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| 1 | Advancement and new perspectives of using formulated reactive amine blends for post-combustion carbon dioxide (CO_(2)) capture technologies显示文摘Chemical absorption using amine-based solvents have proven to be the most studied,as well as the most reliable and efficient technology for capturing carbon dioxide(CO_(2))from exhaust gas streams and synthesis gas in all combustion and industrial processes.The application of single amine-based solvents especially the very reactive monoethanolamine(MEA)is associated with a parasitic energy demand for solvent regeneration.Since regeneration energy accounts for up to threeequarters of the plant operating cost,efforts in its reduction have prompted the idea of using blended amine solvents.This review paper highlights the success achieved in blending amine solvents and the recent and future technologies aimed at increasing the overall volumetric mass transfer coefficient,absorption rate,cyclic capacity and greatly minimizing both degradation and the energy for solvent regeneration.The importance of amine biodegradability(BOD)and low ecotoxicity as well as low amine volatility is also highlighted.Costs and energy penalty indices that influences the capital and operating costs of CO_(2) capture process was also highlighted.A new experimental method for simultaneously estimating amine cost,degradation rate,regeneration energy and reclaiming energy is also proposed in this review paper. | Chikezie Nwaoha Teeradet Supap Raphael Idem Chintana Saiwan Paitoon Tontiwachwuthikul Mohammed JAL-Marri Abdelbaki Benamor | 2017 | Petroleum2017，3，1： | 4 |
| 2 | The development of gas sensor for carbon on oxde monitoring using nanostructure of Nb-TiO2显示文摘 | ANUKUNPRASERT T SAIWAN TRAVERSA E | 2005 | Sci Technol Adv Mater2005，6，3： | 1 |
| 3 | Nano-Titanium Dioxide Synthesis in AOT Microemulsion System with SalinityScan显示文摘 | Krathong S Anukulprasert T | 2004 | Journal of Chemical Engineering of Japan2004，37，2： | 1 |
| 4 | Development of polymer from high internal phase emulsion for CO2adsorption显示文摘 | Pailin Muchan Chintana Saiwan David de Montigny | 2013 | Energy Procedia2013，37，： | 1 |
| 5 | Recent progress and new development of post-combustion carbon-capture technology using reactive solvents (part 5b): Solvent chemistry: reaction kinetics of CO2 absorption into reactive amine solutions显示文摘 | Serna T Naami A Liang Z Shi H Rayer A V Sumon K Z Wattanaphan P Henni A Idem R Saiwan C | 2012 | Carbon Management2012，3，2： | 1 |
| 6 | Elemental transport and distribution in soils amended with incinerated sewage sludge显示文摘 | Paramasivam S Saiwan K S Alva A K VanClief D Hostler K H | 2003 | Journal of Environmental Science and Health2003，38，5： | 1 |
| 7 | Nanostructured TiO2-based mixed metal oxides prepared using microemulsions for carbon monoxide detection显示文摘 | ANUKUNPRASERT T SAIWAN C DI BARTOLOMEO E | 2007 | J Electroceramics2007，18，： | 1 |
| 8 | Microstructure Effect of Nanocrystalline Titanium Dioxide Prepared by Microemulsion Technique on Photocatalytic Decomposition of Phenol显示文摘 | Anukunprasert T Saiwan C Traversa E | 2006 | Journal of Materials Research2006，21，： | 1 |
| 9 | The development of gas sensor for carbon on oxide monitoring using nanostructure of Nb-TiO2显示文摘 | ANUKUNPRASERT T SAIWAN C TRAVERSA E | 2005 | Sci Technol Adv Mater2005，6，3： | 1 |
| 10 | The development of gas sensor for carbon on oxide monitoring using nanostructure of Nb-TiO2 显示文摘 | Anukunprasert T Saiwan Traversa E | 2005 | Science and Technology of Advanced Materials2005，6，3： | 1 |
| 11 | The Development of Gas Sensor for Carbon Monoxide Monitoring Uing Nanostructure of Nb-TiO2显示文摘 | Anukunprasert T Saiwan C Traversa E | 2005 | Science and Technology of Advanced Materials2005，6，3： | 1 |
| 12 | The development of gas sensor for carbonmonoxide monitoring using nanostructure of Nb-TiO2 显示文摘 | Anukunprasert T Saiwan C Traversa E | 2005 | Science and Technology of Advanced Materials2005，6，3： | 1 |
| 13 | Carbon dioxide adsorption/desorption performance of single-and blended-amines-impregnated MCM-41 mesoporous silica in post-combustion carbon capture显示文摘High-surface-area,hexagonal-structured mesoporous silica,MCM-41,was synthesized and wet impregnated with three different amines of 2-(ethylamino)ethanol(EAE),ethylenediamine(EDA),and tetraethylenepentamine(TEPA)for use as solid adsorbents in post-combustion CO_(2) capture application.The CO_(2) adsorption test was performed at 25℃and atmospheric pressure using 15/85 vol%of CO_(2)/N2 at a 20-mL/minute flow rate.Desorption was carried out at 100℃under 20 mL/minute of N2 flow.The results show that the capacity and rate of CO_(2) adsorption obtained from all the amine-modified adsorbents were significantly increased with increasing amine loading due to carbamate formation.Desorption efficiency and heat duty for regeneration were also affected by the amount of amine loading.The more stable the carbamate produced,the higher the energy was required.They exhibited the highest adsorption-desorption performance at 60 wt%amines used for impregnation.Blended EAE/TEPA at different weight ratios at a total concentration at 60 wt%amines was impregnated on MCM-41 adsorbent.Sorbent impregnated with 50%/10%of EAE/TEPA showed the best performance of 4.25 mmolCO_(2)/g at a high adsorption rate,a low heat duty of 12 kJ/mmolCO_(2) and with 9.4%reduction of regeneration efficiency after five repeated adsorption-desorption cycles. | Pailin Muchan Chintana Saiwan Manit Nithitanakul | 2022 | Clean Energy2022，6，3： | 1 |
| 14 | Investigation of adsorption/desorption performance by aminopropyltriethoxysilane grafted onto different mesoporous silica for post-combustion CO_(2) capture显示文摘Mesoporous silicas with hexagonal structure(MCM-41 and SBA-15)and cubical interconnected pore structure(KIT-6)were synthesized and modified with aminopropyltriethoxysilane(APTES)for using as adsorbents in carbon-dioxide(CO_(2))-adsorption application.The CO_(2)-adsorption experiment was carried out at room temperature and atmospheric pressure using 15%CO_(2) with a flow rate of 20 mL/min and the desorption experiment was carried out at 100℃ under N_(2) balance with a flow rate of 20 mL/min.The adsorption capacity and adsorption rate of all modified mesoporous silicas were enhanced due to the presence of primary amine in the structure,which was able to form a fast chemical reaction with CO_(2).All adsorbents showed good adsorption performance stability after using over five adsorption/desorption cycles.Due to the effect of the adsorbents’porous structure on the adsorption/desorption process,an adsorbent with sufficient pore-size diameter and pore volume together with interconnected pore,KIT-6,represents a promising adsorbent that gave the optimum adsorption/desorption performance among others.It showed reasonable adsorption capacity with a high rate of adsorption.In addition,it could also be regenerated with 99.72% efficiency using 12.07 kJ/mmol CO_(2) of heat duty for regeneration. | Pailin Muchan Chintana Saiwan Manit Nithitanakul | 2020 | Clean Energy2020，4，2： | 0 |
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