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您的检索式：作者名="NWaterhouse"
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| 1 | Micropore-confined Ru nanoclusters catalyst for efficient pHuniversal hydrogen evolution reaction显示文摘Pt-based catalysts are used commercially for the hydrogen evolution reaction(HER),even though the low earth abundance and high cost of platinum hinder scale-up applications.Ru metal is a promising alternative catalyst for HER owing to its lower cost but similar metal-hydrogen bond strength to Pt.However,designing an efficient and robust Ru-based electrocatalyst for pHuniversal HER is challenging.Herein,we successfully synthesized N-doped carbon(NC)supported ruthenium catalysts with different Ru sizes(single-atoms,nanoclusters and nanoparticles),and then systematically evaluated their performance for HER.Among these catalysts,the Ru nanocluster catalyst(Ru NCs/NC)displayed optimal catalytic performance with overpotentials of only 14,30,and 32 mV(at 10 mA·cm^(-2))in 1 M KOH,1 M phosphate buffer saline(PBS),and 0.5 M H_(2)SO_(4),respectively.The corresponding mass activities were 32.2,12.1 and 8.1 times higher than those of 20 wt.%Pt/C,and also much better than those of the Ru single-atoms(Ru SAs/NC)and Ru nanoparticle(Ru NPs/NC)catalysts,at an overpotential of 100 mV under alkaline,neutral and acidic conditions,respectively.Density functional theory(DFT)calculations revealed that the outstanding HER performance of the Ru NCs/NC catalyst resulted from a strong interaction between the Ru nanoclusters and the N-doped carbon support,which downshifted the d-band center and thus weakened the*H adsorption ability of Ru sites. | Xiaoxiao Huang Ruihu Lu Yaping Cen Dunchao Wang Shao Jin Wenxing Chen Geoffrey I NWaterhouse Ziyun Wang Shubo Tian Xiaoming Sun | 2023 | Nano Research2023，16，7： | 0 |
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