant treatment for colorectal cancer.Methods:The Cochrane Library,VIP database,Wanfang database,and Chinese Academic Journal Full Text database were searched for potentially eligible articles from inception to December 15,2018.Randomized controlled trials in which patients were diagnosed with colorectal cancer were included.Patients in the control group received chemotherapy alone or combined with other drugs,or chemotherapy combined with radiotherapy.Patients in the experimental group were treated with Astragalus injection combined with interventions in the control group.Results:A total of 8 articles were included.Compared with Western medicine alone,the Astragalus injection could improve the therapeutic effect(RR=1.18,95%CI(1.01,1.38),P=0.03),improved the quality of life of colorectal cancer patients(SMD=1.18,95%CI(0.86,1.50),P<0.001),inhibited leukopenia(RR=0.55,95%CI(0.42,0.71),P<0.001),reduced neurotoxicity(RR=0.43,95%CI(0.34,0.56),P<0.001),and reduced the incidence of nausea and vomiting(RR=0.67,95%CI(0.55,0.80),P<0.001).Conclusion:Astragalus injection can reduce the toxicity and improve the efficiency of the conventional Western medicine in the treatment of colorectal cancer. | Jia Wang Zhu Yang Fengxi Long Li Luo Jinlin Wu Ting Yu Dongxin Tang | 2020 | Traditional Medicine Research2020，5，1： | 0 |
| 12 | Highly selective photocatalytic reduction of CO_(2) to CH_(4) on electron-rich Fe species cocatalyst under visible light irradiation显示文摘Efficient photocatalytic reduction of CO_(2) to high-calorific-value CH4,an ideal target product,is a blueprint for C_(1)industry relevance and carbon neutrality,but it also faces great challenges.Herein,we demonstrate unprecedented hybrid SiC photocatalysts modified by Fe-based cocatalyst,which are prepared via a facile impregnation-reduction method,featuring an optimized local electronic structure.It exhibits a superior photocatalytic carbon-based products yield of 30.0μmol g^(−1) h^(−1) and achieves a record CH_(4) selectivity of up to 94.3%,which highlights the effectiveness of electron-rich Fe cocatalyst for boosting photocatalytic performance and selectivity.Specifically,the synergistic effects of directional migration of photogenerated electrons and strongπ-back bonding on low-valence Fe effectively strengthen the adsorption and activation of reactants and intermediates in the CO_(2)→CH_(4) pathway.This study inspires an effective strategy for enhancing the multielectron reduction capacity of semiconductor photocatalysts with low-cost Fe instead of noble metals as cocatalysts. | Qianying Lin Jiwu Zhao Pu Zhang Shuo Wang Ying Wang Zizhong Zhang Na Wen Zhengxin Ding Rusheng Yuan Xuxu Wang Jinlin Long | 2024 | Carbon Energy2024，6，1： | 0 |
| 13 | S-scheme CoTiO_(3)/Cd_(9.51)Zn_(0.49)S_(10)heterostructures for visible-light driven photocatalytic CO_(2) reduction显示文摘CdZnS solid solutions with strong light absorption are promising materials for solar-driven COreduction;however,their relatively weak redox ability and intrinsic photo-corrosion limit their further development as a photocatalyst.The addition of a second photocatalyst with a suitable band structure to construct a S-scheme photocatalytic system can solve both problems simultaneously.Here,we report a S-scheme photocatalyst based on the heterostructure of CoTiO_(3)/CdZnS(abbreviated as CoTiO_(3)/Cd_(9.51)Zn_(0.49)S_(10))that enables the efficient photocatalytic reduction of CO.Detailed physicochemical characterization resolves the S-scheme charge transfer mechanism in this composite photocatalyst.With the well-designed structure of particles and desirable band offsets,this hybrid system offers visible light absorption in a broad spectral region,large surface area,strong redox ability,and fast carrier separation and transportation.Under visible-light illumination,the CoTiO_(3)/Cd Zn S hybrid system displays a CO formation rate of about 11 mmol hgcombined with a long-term operational stability.Besides,a high apparent quantum efficiency(AQE)of 7.27%is realized for the CO_(2)-to-CO reduction reaction by the optimized Co TiO/Cd Zn S hybrid under 420 nm monochromatic light irradiation. | Bo Su Haowei Huang Zhengxin Ding Maarten B.J.Roeffaers Sibo Wang Jinlin Long | 2022 | Journal of Materials Science & Technology2022，，29： | 0 |
| 14 | Selectively converting CO_(2) to HCOOH on Cu-alloys integrated in hematite-driven artificial photosynthetic cells显示文摘The integration of electrochemical CO_(2)reduction(CO_(2)RR) and photoelectrochemical water oxidation offers a sustainable access to valuable chemicals and fuels. Here, we develop a rapidly annealed hematite photoanode with a photocurrent density of 2.83 mA cm^(-2)at 1.7 VRHEto drive the full-reaction. We also present Cu-alloys electrocatalysis extended from CuInSnS4, which are superior in both activity and selectivity for CO_(2)RR. Specifically, the screened CuInSn achieves a CO_(2)to HCOOH Faradaic efficiency of 93% at a cell voltage of-2.0 V by assembling into artificial photosynthesis cell. The stability test of IT exhibits less than 3% degradation over 24 h. Furthermore, in-situ Raman spectroscopy reveals that both CO_(3)^(-2)and CO_(2)are involved in CO_(2)RR as reactants. The preferential affinity of C for H in the ^(*)HCO_(2)intermediate enables an improved HCOOH-selectivity, highlighting the role of multifunctional Cu in reducing the cell voltage and enhancing the photocurrent density. | Jiwu Zhao Liang Huang Lan Xue Zhenjie Niu Zizhong Zhang Zhengxin Ding Rusheng Yuan Xu Lu Jinlin Long | 2023 | Journal of Energy Chemistry2023，，4： | 0 |
| 15 | Recent Advancements in Photoelectrochemical Water Splitting for Hydrogen Production显示文摘Sunlight is the most abundant and inexhaustible energy source on earth.However,its low energy density,dispersibility and intermittent nature make its direct utilization with industrial relevance challenging,suggesting that converting sunlight into chemical energy and storing it is a valuable measure to achieve global sustainable development.Carbon–neutral,clean and secondary pollution-free solar-driven water splitting to produce hydrogen is one of the most attractive avenues among all the current options and is expected to realize the transformation from dependence on fossil fuels to zero-pollution hydrogen.Artificial photosynthetic systems(APSs)based on photoelectrochemical(PEC)devices appear to be an ideal avenue to efficiently achieve solar-to-hydrogen conversion.In this review,we comprehensively highlight the recent developments in photocathodes,including architectures,semiconductor photoabsorbers and performance optimization strategies.In particular,frontier research cases of organic semiconductors,dye sensitization and surface grafted molecular catalysts applied to APSs based on frontier(molecular)orbital theory and semiconductor energy band theory are discussed.Moreover,research advances in typical photoelectrodes with the metal–insulator–semiconductor(MIS)architecture based on quantum tunnelling are also introduced.Finally,we discuss the benchmarks and protocols for designing integrated tandem photoelectrodes and PEC systems that conform to the solar spectrum to achieve high-efficiency and cost-effective solar-to-hydrogen conversion at an industrial scale in the near future. | Yibo Zhao Zhenjie Niu Jiwu Zhao Lan Xue Xianzhi Fu Jinlin Long | 2023 | Electrochemical Energy Reviews2023，6，1： | 0 |
| 16 | Dynamics of neutralizing antibody responses to SARS-CoV-2 in patients with COVID-19: an observational study显示文摘Our understanding of the protective immunity,particularly the long-term dynamics of neutralizing antibody(NAbs)response to SARS-CoV-2,is currently limited.We enrolled a cohort of 545 COVID-19 patients from Hubei,China,who were followed up up to 7 months,and determined the dynamics of NAbs to SARS-CoV-2 by using a surrogate virus neutralization test(sVNT).In our validation study,sVNT IC50 titers and the neutralization rate measured at a single dilution(1:20)were well correlated with FRNT titers(r=0.85 and 0.84,respectively).The median time to seroconversion of NAbs was 5.5 days post onset of symptoms.The rate of positive sVNT was 52% in the first week,reached 100% in the third week,and remained above 97% till 6 months post onset.Quantitatively,NAbs peaked in the fourth week and only a quarter of patients had an estimated peak titer of>1000.NAbs declined with a half-time of 61 days(95%CI:49-80 days)within the first two months,and the decay deaccelerated to a half-time of 104 days(95%CI:86-130 days)afterward.The peak levels of NAbs were positively associated with severity of COVID-19 and age,while negatively associated with serum albumin levels.The observation that the low-moderate peak neutralizing activity and fast decay of NAbs in most naturally infected individuals called for caution in evaluating the feasibility of antibody-based therapy and vaccine durability.NAbs response positively correlated with disease severity,warning for the possibility of repeat infection in patients with mild COVID-19. | Xin Xu Sheng Nie Yanqun Wang Quanxin Long Hong Zhu Xiaoyong Zhang Jian Sun Qinglang Zeng Jincun Zhao Li Liu Ling Li Ailong Huang Jinlin Hou Fan Fan Hou | 2021 | Signal Transduction and Targeted Therapy2021，6，6： | 0 |
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