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| 1 | Synthesis of HTLcs modified by K_(3)PO_(4) for side chain alkylation of toluene with methanol显示文摘A series of calcined HTLcs catalysts were prepared and modified with potassium phosphate by impregnation method to clarify the influence of catalyst alkalinity on the side chain alkylation of toluene with methanol for synthesis of ethylbenzene and styrene.The catalysts were characterized by X-ray diffraction(XRD),N_(2)physical adsorption-desorption,Fourier-transform infrared spectroscopy(FT-IR),Scanning electron microscopy(SEM),X-ray photoelectron spectrometry(XPS),NH_(3)temperature-programmed desorption(NH_(3)-TPD)and CO_(2)temperature-programmed desorption(CO_(2)-TPD).It was found that the selectivity of styrene was highest(39.25%)when the K_(3)PO_(4)loading was 7.5 wt%.And the total yield of styrene and ethylbenzene could reach 65.08%with 10 wt%K_(3)PO_(4)loading.This might due to the fact that the addition of K_(3)PO_(4)could adjust the acid and basic sites of catalysts.In addition,appropriate strength and amount of basic sites were favorable to producing more styrene. | Chunyao Hao Yueli Wen Bin Wang Faraz Ahmad Yuhua Liu Huijun Li Wei Huang | 2021 | Green Energy & Environment2021,6,6: | 6 |
| 2 | Injectable self-healing polysaccharide hydrogel loading CuS and pH-responsive DOX@ZIF-8 nanoparticles for synergistic photothermal-photodynamic-chemo therapy of cancer显示文摘The injectable self-healing polysaccharide hydrogel was prepared by the formation of Schiff base bonds between aldehyde-modified methylcellulose(MC–CHO)and carboxymethyl chitosan(CMC).The copper sulfide nanoparticles(CuS NPs)and pH-sensitive doxorubicin-loaded zeolitic imidazolate frameworks nanoparticles(DOX@ZIF-8 NPs)were prepared and could be well-dispersed into the hydrogel system.The presence of CuS NPs can achieve photothermal therapy(PTT)for tumors under the irradiation of the near-infrared(NIR)laser.Moreover,CuS NPs can generate photodynamic effects under NIR irradiation,converting oxygen into toxic reactive oxygen species(ROS)and presenting efficient photodynamic therapy(PDT).The DOX@ZIF-8 NPs can be decomposed under an intracellular acidic environment and realize the controlled release of DOX.The injectable self-healing hydrogel loading Cu S and DOX@ZIF-8 NPs can achieve synergistic photothermal-photodynamic-chemo therapy for tumors and will inspire the researchers to construct a platform from hydrogel combined with multifunctional nanomaterials to realize the effective multimodal therapy for tumor. | Zhiyi Qian Nuoya Zhao Chunyao Wang Weizhong Yuan | 2022 | Journal of Materials Science & Technology2022,,32: | 2 |
| 3 | Founding team and start-up competitive advantage 显示文摘 | Wu Leiyu Wang Chunju Tseng Chunyao | 2009 | Management Decision2009,47,2: | 1 |
| 4 | Attitude control of apricot during orientation transmission显示文摘The kinetic characteristics of apricots during orientation transmission were studied to provide a basis for improving the structure of the transmission device.Previous studies have generally focused on the development of orientation devices,but few studies have been conducted to analyze the mechanisms of orientation.In order to study the attitude control in the orientation mechanisms,an orthogonal combination test was performed and a rigid kinetic model for a monosymmetric apricot was developed based on Euler’s kinetic equations with the modified Rodrigue parameters(MRPs).Kinetic simulation and analysis based upon the attitude control law were conducted and an attitude control simulation platform was created.The simulation results showed that the orientation transmission system for monosymmetric apricots was globally convergent and tended to stable.The experimental torques also affected the orientation success rates.The calculated average experimental torque value(0.164 N·m)was consistent with the maximum control torque value(0.16478 N·m)when the system was in a stable state in Simulink.The consistency between the simulation result and the calculated control torque validates the correctness of the designed control torques. | Ding Xiangyan Wang Chunyao Huang Chunyang Luo Jianqing | 2016 | International Journal of Agricultural and Biological Engineering2016,9,5: | 1 |
| 5 | On automatic-verification pattern generation for SoC with port-order fault model显示文摘 | | 2002 | IEEE Transactions on Computer-Aided Design of Integrated Circuits and Systems2002,4,: | 1 |
| 6 | 稀有金属材料与工程显示文摘 | Zhan Chunyao(占春耀) Wang Wei(王为) Liu Yangbang(刘扬邦) | 2011 | 40(4):6502011,40,4: | 1 |
| 7 | Coordination environments build up and tune a superior synergistic “genome” toward novel trifunctional (TM-N_(x)O_(4−x))@g- C_(16)N_(3)-H_(3): High-throughput inspection of ultra-high activity for water splitting and oxygen reduction reactions显示文摘Emerging as a prominent area of focus in energy conversion and storage technologies,the development of highly active metal-based single-atom catalysts(SACs)holds great significance in searching alternatives to replace precious metals toward the efficient,stable,and low-cost hydrogen evolution reaction(HER),as well as the oxygen evolution reaction(OER)and the oxygen reduction reaction(ORR).Combining the tremendous tunability of ligand and coordination environment with rich metal-based electrocatalysts can create breakthrough opportunities for achieving both high stability and activity.Herein,we propose a novel and stable holey graphene-like carbon nitride monolayer g-C_(16)N5(N_(4)@g-C_(16)N_(3))stoichiometries interestingly behaving as a natural substrate for constructing SACs((TM-N_(4))@g-C_(16)N_(3)),whose evenly distributed holes map rich and uniform nitrogen coordination positions with electron-rich lone pairs for anchoring transition metal(TM)atoms.Then,we employed density functional theory(DFT)calculations to systematically investigate the electrocatalytic activity of(TM-N_(4))@g-C_(16)N_(3) toward HER/OER/ORR,meanwhile considering the synergistic modulation of H-loading and O-coordination((TM-N_(x)O_(4-x))@g-C_(16)N_(3)^(-)H_(3),x=0–4).Together a“four-step procedure”screening mechanism with the first-principles high-throughput calculations,we find that(Rh-N_(4))and(Ir-N_(2)O_(2)-II)distributed on g-C_(16)N_(3)^(-)H_(3) can modulate the adsorption strength of the adsorbates,thus achieving the best HER/OER/ORR performance among 216 candidates,and the lowest overpotential of 0.098/0.3/0.46 V and 0.06/0.48/0.45 V,respectively.Additionally,the d-band center,crystal orbital Hamilton population(COHP),and molecular orbitals are used to reveal the OER/ORR activity source.Particularly,the Rh/Ir-d orbital is dramatically hybridized with the O-p orbital of the oxygenated adsorbates,so that the lone-electrons incipiently locate at the antibonding orbital pair up and populate the downward bonding orbital,allowing oxygenated intermediates to be adsorbed onto(TM-N_(x)O_(4-x))@g-C_(16)N_(3)^(-)H_(3) appropriately. | Chunyao Fang Xian Wang Qiang Zhang Xihang Zhang Chenglong Shi Jingcheng Xu Mengyu Yang | 2024 | Nano Research2024,17,4: | 0 |
| 8 | Practical Teaching Reforms of Engineering Management Major for Applied Talents显示文摘This paper is an overview of the practical teaching system of engineering management,applied training direction,and the current situation of practical teaching practice in engineering management.This paper mainly discusses the new ideas of practical teaching reforms in engineering management courses,and it is hoped that the contents in this paper can provide some help in improving practical teaching of engineering management teachers. | Liu Jianxin Deng Chunyao Wang Xuedong Guan Zhiwen | 2018 | Journal of Contemporary Educational Research2018,2,5: | 0 |