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1篇 您的检索式:作者名="Savan M.Darjee"
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1Scrupulous recognition of biologically important acids by fluorescent "turn off-on" mechanism of thaicalix reduced silver nanoparticles显示文摘Water dispersible silver nanoparticles(AgNps) were prepared using thiacalix[4]arene tetrahydrazide(TCTH) as a reducing and stabilizing agent.TCTH-AgNps were characterized by surface plasmon resonance(SPR),transmission electron microscopy(TEM) and energy dispersive X-ray(EDX).Relatively uniform 20 nm spherical particles of TCTH-AgNps were efficiently formed over a pH range of 5-9 and from 10-40 ℃.The interaction behavior of TCTH-AgNps with different amino acids was investigated using spectrophotometry and spectrofluorimetry.Among the amino acids tested,only tryptophan and histidine showed fluorescence quenching and fluorescence enhancement,respectively.The linear detection range by Stern-Volmer plot was 5 nmol/L to 0.48 μmol/L for tryptophan and 4 nmol/L to 0.54 μmol/L for histidine.TCTH-AgNps were able to effectively reduce the levels of gram-positive bacteria,gram-negative bacteria,and fungi.These properties argue for the potential use of TCTH-AgNps as detectors of histidine and tryptophan and as antibiotics.Savan M.Darjee Keyur D.Bhatt Urvi S.Panchal Vinod K.Jain 2017Chinese Chemical Letters2017,28,2:1
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