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| 1 | Enhanced microwave absorption performance of highly dispersed CoNi nanostructures arrayed on graphene显示文摘 | Genban Sun Hong Wu Qingliang Liao Yue Zhang | 2018 | Nano Research2018，11，5： | 11 |
| 2 | Ordered two-dimensional porous Co3O4 nanosheets as electrocatalysts for rechargeable Li-O2 batteries显示文摘Lithium-oxygen batteries have attracted considerable interest in the past a few years, because they have higher theoretical specific energy than Li-ion batteries. However, the available en ergy den sities of the Li-O2 batteries are much less than expected. It is particularly urgent to find catalyst with high activity. Herein, a series of Co3O4 with differe nt morphologies (ordered two-dimensio nal porous nano sheets, flowerlike and cuboidlike) were successfully prepared through facile hydrothermal and calcinatio n methods. Ordered two-dime nsional Co3O4 nano sheets show the best cycling stability. Detailed experimental results reveal that the superiority of the unique two-dimensional uniform porous structures is vital for Li-O2 batteries cathode catalysts. Due to the ordered structures with high surface areas and active sites, the catalysts indicate a high specific discharge capacity of about 10,417 mAh/g at a current density of 200 mA/g, and steadily cycle for more than 50 times with a limited capacity of 1,000 mAh/g. | Yu Zhang Mingzhen Hu Mengwei Yuan Genban Sun Yufeng Li Kebin Zhou Chen Chen Caiyun Nan Yadong Li | 2019 | Nano Research2019，12，2： | 3 |
| 3 | In situ decoration of nanosized metal oxide on highly conductive MXene nanosheets as efficient catalyst for Li-O2 battery显示文摘Combining nanomaterials with complementary properties in a well-designed structure is an effective tactic to exploit multifunctional, high-performance materials for the energy conversion and storage. Nonprecious metal catalysts, such as cobalt oxide, with superior activity and excellent stability to other catalysts are widely desired. Nevertheless, the performance of CoO nanoparticles as an electrode material were significantly limit for its inferior conductivity, dissolution, and high cohesion. Herein, we grow ultrafine cobalt monoxide to decorate the interlayer and surface of the Ti3C2 Txnanosheets via a hydrothermal method companied by calcination. The layered MXenes act as the underlying conductive substrate,which not only increase the electron transfer rate at the interface but also greatly improve the electrochemical properties of the nanosized Co O particles by restricting the aggregation of CoO. The resulting CoO/Ti3C2 Txnanomaterial is applied as oxygen electrode for lithium-oxygen battery and achieves more than 160 cycles and first cycle capacity of 16,220 mAh g-1 at 100 mA g-1. This work paves a promising avenue for constructing a bi-functional catalyst by coupling the active component of a transition metal oxide(TMO) with the MXene materials in lithium-oxygen battery. | Xingyu Li Caiying Wen Huifeng Li Genban Sun | 2020 | Journal of Energy Chemistry2020，29，8： | 3 |
| 4 | Ultrathin hexagonal boron nitride as a van der Waals,force initiator activated graphene for engineering efficient non-metal electrocatalysts of Li-CO_(2) battery显示文摘Reasonably regulating electronic coupling to promote charge transfer and exciton separation has been regarded a promising approach in catalysis.The material engineering of van der Waals heterojunction(vdWsH)based on two-dimensional(2D)materials would be a potential way to optimize the as-prepared extrinsic physicochemical characteristics.However,it was still an almost uncultivated land waiting for exploration in catalysis.Herein,we introduced the inert h-boron nitride(h-BN)in non-metal reduced graphene oxide(GN)catalysts and constructed BN-GN vdWsH.The theoretical calculation demonstrated that the h-BN can effectively modify the electronic properties of graphene.With the introduction of h-BN,the BN-GN vdWsH can obviously enhance the catalytic activity of Li-CO_(2) battery.The existence of BN-GN vdWsH can reduce the overpotential more than 700 mV compared with reduced graphene oxide during the CO_(2) reduction reaction(CO_(2)RR)and CO_(2) evolution reaction(CO_(2)ER),and it extended cyclic stability more than three times,which was one structure design made it work as a high efficient electrocatalyst,catalytic materials. | Zemin Sun Di Wang Liu Lin Yuhui Liu Mengwei Yuan Caiyun Nan Huifeng Li Genban Sun Xiaojing Yang | 2022 | Nano Research2022，15，2： | 3 |
| 5 | Ultralong cycle life enabled by in situ growth of CoMo_(1-x)P/Mo heterostructure for lithium-sulfur batteries显示文摘Lithium-sulfur batteries(Li-S batteries) are considered as promising new-generation electrochemical energy storage devices due to their extremely high theoretical energy density(2600 Wh kg-1) and theoretical specific capacity(1675 m Ah g^(-1)). However, numerous problems such as poor conductivity and the shuttle effect during discharge-charge process limit the practical application of lithium-sulfur batteries. In this work, porous tubular Co Mo_(1-x)P/Mo constructed by in situ growth of metal Mo was designed as the sulfur host for lithium-sulfur batteries. The introduction of Mo modulated the electronic structure of Co Mo P to improve the conductivity of cathode and facilitate the redox kinetics, as well as the Co Mo_(1-x)P/Mo heterostructure was beneficial to inhibit the shuttle effect through the interaction with lithium polysulfides, which improved cycling stability. As a result, Co Mo_(1-x)P/Mo/S cathode had a low-capacity decay rate of only 0.029% per cycle after 2000 cycles at 0.5 C. This work provided a new perspective for the further design of high-performance lithium-sulfur battery cathode materials. | Donghua Guo Mengwei Yuan Xingzi Zheng Miaomiao Li Caiyun Nan Genban Sun Xianqiang Huang Huifeng Li | 2022 | Journal of Energy Chemistry2022，31，10： | 2 |
| 6 | Nanostructured Ni/Ti3C2Tx MXene hybrid as cathode for lithium-oxygen battery显示文摘Ti3C2 belongs to MXenes family,which is a new two-dimensional material and has been applied in many fields.With simple method of hydrothermal and high temperature calcination,nano structured Ni/Ti3C2Tx hybrid was synthesized.The stable layer structure of Ti3C2 MXene providing high surface area as well as excellent electronic conductivity are beneficial for deposition and decomposition of discharge product Li2O2.Furthermore,possessing special catalytic activity,Ni nanoparticles with size of about 20 nm could accelerate Li2O2 breaking down.Taking advantage of two kinds of materials,Ni/Ti3C2Tx hybrid as cathode of Li-O2 battery can achieve a maximal specific capacity of 20,264 mAh/g in 100 mA/g and 10,699 mAh/g in 500 mA/g at the first cycle.This work confirms that the prepared Ni/Ti3C2Tx hybrid exhibiting better cycling stability points out a new guideline to improve the electrochemical performance of lithium-oxygen batteries. | Caiying Wen Tianjiao Zhu Xingyu Li Huifeng Li Xianqiang Huang Genban Sun | 2020 | Chinese Chemical Letters2020，31，4： | 2 |
| 7 | The synthesis and photoluminescent properties of calcium tungstate nanocrystals显示文摘 | Lingna Sun Minhua Cao Yonghui Wang Genban Sun Changwen Hu | 2005 | Journal of Crystal Growth2005，，1： | 1 |
| 8 | Self-Catalyzed Rechargeable Lithium-Air Battery by in situ Metal Ion Doping of Discharge Products: A Combined Theoretical and Experimental Study显示文摘Lithium-air battery has emerged as a viable electrochemical energy technology;yet a substantial overpotential is typically observed,due to the insulating nature of the discharge product Li_(2)O_(2) that hinders the reaction kinetics and device performance.Furthermore,finite solid–solid/-liquid interfaces are formed between Li_(2)O_(2) and catalysts and limit the activity of the electrocatalysts in battery reactions,leading to inadequate electrolytic efficiency.Herein,in-situ doping of Li_(2)O_(2) by select metal ions is found to significantly enhance the lithium-air battery performance,and Co^(2+)stands out as the most effective dopant among the series.This is ascribed to the unique catalytic activity of the resulting Co-O_(x) sites towards oxygen electrocatalysis,rendering the lithium-air battery self-catalytically active.Theoretical studies based on density functional theory calculations show that structural compression occurs upon Co^(2+)doping,which lowers the energy barrier of Li_(2)O_(2) decomposition.Results from this study highlight the significance of in situ electrochemical doping of the discharge product in enhancing the performance of lithium-air battery. | Mengwei Yuan Zemin Sun Han Yang Di Wang Qiming Liu Caiyun Nan Huifeng Li Genban Sun Shaowei Chen | 2023 | Energy & Environmental Materials2023，6，1： | 1 |
| 9 | Anionic surfac-tantassisted hydrothermal synthesis of high-aspect-ratio ZnO nanowires and their photoluminescence property显示文摘 | Sun Genban Cao Minhua Wang Yonghui | 2006 | Materials Letters2006，60，21： | 1 |
| 10 | Hierarchical Dendrite-Like Magnetic Materials of Fe3O4,gamma- Fe2O3, and Fe with High Performance of Microwave Absorption显示文摘 | Sun Genban Dong Bingxiang Cao Minhua | 2011 | Chemistry of Materials2011，23，6： | 1 |
| 11 | Rational design of hollow rice-grainedα-Fe_(2)O_(3)/carbon nanofibers with optimized impedance matching for electromagnetic wave absorption enhanced显示文摘Electromagnetic wave absorption materials are widely used in electronic equipment and military fields.However,high cost and complex preparation processes become a major obstacle in promoting popularization in the civil field.To solve the problems above,researchers have made great efforts to develop Fe-based carbon composites.However,most of the typical composites require a high filling ratio while achieving excellent properties.Therefore,in this study,carbon nanofibers(CNFs)combined with the hollow rice-grainedα-Fe_(2)O_(3)nanoparticles were prepared by the in-situ transformation method.The rational microstructure design provided a solution for reducing the filling ratio,optimizing impedance matching,and improving electromagnetic wave absorption performance.The strong reflection loss value(−38.1 dB)and broad effective absorption bandwidth(4.6 GHz)for Fe_(2)O_(3)/CNFs composites were achieved with a low filling ratio(20 wt.%),and the analysis of electromagnetic parameters validated that the microstructure of Fe_(2)O_(3)/CNFs plays a crucial role in the performance improvement.With the optimized impedance matching and simple preparation method,Fe_(2)O_(3)/CNFs have broad application prospects in electromagnetic wave absorption. | Jingshen Xu Na Lu Mengwei Yuan Genban Sun | 2023 | Nano Research2023，16，4： | 1 |
| 12 | In situ decoration of CoP/Ti_(3)C_(2)Tx composite as efficient electrocatalyst for Li-oxygen battery显示文摘Application of Li-oxygen(Li-O_(2)) battery is in urgent need of bifunctional ORR/OER electrocatalyst. A surface-functionalization CoP/Ti_(3)C_(2)Txcomposite was fabricated theoretically, with the optimized electronic structure and more active electron, which is beneficial to the electrochemical reaction. The accordion shaped Ti_(3)C_(2)Txis featured with large specific surface area and outstanding electronic conductivity, which is beneficial for the adequate exposure of active sites and the deposition of Li2O2. Transition metal phosphides provide more electrocatalytic active sites and present good electrocatalytic effect. The CoP/Ti_(3)C_(2)Txcomposite served as the electrocatalyst of Li-O_(2)battery reaches a high specific discharge capacity of 17,413 m Ah/g at 100 m A/g and the lower overpotential of 1.25 V, superior to those of the CoP and Ti_(3)C_(2)Txindividually. The composite of transition metal phosphides and MXene are applied in Li-O_(2)battery, not only demonstrating higher cycling stability of the prepared CoP/Ti_(3)C_(2)Txcomposite, but pointing out the direction for their electrochemical performance improvement. | Xingzi Zheng Mengwei Yuan Xianqiang Huang Huifeng Li Genban Sun | 2023 | Chinese Chemical Letters2023，34，1： | 1 |
| 13 | Coupling interface constructions of hollow Co-Mo mixed multiple oxidation states heterostructure for high-performance aprotic Li-O_(2) battery显示文摘Constructing interfaces in heterostructures is effective for modulating the electronic properties of electrocatalysts.The hollow CoMoO_(4)-Co_(3)O_(4) heterostructure(HCMCH)was prepared as a bifunctional electrocatalyst for Li-O_(2) battery.The different components in CoMoO_(4)-Co_(3)O_(4) heterostructure presented the efficient coupling and enhanced the electrocatalytic activity for aprotic oxygen reduction reaction(ORR)and oxygen evolution reaction(OER),in which it improved the obviously reduced overpotential of 300 mV(compared with the pure Ketjen black(KB)electrode),enhanced reversibility of 80%capacity retention after 6 full cycles and the superior cyclability of more than 200 cycles with an optimized strategy.The battery performance of the HCMCH was not only associated with the unique hollow structure and rich active sites but also with coupling interface constructions synergetic effects attaching to the improving conductivity and optimized the discharge conversion.These results suggested that this HCMCH electrocatalyst was a promising candidate for the Li-O_(2) battery and it gave a novel insight for high performance electrocatalyst designing. | Xingzi Zheng Mengwei Yuan Jingshen Xu Zihan Li Caiyun Nan Genban Sun | 2024 | Nano Research2024，17，5： | 0 |
| 14 | Flower-like CuS/γ-Fe_(2)O_(3) van der Waals heterostructures with highefficient electromagnetic wave absorption显示文摘The escalating electromagnetic(EM)pollution issues and the demand to elevate military stealth technology make it imperative to develop cost-effective and high-performance electromagnetic wave(EMW)absorbing materials.In this paper,the flower-like CuS/γ-Fe_(2)O_(3) van der Waals(vdW)heterostructures have been synthesized via a facile two-step solvothermal approach.The flower-like CuS skeleton increases the attenuation path of EMW while reducing the material density.Different contents ofγ-Fe_(2)O_(3) nanoparticles anchor between the flower-like CuS nanosheets to constitute a heterogeneous structure,which enables dielectric and magnetic loss synergistically to optimize impedance matching and remarkably improve the EMW absorption performance.The minimum reflection loss(RLmin)is-49.36 dB with a thickness of only 1.6 mm and the effective absorption bandwidth(EAB)reaches 4.64 GHz(13.36–18 GHz).By adjusting the thickness of the absorber,the EAB can cover 96%of the GHz band.Notably,the superior absorption of-61.53 dB at middle frequency band can be obtained by adjusting the amount of Fe_(2)O_(3) addition.In this study,the adjustment of EM parameters and the optimization of impedance matching have been achieved by constructing a novel vdW heterogeneous structure,which provides fresh ideas and references for the design of high-performance EMW absorbing materials. | Na Lu Jingshen Xu Mengwei Yuan Genban Sun | 2024 | Nano Research2024，17，4： | 0 |
| 15 | Hollow catalysts through different etching treatments to improve active sites and oxygen vacancies for high-performance Li-O_(2)battery显示文摘Li-O_(2)batteries are regarded as one of the most promising next-generation battery systems due to their high theoretical energy density,finding effective cathode catalysts with fine-tuned structure is a key way to improve the performance.Herein,based on the structure of cubic zeolitic imidazolate framework-67(ZIF-67),a series of hollow catalysts were synthesized by different chemical etching treatments.Firstly,from the perspective of metal,nickel nitrate is used for etching,hollow Ni ZIF is obtained through Kirkendall effect.Secondly,hollow TA-ZIF is obtained by adding tannic acid to replace the methylimidazole ligand.Hollow structures have larger surface areas,materials can expose more active sites,which can lead to better performance of Li-O_(2)batteries.On this basis,having more oxygen vacancies can also improve the battery performance.At the same time,further loading noble metal ruthenium on the synthesized cobalt-based catalyst can effectively reduce the overpotential of Li-O_(2)battery and improve the battery performance.For TA-ZIF with more stable hollow structure and more oxygen vacancies,the cycle performance reaches 330 cycles after loading Ru.Compared with the 64 cycles of solid Co_(3)O_(4),it has a great improvement. | Jiachen Qiu Yuran Lin Shuting Zhang Jie Ma Yu Zhang Mengwei Yuan Genban Sun Caiyun Nan | 2023 | Nano Research2023，16，5： | 0 |
| 16 | Recent progress in cathodic reduction-enabled organic electrosynthesis: Trends, challenges, and opportunities显示文摘Compared with general redox chemistry,electrochemistry using the electron as a potent,controllable,yet traceless alternative to chemical oxidants/reductants usually offers more sustainable options for achieving selective organic synthesis.With its environmentally benign features gradually being uncovered and studied,organic electrosynthesis is currently undergoing a revival and becoming a rapidly growing area within the synthetic community.Among the electrochemical transformations,the anodically enabled ones have been far more extensively exploited than those driven by cathodic reduction,although both approaches are conceptually attractive.To stimulate the development of cathodically enabled organic reactions,this review summarizes the recently developed reductive electrosynthetic protocols,discussing and highlighting reaction features,substrate scopes,applications,and plausible mechanisms to reveal the recent trends in this area.Herein,cathodic reduction-enabled preparative organic transformations are categorized into four types:reduction of(1)unsaturated hydrocarbons,(2)heteroatom-containing carbon-based unsaturated systems,(3)saturated C-hetero or C–C polar/strained bonds,and(4)hetero-hetero linkages.Apart from net electroreductive reactions,a few examples of reductive photo-electrosynthesis as well as paired electrolysis are also introduced,which offer opportunities to overcome certain limitations and improve synthetic versatility.The electrochemically driven,transition metal-catalyzed reductive cross-couplings that have been comprehensively discussed in several other recent reviews are not included here. | Binbin Huang Zemin Sun Genban Sun | 2022 | eScience2022，2，3： | 0 |
| 17 | Corrigendum to'In situ decoration of nanosized metal oxide on highly conductive MXene nanosheets as efficient catalyst for Li-O2 battery'[J.Energy.Chem.47(2020)272-280]显示文摘The authors regret that the printed version of the above article contained some errors.(1)In the original edition of Fig.5(b),the black and red chargedischarge curves represent the opposite current density.The red and black curve should represent the charge-discharge profiles at current densities of 100 and 500 mA g-1,respectively. | Xingyu Li Caiying Wen Huifeng Li Genban Sun | 2021 | Journal of Energy Chemistry2021，30，5： | 0 |
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