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| 1 | In situ boron isotope measurements of natural geological materials by LA-MC-ICP-MS显示文摘There are two main methods to determine boron isotopic composition.One is the solution method,in which boron is purified after the samples are dissolved in solution and the boron isotope ratios are determined by thermal ionization mass spectrometry(P-TIMS and N-TIMS) or multicollector inductively coupled plasma mass spectrometry(MC-ICP-MS).The other is an in-situ analysis method,in which the in-situ boron isotopic ratios in minerals are analyzed directly using secondary ion mass spectrometry(SIMS) or laser ablation multicollector inductively coupled plasma mass spectrometry(LA-MC-ICP-MS).In the in-situ analysis method for boron isotopes,the multifarious chemical purification and separation processes of the solution method are avoided,with increased work efficiency.In addition,the microzones and microbeddings of minerals can be analyzed in-situ to reveal the fine processes and conditions of mineral formation.In this study,using the standard-sample-bracketing(SSB) method,mass bias of the instrument and the fractionation of isotopes were calibrated,and the in-situ determination method of LA-MC-ICP-MS for boron isotopes was established.Through detailed analyses on a series of boron isotope standards and samples,a matrix effect was assessed but not detected,and the analysis results were in accordance with the formerly reported values or P-TIMS determined values,within the error range.The analytical results for IAEA B4 and IMR RB1 with relatively high boron contents were δ 11B =-(8.36±0.58)‰(2σ,n=50) and δ 11B =-(12.96±0.97)‰(2σ,n=57),respectively;the analytical result for IAEA B6 with rela-tively low boron content was δ 11B =-(3.29±1.12)‰(2σ,n=35).In-situ measurements for B isotopes were performed on geo-logical samples such as tourmaline,ulexite,ludwigite,inyoite and ascharite,with the results consistent with those determined by P-TIMS,within the error range. | HOU KeJun LI YanHe XIAO YingKai LIU Feng TIAN YouRong | 2010 | Chinese Science Bulletin2010，55，29： | 13 |
| 2 | Chromosome-level genome of Himalayan yew provides insights into the origin and evolution of the paclitaxel biosynthetic pathway显示文摘Taxus,commonly known as yew,is a well-known gymnosperm with great ornamental and medicinal value.In this study,by assembling a chromosome-level genome of the Himalayan yew(Taxus wallichiana)with 10.9 Gb in 12 chromosomes,we revealed that tandem duplication acts as the driving force of gene family evolution in the yew genome,resulting in the main genes for paclitaxel biosynthesis,i.e.those encoding the taxadiene synthase,P450s,and transferases,being clustered on the same chromosome.The tandem duplication may also provide genetic resources for the nature to sculpt the core structure of taxoids at different positions and subsequently establish the complex pathway of paclitaxel by neofunctionalization.Furthermore,we confirmed that there are two genes in the cluster encoding isoenzymes of a known enzyme in the paclitaxel biosynthetic pathway.The reference genome of the Himalayan yew will serve as a platform for decoding the complete biosynthetic pathway of paclitaxel and understanding the chemodi-versity of taxoids in gymnosperms. | Jian Cheng Xiao Wang Xiaonan Liu Xiaoxi Zhu Zihe Li Huanyu Chu Qian Wang QianQian Lou Bijun Cai Yiqun Yang Xiaoyun Lu Kai Peng Dingyu Liu Yuwan Liu Lina Lu Huan Liu Ting Yang Qijin Ge Chengcheng Shi Guichun Liu Zhiwei Dong Xun Xu Wen Wang Huifeng Jiang Yanhe Ma | 2021 | Molecular Plant2021，14，7： | 6 |
| 3 | Synthesis of mesoporous ZnO nanowires through a simple in situ precipitation method 显示文摘 | XIAO Yanhe LI Liang LI Yan | 2005 | Nanotechnology2005，16，6： | 1 |
| 4 | Efficient removal of uranium from aqueous solution by zero-valent iron nanoparticle and its graphene composite显示文摘 | LI Zi-jie WANG Lin YUAN Li-yong XIAO Cheng-liang MEI Lei ZHENG Li-Rong ZHANG Jing YANH Ju-hua ZHAO Yu-liang ZHU Zhen-tai CHAI Zhi-fang SHI Wei-qun | 2015 | Journal of Hazardous Materials2015，，290： | 1 |
| 5 | Two-dimensional layered In_(2)P_(3)S_(9): A novel superior anode material for sodium-ion batteries显示文摘Developing reliable and efficient anode materials is essential for the successfully practical application of sodium-ion batteries.Herein,employing a straightforward and rapid chemical vapor deposition technique,two-dimensional layered ternary indium phosphorus sulfide(In_(2)P_(3)S_(9)) nanosheets are prepared.The layered structure and ternary composition of the In_(2)P_(3)S_(9) electrode result in impressive electrochemical performance,including a high reversible capacity of 704 mA h g^(-1) at 0.1 A g^(-1),an outstanding rate capability with 425 mA h g^(-1) at 5 A g^(-1),and an exceptional cycling stability with a capacity retention of88% after 350 cycles at 1 A g^(-1).Furthermore,sodium-ion full cell also affords a high capacity of 308 and114 mA h g^(-1) at 0.1 and 5 A g^(-1).Ex-situ X-ray diffraction and ex-situ high-resolution transmission electron microscopy tests are conducted to investigate the underlying Na-storage mechanism of In_(2)P_(3)S_(9).The results reveal that during the first cycle,the P-S bond is broken to form the elemental P and In_(2)S_(3),collectively contributing to a remarkably high reversible specific capacity.The excellent electrochemical energy storage results corroborate the practical application potential of In_(2)P_(3)S_(9) for sodium-ion batteries. | Longsheng Zhong Hongneng Chen Yanzhe Sheng Yiting Sun Yanhe Xiao Baochang Cheng Shuijin Lei | 2024 | Journal of Energy Chemistry2024，90，3： | 0 |
| 6 | Synergistic engineering of cobalt selenide and biomass-derived S,N,P co-doped hierarchical porous carbon for modulation of stable Li-S batteries显示文摘Hierarchical porous carbon co-doped with heterogeneous atoms has attracted much attention thanks to sizable internal void space accommodating electrolyte,high-density microporous structure physically con-fining polysulfides(LPS),and heterogeneous atoms serving as active sites to capture LPS.However,solely relying on carbon material defects to capture LPS proves ineffective.Hence,metal compounds must be introduced to chemisorb LPS.Herein,cobalt ions are in-situ grown on the polydopamine layer coated on the surface of biomass-derived S,N,P co-doped hierarchical porous carbon(SNP-PC).Then a layer of nitrogen-doped porous carbon(MPC)dotted with CoSe nanoparticles is acquired by selenizing.Thus,a strong-polar/weak-polar composite material of SNP-PC studded with CoSe nanoparticles is obtained(SNP-PC@MPC@CoSe).Button cells assembled with SNP-PC@MPC@CoSe-modified separator enable superb long-cycle stability and satisfactory rate performance.An excellent rate capacity of 796 mAh g^(−1)at a high current rate of 4 C with an ultra-low capacity fading of 0.06%over 700 cycles can be acquired.More impressively,even in a harsh test condition of 5.65 mg cm^(−2)sulfur loading and 4μL mg^(−1)ratio of electrolyte to active materials,the battery can still display a specific capacity of 980 mAh g^(−1)(area capacity of∼5.54 mAh cm^(−2))at 0.1 C.This work provides a promising route toward high-performance Li-S batteries. | Yang Lin Song He Zhiyong Ouyang Jianchao Li Jie Zhao Yanhe Xiao Shuijin Lei Baochang Cheng | 2023 | Journal of Materials Science & Technology2023，，3： | 0 |
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