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52篇 您的检索式:作者名="Williams HL"
    题名 作者 年代 出处 被引量
1Estimation of Time to Maximum Rate Under Adiabatic Conditions(TMR_(ad)) Using Kinetic Parameters Derived From DSC-Investigation of Thermal Behavior of 3-Methyl-4-Nitrophenol显示文摘Kinetic parameters of the decomposition of hazardous chemicals can be applied for the estimation of their thermal behavior under any temperature profile.Presented paper describes the application of the advanced kinetic approach for the determination of the thermal behavior also under adiabatic conditions occurring e.g.in batch reactors in case of cooling failure.The kinetics of the decomposition of different samples(different manufacturers and batches) of 3-methyl-4-nitrophenol were investigated by conventional DSC in non-isothermal(few heating rates varying from 0.25 to 8.0K/min) and isothermal(range of 200~260℃) modes.The kinetic parameters obtained with AKTS-Thermokinetics Software were applied for calculating reaction rate and progress under different heating rates and temperatures and verified by comparing simulated and experimental signals.After application of the heat balance to compare the amount of heat generated during reaction and its removal from the system,the knowledge of reaction rate at any temperature profiles allowed the determination of the temperature increase due to the self-heating in adiabatic and pseudo-adiabatic conditions.Applied advanced kinetic approach allowed simulation the course of the Heat-Wait-Search(HWS) mode of operation of adiabatic calorimeters.The thermal safety diagram depicting dependence of Time to Maximum Rate(TMR) on the initial temperature was calculated and compared with the results of HWS experiments carried out in the system with Ф-factor amounting to 3.2.The influence of the Ф-factor and reaction progress reached at the end of the HWS monitoring on the TMR is discussed.Presented calculations clearly indicate that even very minor reaction progress reduces the TMRad of 24h characteristic for a sample with initial reaction progress amounting to zero.Described estimation method can be verified by just one HWS-ARC,or by one correctly chosen ISO-ARC run of reasonable duration by knowing in advance the dependence of the TMR on the initial temperature for any Ф-factor.Proposed procedure results in significant shortening of the measuring time compared to a safety hazard approach based on series of ARC experiments carried out at the beginning of a process safety evaluation.Bertrand Roduit Patrick Folly Alexandre Sarbach Beat Berger Franz Brogli Francesco Mascarello Mischa Schwaninger Thomas Glarner Eberhard Irle Fritz Tobler Jacques Wiss Markus Luginbühl Craig Williams Pierre Reuse Francis Stoessel 2011化学推进剂与高分子材料2011,9,1:3
2Oral niacin prevents photocarcinogenesis and photoimmunosuppression in mice 显示文摘Gensler HL Williams T Huang AC 1999Nutr Cancer1999,34,1:1
3Septicemia due to Klebsiella pneumonia originating from a hand cream dispenser 显示文摘Morse LJ Williams HL Grenn FP 1967New Engl J Med1967,277,:1
4Stem cells in lung development, disease, and therapy显示文摘Mason RJ Williams MC Moses HL 1997Am J Respir Cell Mol Biol1997,16,4:1
5Polyglutamine neurodegeneration:protein misfolding revisited显示文摘Williams AJ Paulson HL 2008Trends Neurosci2008,31,10:1
6Stem cells in lung development,disease,and therapy 显示文摘Mason RJ Williams MC Moses HL 1997Am J Respir Cell Mol Biol1997,16,4:1
7The red imported fire ant(Hymenoptera: Formicidae): an historical perspective of treatment programs and the development of chemical baits for control 显示文摘Williams DF Collins HL Oi DH 2001American Entomologist2001,7,:1
8Update on the management of Tl renal cortical tumours显示文摘Cutress ML Ratan HL Williams ST 2010British Journal of Urology International2010,,08:1
9Role of taste and calories in the selection of ethanol by C57BL/6NHsd and Hsd: ICR mice显示文摘McMillen BA Williams HL 1998Alcohol1998,15,3:1
10Anticoagulation with warfarin in vitreoretinal surgery显示文摘Fu AD McDonald HR Williams DF Cantrill HL Ryan EH Jr Johnson RN 2007Retina2007,27,3:1
11Stress-stain Properties of Linear Aromatic Polyesters in the Nonlinear Viscoelastic Range显示文摘Ng TH Williams HL 1986Journal of Applied Polymer Science1986,32,:1
12Use of chronic epilepsy models in antiepileptic drug discovery:the effect of topiramate on spontaneous motor seizures in rats with kainate-induced epilepsy显示文摘Grabenstatter HL Ferraro DJ Williams PA 2005Epilepsia2005,46,1:1
13Stem cells in lung development, disease, and therapy显示文摘Mason RJ Williams MC Moses HL 1997Am J Respir Cell Mol Biol1997,16,4:1
14Use of chronic epilepsy models in antiepileptic drug discovery:,the effect of topiramate on spontaneous motor seizures in rats with kainate-induced epilepsy显示文摘 Ferraro DJ Williams PA etal 2005Epilepsia2005,46,1:1
15Antibody-targeted chemotherapy for the treatment of relapsed acute myeloid leukemia显示文摘Williams JP ttandler HL 2000Am J Manag Care2000,6,18:1
16The effects of sucralfate upon phenytoin absorption in man显示文摘Smart HL Somerville KW Williams J 1985Br J Clin Pharmacol1985,20,3:1
17Antibody-targeted chemotherapy for the treatment of relapsed acute myeloid leukemia显示文摘Williams JP Handler HL 2000Am J Manag Care2000,6,18:1
18Direce measurement of cognitive deficit in schizophrenia 显示文摘Lubin A Gieseking CF Williams HL 1962J Consuit Psychol1962,26,:1
19Glial glutamate transporter expression patterns in brains from multiple mammalian species 显示文摘Williams SM Sullivan RK Scott HL 2005Glia2005,49,4:1
20The psychological well- being and self - efficacy of carers of children with disabilities following attendance on a simple massage training and support prograrnme:A 12-month comparison study of adherers and non-adherers显示文摘Williams HL Cullen LA Barlow H 2005Complementary Therapies in Medicine2005,13,:1
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