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| 1 | Review of current progress in hole-transporting materials for perovskite solar cells显示文摘Recent advancements in perovskites’ application as a solar energy harvester have been astonishing. The power conversion efficiency(PCE) of perovskite solar cells(PSCs) is currently reaching parity(>25 percent), an accomplishment attained over past decades. PSCs are seen as perovskites sandwiched between an electron transporting material(ETM) and a hole transporting material(HTM). As a primary component of PSCs, HTM has been shown to have a considerable effect on solar energy harvesting, carrier extraction and transport, crystallization of perovskite, stability, and price. In PSCs, it is still necessary to use a HTM.While perovskites are capable of conducting holes, they are present in trace amounts, necessitating the use of an HTM layer for efficient charge extraction. In this review, we provide an understanding of the significant forms of HTM accessible(inorganic, polymeric and small molecule-based HTMs), to motivate further research and development of such materials. The identification of additional criteria suggests a significant challenge to high stability and affordability in PSC. | Prerna Mahajan Bhavya Padha Sonali Verma Vinay Gupta Ram Datt Wing Chung Tsoi Soumitra Satapathi Sandeep Arya | 2022 | Journal of Energy Chemistry2022，31，5： | 3 |
| 2 | Down-conversion materials for organic solar cells:Progress,challenges,and perspectives显示文摘Organic solar cells(OSCs)in terms of power conversion efficiency(PCE)and operational lifetime have made remarkable progress during the last decade by improving the active layer materials and introducing new interlayers.The newly developed wide bandgap organic donor and low bandgap acceptor molecules covered the absorption from the visible to the near-infrared region.Whereas the incident high energy region(UV)is not in favor of OSCs.Its absorption causes thermalization losses and photoinduced degradation,which hinders the PCE and lifetime of OSCs.Recently,lanthanide and non-lanthanide-based down-conversion(DC)materials have been introduced,which can effectively convert the high-energy photons(UV)to low-energy photons(visible)and resolve the spectral mismatch losses that limit the absorption of OSCs in high energy incident spectrum.Furthermore,the DC materials also protect the OSCs from UV-induced degradation.The DC materials were also proposed to cross the Shockley-Queisser efficiency limit of the solar cell.In this review,the need for DC materials and their processing method for OSCs have been thoroughly discussed.However,the main emphasis has been given to developing lanthanides and non-lanthanides-based DC materials for OSCs,their applications,and their impact on photovoltaic device performance,stability,and future perspectives. | Ram Datt Swati Bishnoi Harrison Ka Hin Lee Sandeep Arya Sonal Gupta Vinay Gupta Wing Chung Tsoi | 2022 | Aggregate2022，3，3： | 0 |
| 3 | Organic Solar Cells at Stratospheric Condition for High Altitude Platform Station Application显示文摘High specific power or power to mass ratio is a critical concern of photovoltaic(PV)for aerospace applications.Organic solar cells(OSCs)have advantages such as high absorption coefficient,compatibility with flexible substrate,light-weight,etc.Moreover,recently OSCs achieved power conversion efficiency(PCE)over 20%with the incorporation of the non-fullerene based small molecule acceptor and high specific power is believed to be obtained.To enter the market,high-altitude platform station(HAPS)is perhaps the first place to start with.In this work,we explore and compare the in-situ performance of two high performing OSCs,using the same donor but different acceptors,in mimic HAPS environment where the pressure,temperature and the illumination conditions are controlled.We found that the use of acceptor can result in substantial difference in the performance at low temperatures. | Ram Datt Harrison Ka Hin Lee Guichuan Zhang Hin-Lap Yip Wing Chung Tsoi | 2022 | Chinese Journal of Chemistry2022，40，24： | 0 |
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