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| 1 | Review on photocatalytic and electrocatalytic artificial nitrogen fixation for ammonia synthesis at mild conditions: Advances,challenges and perspectives显示文摘The ammonia synthesis from nitrogen and water under ambient conditions is one of the most inviting but challenging reaction routes.Although nitrogen is abundant in the atmosphere and the ammonia synthesis reaction is exothermic on the thermodynamics,the conversion of N2 to ammonia is actually hard to proceed owing to the chemical inertness and stability of N2 molecules.In industry,ammonia synthesis is carried out by the Haber-Bosch process under harsh conditions (300-500 ℃,20-30 MPa) associated with the requirement of substantial energy input and the enormous emission of greenhouse gases (e.g.,CO2).Recently,a growing number of studies on photo(electro)catalytic and electrocatalytic nitrogen reduction reaction (NRR) in aqueous solution have attracted extensive attention,which holds great promise for nitrogen fixation under room temperature and atmospheric pressure.However,the very low efficiency and ambiguous mechanism still remain as the major hurdles for the development of photochemical and electrochemical NRR systems.Here we provide an overview of the latest progresses,remaining challenges and future prospects in photocatalytic and electrocatalytic nitrogen fixation.Moreover,this review offers a helpful guidance for the reasonable design of photocatalysts and electrocatalysts towards NRR by combining theory predictions and experiment results.We hope this review can stimulate more research interests in the relatively understudied but highly promising research field of NRR. | Xiaolan Xue Renpeng Chen Changzeng Yan Peiyang Zhao Yi Hu Wenjun Zhang Songyuan Yang Zhong Jin | 2019 | Nano Research2019，12，6： | 20 |
| 2 | PGC-1α induces apoptosis in human epithelial ovarian cancer cells through a PPARy-dependent pathway显示文摘Peroxisome 激活 proliferator 的受体鲸鱼群妈(PPAR γ) coactivator-1 高山哈(PGC-1 α) coactivates 多重抄写因素并且调整几个代谢过程。Thecurrent 学习在人的上皮的卵巢的癌症房间在 apoptosis 的正式就职调查了 PGC-1 α的角色。在人的卵巢和人的卵巢的上皮的肿瘤之间的 PGC-1 α信使 rna 水平被量的 RT-PCR 检验。更少的 PGC-1 α表示与正常卵巢相比在恶意的肿瘤的表面上皮被发现。在人的上皮的卵巢的癌症房间线 Ho-8910 的 PGC-1 α的 Overexpression 通过 Bcl-2 和 Bax 表示的协调规定导致了房间 apoptosis。Microarray 分析证实 PGC-1 α戏剧性地在 Ho-8910 房间影响了 apoptosis 相关的基因。 Mitochondrial 功能的试金证明 apoptosis 的正式就职通过由细胞色素 c.Furthermore 的版本的终端阶段,导致的 apoptosis 部分是,然而并非完全,由 PPAR γa ntagonist ( GW9662 )堵住了的 PGC-1 α-,并且由 siRNA 的 PPAR γ 表示的抑制也在 Ho-8910 房间禁止了 PGC-1 α- inducedapoptosis 。这些数据建议 PGC-1 α通过 aPPAR γ - 依赖者小径施加了它的效果。我们的调查结果显示 PGC-1 α涉及 apoptotic signaltransduction 小径, PGC-1 α的 down 规定可以是在支持上皮的卵巢的癌症生长和前进的一个关键点。 | Yan Zhang Yi Ba Chang Liu Guoxun Sun Li Ding Songyuan Gao Jihui Hao Zhentao Yu Junfeng Zhang Ke Zen Zhongsheng Tong Yang Xiang Chen-Yu Zhang | 2007 | Cell Research2007，17，4： | 14 |
| 3 | Procalcitonin could be a reliable marker in differential diagnosis of post-implantation syndrome and infection after percutaneous endovascular aortic repair显示文摘 | Xue Ling Luo Songyuan Luo Jianfang Liu Zhen Gu Mengnan Kang Huiyuan Yang Fan Nie Bingrong Liu Yuan Huang Wenhui Xie Nianjin He Pengcheng Dong Haojian Ni Zhonghan Fan Ruixin Chen Jiyan | 2014 | Chinese Medical Journal2014，，14： | 8 |
| 4 | Inside-out Ostwald ripening: A facile process towards synthesizing anatase TiO2 microspheres for high- efficiency dye-sensitized solar cells显示文摘一灵巧在内外面,到 TiO 2 microspheres 的控制形态学的准备的 Ostwald 成熟线路被开发。这里, TiO 2 空 microspheres (HM ) 和稳固的 microspheres (SM ) 被在 solvothermal 过程以 acetylacetone (Acac ) 调整 isopropanol (国际语音学协会) 的体积比率准备。在 HM,稳固的核心的降水,核心的表面上的外部壳的随后的免职,和同时的核心的形成过程期间,溶解和壳再结晶被观察,它验证在内外面 Ostwald 成熟机制。TiO 2 microspheres 的性质(毛孔尺寸,表面区域,和陷井状态) 的设计和优化对 dyesensitized 太阳能电池(DSSC ) 的高效重要。优化 TiO 2 microspheres (rHM 和 rSM ) 在再结晶上由 processing 以后获得了,拥有大毛孔尺寸,高表面区域和减少的陷井状态(Ti 3+ 和氧空缺) ,并且因此是为光电的设备的理想的材料。用 rHM photoanode 制作的 DSSC 的力量变换效率是 11.22% ,它显著地与基于 rSM 的 DSSC 的 10.54% 效率相比被改进。我们的工作为综合提供策略 TiO 2 microspheres 同时提供不同物理性质以表面区域, crystallinity,形态学,和 mesoporosity。 | Yong Ding Xin Xia Wangchao Chen Linhua Hu Li'e Mo Yang Huang Songyuan Dai | 2016 | Nano Research2016，9，7： | 7 |
| 5 | Metal chalcogenide complex-mediated fabrication of Cu_2S film as counter electrode in quantum dot sensitized solar cells显示文摘Cu2S film onto FTO glass substrate was obtained to function as counter electrode for polysulfide redox reactions in CdS/CdSe co-sensitized solar cells by sintering after spraying a metal chalcogenide complex, N4H9Cu7S4 solution. Relative to Pt counter electrode, the Cu2S counter electrode provides greater electrocatalytic activity and lower charge transfer resistance. The prepared Cu2S counter electrode represented nanoflower-like porous film which was composed of Cu2S nanosheets on FTO and had a higher surface area and lower sheet resistance than that of sulfided brass Cu2S counter electrode. An energy conversion efficiency of 3.62% was achieved using the metal chalcogenide complex-mediated fabricated Cu2S counter electrode for CdS/CdSe co-sensitized solar cells under 1 sun, AM 1.5 illumination. | YU XueChao ZHU Jun LIU Feng WEI JunFeng HU LinHua DAI SongYuan | 2013 | Science China Chemistry2013，56，7： | 6 |
| 6 | Deletion analysis of oligomycin PKS genes (olmA) in Streptomyces avermitilis显示文摘Gene deletion vector pXL05(pKC1139∷△olmA1 +△olmA4) was used to disrupt oligomycin PKS en-coding genes (olmA) in Streptomyces avermitilis CZ8-73, the producer of anthelmintic avermectins B and the cell growth inhibitor oligomycin. olmA gene cluster in the chromosome was displaced by deletion allele on the plasmid via double crossover. Four of disruptants were confirmed by Southern blotting. Shaking flask experiments and HPLC analyses showed that the four mutants no longer produced the toxic oligomycin, but only made four components of avermectins B, which were avermectin B1a, B1b, B2a, B2b. The yields of avermectins B in these mutants were separately equal to those in CZ8-73. This revealed that olmA genes deletion did not affect the biosynthesis of avermectins. The deletion mu-tants were proved to be genetically stable, and thus might be promising strains in industrial production of avermectins B. | ZHANGXiaolin CHENZhi ZHAOJinlei SONGYuan WENYing LIJilun | 2004 | Chinese Science Bulletin2004，49，4： | 6 |
| 7 | The Fault Block's Framework in Boli Basin and its Control Over the Deposition显示文摘Boli basin, between Yishu fracture belt and Dunmi fracture belt, is the biggest Mesozoic coal basin in the east of Heilongjiang Province. Now it is a fault-fold remnant basin. The basin’s shape is generally consistent with the whole distribution of the cover folds, an arc protruding southwards. The basement of the basin can be divided into three fault blocks or structural units. The formation and evoluation of the basin in Mesozoic was determined by the basement fault blocks’ dis- placement features rusulted from by the movement of the edge faults and the main basement faults. | Cao Chengrun, Shan Xuanlong, Wang Dongpo (Jilin University, Changchun 130026 P. R. China) Wang Xianmin and Yao Ping (Jilin oil feild. Songyuan 131150 P. R. China) | 2001 | Global Geology2001，6，1： | 5 |
| 8 | Ultrasound-guided microwave ablation for symptomatic adenomyosis:More areas of concern for more uniform and promising outcomes显示文摘Adenomyosis is a common gynecological disease in reproductive women,which causes serious dysmenorrhea,menorrhagia,anemia,and infertility,and has a serious impact on the physical and mental health of women.Considering that the efficacy of the traditional medication and surgical treatment is not ideal,an increasing number of patients are searching for more effective and less invasive therapies.Ultrasound(US)-guided microwave ablation(MWA)has emerged as a new effective and minimally invasive alternative treatment for symptomatic adenomyosis,and it is widely being used in clinical settings.Several studies have proven that it is an efficient and safe treatment modality for symptomatic adenomyosis,but a significant variance in clinical outcomes reported in previous studies was also observed.Herein,we have analyzed the potential causes of this problem from the aspects of the diagnosis of adenomyosis,symptom evaluation before ablation,steps of USguided ablation treatment,and outcome evaluation after ablation.Simultaneously,the clinical problems existing in the ablation treatment of adenomyosis are discussed,and the directions of future research are pointed out. | Huili Zhang Songyuan Yu Huixiong Xu | 2022 | Journal of Interventional Medicine2022，5，3： | 4 |
| 9 | Ionic liquid crystal-based electrolyte with enhanced charge transport for dye-sensitized solar cells显示文摘A room temperature ionic liquid crystal,1-dodecyl-3-ethylimidazolium iodide(C12EImI),and an ionic liquid,1-decyl-3-ethylimidazolium iodide(C10EImI),have been synthesized,characterized and employed as the electrolyte for dye-sensitized solar cells(DSSC).The physicochemical properties show that a smectic A(SmA)phase with a lamellar structure is formed in C12EImI.Both C12EImI and C10EImI have good electrochemical and thermal stability facilitating their use in DSSC.The steady-state voltammograms reveal that the diffusion coefficient of I3–in C12EImI is larger than that in C10EImI,which is attributed to the existence of the SmA phase in C12EImI.Because the iodide species are located between the layers of imidazolium cations in C12EImI,exchange reaction-based diffusion is increased with a consequent increase in,the overall diffusion.The electrochemical impedance spectrum reveals that charge recombination at the dyed TiO2/electrolyte interface of a C12EImI-based DSSC is reduced due to the increase in I3–diffusion,resulting in higher open-circuit voltage.Moreover,both short-circuit current density and fill factor of the C12EImI based DSSC increase,as a result of the increasing transport of I3–in C12EImI.Consequently,the photoelectric conversion efficiency of C12EImI-based DSSC is higher than that of the C10EImI–based DSSC. | PAN Xu WANG Meng FANG XiaQing ZHANG ChangNeng HUO ZhiPeng DAI SongYuan | 2013 | Science China Chemistry2013，56，10： | 4 |
| 10 | Precursor-dependent structural diversity in luminescent carbonized polymer dots(CPDs):the nomenclature显示文摘Carbon dots(CDs)have received immense attention in the last decade because they are easy-to-prepare,nontoxic,and tailorable carbon-based fluorescent nanomaterials.CDs can be categorized into three subgroups based on their morphology and chemical structure:graphene quantum dots(GQDs);carbon quantum dots(CQDs),and carbonized polymer dots(CPDs).The detailed structures of the materials can vary significantly,even within the same category.This property is particularly predominant in chemically synthesized CPDs,as their formation proceeds via the polymerization-carbonization of molecules or polymer precursors.Abundant precursors endow CPDs with versatile structures and properties.A wide variety of carbon nanomaterials can be grouped under the category of CPDs because of their observed diversity.It is important to understand the precursor-dependent structural diversity observed in CPDs.Appropriate nomenclature for all classes and types of CPDs is proposed for the better utilization of these emerging materials。 | Qingsen Zeng Tanglue Feng Songyuan Tao Shoujun Zhu Bai Yang | 2021 | Light(Science & Applications)2021，10，8： | 4 |
| 11 | Surface states in TiO2 submicrosphere films and their effect on electron transport显示文摘 | Li'e Mo Wangchao Chen Ling Jiang Yong Ding Zhaoqian Li Linhua Hu Songyuan Dai | 2017 | Nano Research2017，10，11： | 3 |
| 12 | Self-adaptive Processing and Forecasting Algorithm for Univariate Linear Time Series显示文摘As the Box-Jenkins method could not grasp the non-stationary characteristics of time series exactly, nor identify the optimal forecasting model order quickly and precisely, a self-adaptive processing and forecasting algorithm for univariate linear time series is proposed. A self-adaptive series characteristic test framework which employs varieties of statistic tests is constructed to solve the problem of inaccurate identification and inadequate processing for non-stationary characteristics of time series. To achieve favorable forecasts, an optimal forecasting model building algorithm combined with model filter and candidate model pool is proposed, in which a univariate linear time series forecasting model is built. Experimental data demonstrates that the proposed algorithm outperforms the comparative method in all forecasting performance statistics. | LIU Shufen GU Songyuan PENG Jun | 2017 | Chinese Journal of Electronics2017，26，6： | 2 |
| 13 | The Main Progress of Perovskite Solar Cells in 2020-2021显示文摘Perovskite solar cells(PSCs)emerging as a promising photovoltaic technology with high efficiency and low manufacturing cost have attracted the attention from all over the world.Both the efficiency and stability of PSCs have increased steadily in recent years,and the research on reducing lead leakage and developing eco-friendly lead-free perovskites pushes forward the commercialization of PSCs step by step.This review summarizes the main progress of PSCs in 2020 and 2021 from the aspects of efficiency,stability,perovskite-based tandem devices,and lead-free PSCs.Moreover,a brief discussion on the development of PSC modules and its challenges toward practical application is provided. | Tianhao Wu Zhenzhen Qin Yanbo Wang Yongzhen Wu Wei Chen Shufang Zhang Molang Cai Songyuan Dai Jing Zhang Jian Liu Zhongmin Zhou Xiao Liu Hiroshi Segawa Hairen Tan Qunwei Tang Junfeng Fang Yaowen Li Liming Ding Zhijun Ning Yabing Qi Yiqiang Zhang Liyuan Han | 2021 | Nano-Micro Letters2021，13，10： | 2 |
| 14 | A New Quantum Algorithm for Computing RSA Ciphertext Period显示文摘Shor proposed a quantum polynomial-time integer factorization algorithm to break the RSA public-key cryptosystem.In this paper,we propose a new quantum algorithm for breaking RSA by computing the order of the RSA ciphertext C.The new algorithm has the following properties:1)recovering the RSA plaintext M from the ciphertext C without factoring n;2)avoiding the even order of the element;3)having higher success probability than Shor's;4)having the same complexity as Shor's. | WANG Yahui YAN Songyuan ZHANG Huanguo | 2017 | Wuhan University Journal of Natural Sciences2017，22，1： | 2 |
| 15 | Estimating leaf mercury content in Phragmites australis based on leaf hyperspectral reflectance显示文摘Introduction:Highmercury(Hg)concentrations affect the chlorophyll in leaves,therebymodifying leaf spectra.Hyperspectra is a promising technique for the rapid,nondestructive evaluation of leaf Hg content.In this study,we investigated Hg contents and reflective hyperspectra of reed leaves(Phragmites communis)in a gold mining(Jilin province,China).Spectral parameters sensitive to Hg content were identified through basic spectral transformations,continuous wavelet transformation(CWT),and spectral indices techniques.Leaf Hg inversion models were developed using stepwise multiple linear regression,partial least squares regression,and random forest algorithms.Outcomes:The results indicated that:1)leaf Hg content decreased with increasing distance from the mine:Jiapigou(JPG)>Erdaocha(EDC)>Laojingchang(LJC)>Erdaogou(EDG)>Lingqian(LQ)>Weishahe(WSH).2)Hg–sensitive wavelengths were primarily in the visible region;CWT increased the correlation between hyperspectral data and leaf Hg content,and improved the regression and accuracy of inversion;3)the continuumremoval–CWT–stepwise multiple linear regression was better for estimating low leaf Hg content;while the differential spectral index–partial least squares regression was better for estimating high leaf Hg content.Conclusion:These hyperspectral inversion methods could be used for rapid,nondestructive monitoring of wetland plants. | Weiwei Liu Mengjie Li Manyin Zhang DaanWang Ziliang Guo Songyuan Long Si Yang Henian Wang Wei Li Yukun Hu Yuanyun Wei Hongye Xiao | 2020 | Ecosystem Health and Sustainability2020，6，1： | 2 |
| 16 | Numerical analysis of the three-dimensional aerodynamics of a hovering rufous hummingbird(Selasphorus rufus)显示文摘Hummingbirds have a unique way of hovering. However, only a few published papers have gone into details of the corresponding three-dimensional vortex structures and transient aerodynamic forces. In order to deepen the understanding in these two realms, this article presents an integrated computational fluid dynamics study on the hovering aerodynamics of a rufous hummingbird. The original morphological and kinematic data came from a former researcher's experiments. We found that conical and stable leading-edge vortices(LEVs) with spanwise flow inside their cores existed on the hovering hummingbird's wing surfaces. When the LEVs and other near-field vortices were all shed into the wake after stroke reversals, periodically shed bilateral vortex rings were formed. In addition, a strong downwash was present throughout the flapping cycle. Time histories of lift and drag were also obtained. Combining the three-dimensional flow field and time history of lift, we believe that high lift mechanisms(i.e., rotational circulation and wake capture) which take place at stroke reversals ininsect flight was not evident here. For mean lift throughout a whole cycle, it is calculated to be 3.60 g(104.0 % of the weight support). The downstroke and upstroke provide64.2 % and 35.8 % of the weight support, respectively. | Songyuan Yang Weiping Zhang | 2015 | Acta Mechanica Sinica2015，31，6： | 2 |
| 17 | Improving the performance of arylamine-based hole transporting materials in perovskite solar cells: Extending π-conjugation length or increasing the number of side groups?显示文摘In this work, we prepared three simple arylamine-based hole transporting materials from commercially available starting materials. The effect of extending 7 r-conjugation length or increasing the number of side groups compared with reference compound on the photophysical, electrochemical, hole mobility properties and performance in perovskite solar cells were further studied. It is noted that these two kinds of molecular modifications can significantly lower the HOMO level and improve the hole mobility, thus improving the hole injection from valence band of perovskite. On the other hand, the compound with more side groups showed higher hole injection efficiency due to lower HOMO level and higher hole mobility compared with the compound with extending π-conjugation length. The perovskite solar cells with the modified molecules as hole transporting materials showed a higher efficiency of 15.40% and 16.95%,respectively, which is better than that of the reference compound(13.18%). Moreover, the compound with increasing number of side groups based devices showed comparable photovoltaic performance with that of conventional spiro-OMeTAD(16.87%). | Xuepeng Liu Fantai Kong Wangchao Chen Ting Yu Yin Huang Tasawar Hayat Ahmed Alsaedi Hongxia Wang Jian Chen Songyuan Dai | 2018 | Journal of Energy Chemistry2018，27，5： | 2 |
| 18 | Aggregation and luminescence in carbonized polymer dots显示文摘The aggregate luminescence behavior of organic luminescent materials has been studied extensively.As a new kind of luminescent nanomaterials,carbonized polymer dots(CPDs)not only inherit the stability and biocompatibility of carbon materials,but also possess the luminescence tunability,water solubility,and high photoluminescence quantum yield of organic luminescent materials,rendering them a strong candidate for the next generation of light-emitting materials.Previously,people mainly understood its luminescence from the perspective of carbon materials,but some luminescence mechanisms are still unclear.In this review,we discuss the luminescence mechanism by referring to organic luminescent materials with emphasis on their aggregation behavior.Firstly,three representative aggregate luminescence phenomena of organic luminescent materials are briefly introduced.Chromophores present in CPDs are elaborated to further discuss the potential interactions between them,with emphasis on the role of crosslinked polymer networks.On this basis,some special luminescence phenomena of CPDs in the aggregate state are summarized,and relevant mechanisms are discussed in detail to consolidate relevant statements. | Chunyuan Kang Songyuan Tao Fan Yang Bai Yang | 2022 | Aggregate2022，3，2： | 2 |
| 19 | A multistep attachment process:Transformation of titanate nanotubes into nanoribbons显示文摘The mechanism of the conversion of titanate nanotubes into nanoribbons is of considerable interest.The details of the transformation processes involved when nanoribbons are produced from a P25 TiO 2 powder precursor by alkaline hydrothermal treatment have been investigated systematically by transmission electron microscopy.A multistep attachment model is proposed for the growth at the early stage of coarsening.The treatment duration has a strong effect on the change in product morphology from hollow nanotubes into nanoribbons,since the nanotubes cannot retain their morphology in the strong alkaline solution for extended periods of time.Most of the nanotubes were etched and dissolved,providing the nutrients for subsequent nanoribbon growth.Some stable nanotubes grew spirally internally to form nanowires or became connected together to form rafts which acted as the grains for nanoribbon growth.With increasing hydrothermal time,a large number of nanotubes and other fragments became attached to the grains which began to grow larger and eventually formed the nanoribbons,in a process in which the stepped faces and kinked faces became fused and were eliminated while the flat faces were retained in the nanoribbon morphology. | SHENG Jiang HU LinHua MO Li'E LI WenXin TIAN HuaJun DAI SongYuan | 2012 | Science China Chemistry2012，55，3： | 2 |
| 20 | In-situ grown CuO_(x)nanowire forest on copper foam:A 3D hierarchical and freestanding electrocatalyst with enhanced carbonaceous product selectivity in CO_(2)reduction显示文摘Electrocatalytic carbon dioxide(CO_(2))reduction is considered as an economical and environmentally friendly approach to neutralizing and recycling greenhouse gas CO_(2).However,the design of preeminent and robust electrocatalysts for CO_(2)electroreduction is still challenging.Herein,we report the in-situ growth of dense CuO_(x)nanowire forest on 3D porous Cu foam(CuO_(x)-NWF@Cu-F),which can be directly applied as a freestanding and binder-free working electrode for highly effective electrocatalytic CO_(2)reduction.By adjusting the surface morphology and chemical composition of CuO_(x)nanowires via surface reconstruction,large electrochemically active surface area and abundant Cu(+1)sites were generated,leading to remarkable activity for CO_(2)electroreduction.The as-prepared hierarchical conductive electrode exhibited an enhanced Faradaic efficiency of 15.0%for ethanol formation(FE_(C_(2)H_(5)OH))and a total Faradaic efficiency of 69.4%for all carbonaceous compounds(FE_(C-total))at a mild applied potential of–0.45 V vs.RHE in 0.1 M KHCO_(3)electrolyte.It achieved a 4-fold increase in FE_(C-total)than that of Cu nanowire forest supported on 3D porous Cu foam(Cu-NWF@Cu-F)obtained by in-situ reduction of the CuO_(x)-NWF@Cu-F via annealing at H_(2)atmosphere,and thereby effectively suppressed the hydrogen evolution side-reaction. | Wenjun Zhang Minghang Jiang Songyuan Yang Yi Hu Bin Mu Zuoxiu Tie Zhong Jin | 2022 | Nano Research Energy2022，1，3： | 2 |
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