| 1 | Petrogenetic contrastive studies on the Mesozoic early stage ore-bearing and late stage ore-barren granites from the southern Anhui Province显示文摘Yanshanian magmatisms are intensive in the southern Anhui Province and can be divided into early(152–137 Ma)and late(136–122 Ma) stages. A Yanshanian granitic zone was found to crop out along Qingshan to Changgai areas in the Tunxi district in Field investigation which has a genetic link with molybdenum multiple metal mineralization. To be a representative syenitic granite in the southern Anhui Province, the Huangshan pluton has not been found so far to have any genetic link with mineralization. Zircon LA-ICP-MS dating indicate that the four granitic bodies from the Qingshan-Changgai zone have concurrent formed ages from 140±4 to 141±2 Ma, belonging to the Yanshanian early stage magmatism. However, the Huangshan granite is dated to be 129±2 Ma, belonging to the Yanshanian late stage magmatism. The Qingshan-Changgai granites show high SiO2 and K2 O contents, low P2O5 contents and middle Al2O3 contents and are high-K calc-alkaline series metaluminum I-type granite. These rocks are characterized by enrichments in the large ion lithophile elements and light rare earth elements(REE), depletions in the high field-strength elements, and middle degree negative anomalies of Eu, geochemical features of arc or continent crustal derived magma affinities. These rocks have 87Sr/86Sr(t) ratios from 0.7120 to 0.7125, εNd(t) values from.7.24 to.4.38 and zircon εHf(t) values of.4.4 to 6.7, similar to that of the coeval ore-bearing granodiorites in the southern Anhui Province. Integrated geochemical studies indicate that the Yanshanian ore-bearing granodiorites were formed by partial melting of the Meso-Neoproterozoic accreted thickened low crust. Meanwhile, the Qingshan-Changgai granites were formed through a AFC process of plagioclase+amphibole+Shangxi Group of magmas that formed the ore-bearing granodiorites. The Huangshan granites are characterized by high SiO2 and K2 O contents, moderate Al2O3 contents, seagull shape REE distributed pattern and distinct Eu negative abnormities. Comparing with the Qingshan-Changgai granites, the Huangshan granites show more Ba, Sr, P,and Ti negative abnormities with no Nb and Ta depletions and are high-K calc-alkaline series metaluminum A-type granite. εHf(t)values of the Huangshan granites are from.6.6 to.1.2, similar to that of the early stage ore-bearing granodiorites, indicating that they were also formed by anatexis of the Meso-Neoproterozoic accreted crust, but their magma sources might be residual granulitic crust which ever underwent Yanshanian early stage I-type intermediate-acid magma extraction. Comparing studies on the two stages granites indicate that the early stage granites derived from a relative thickened low crust under a lower temperature condition. Their magma sources were Meso-Neoproterozoic accreted crust which enriched in ore-forming materials and further became more enriched through processes of magma AFC evolution. However, the late stage A-type granites originated from relative shallow crust under a higher temperature condition. Their magma source was depleted in ore-forming materials due to the early stage magma extraction and thus had weak ore-forming capacity. From early to late stage, the magmatisms tectonic setting translated from post-orogenic to anorogenic and the later corresponded to a back-arc extensional setting as increase of the slab subducted angle of the Paleo-Pacific plate. | YAN Jun HOU TianJie WANG AiGuo WANG DeEn ZHANG DingYuan WENG WangFei LIU JianMin LIU XiaoQiang LI QuanZhong | 2017 | Science China Earth Sciences2017，60，11： | 9 |
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