| 2 | U-Doped Y-Ba-Cu-O Melt-Processed Superconductor显示文摘Large grain Y-Ba-Cu-O (YBCO) superconductors doped with various amounts of deplete d uranium oxide have been fabricated by top seeded melt growth (TSMG). The effec t of depleted UO2 on the large grain microstructure has been studied systemati cally in samples with and without added Pt. Addition of uranium oxide results in the formation of U-phase particles of dimensions of a few hundred nanometers w ith an approximately spherical morphology in the superconducting YBa2Cu3O 7-δ (Y-123) phase matrix. Addition of Y2O3 to the uran ium doped precursor powder, rather than Y-211, yields a significantly finer dis tribution of second phase particles. The chemical composition of the U-phase pa rticles, found in samples with no Pt addition, has been identified as Y2Ba4C u UOy, which exhibits paramagnetic behaviour. It has been confir med experimentally that this phase forms during the peritectic solidification pr ocess. Magnetic measurements show that U-doped melt processed YBCO exhibits imp roved critical current densities and trapped fields compared to un-doped material. | N.Hari Babu D.A.Cardwell C.D.Tarrant K.R.Schneider | 2003 | Tsinghua Science and Technology2003，8，3： | 0 |
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