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| 1 | Self-assembly synthesis of phosphorus-doped tubular g-C_(3)N_(4);Ti_(3)C_(2)MXene Schottky junction for boosting photocatalytic hydrogen evolution显示文摘Establishing highly effective charge transfer channels in carbon nitride(g-C_(3)N_(4)) to enhance its photocatalytic activity is still a challenging issue.Herein,the delaminated 2D Ti_(3)C_(2) MXene nanosheets were employed to decorate the P-doped tubular g-C_(3)N_(4)(PTCN)for engineering 1D/2D Schottky heterojunction(PTCN/TC)through electrostatic self-assembly.The optimized PTCN/TC exhibited the highest hydrogen evolution rate(565 μmol h^(-1)g^(-1)),which was 4.3 and 2.0-fold higher than pristine bulk g-C_(3)N_(4) and PTCN,respectively.Such enhancement may be primarily attributed to the phosphorus heteroatom doped and unique structure of 1D/2D g-C_(3)N_(4)/Ti_(3)C_(2) Schottky heterojunction,enhancing the light-harvesting and charges’separation.One-dimensional pathway of g-C_(3)N_(4) tube and built-in electric field of interfacial Schottky effect can significantly facilitate the spatial separation of photogenerated charge carriers,and simultaneously inhibit their recombination via Schottky barrier.In this composite,metallic Ti_(3)C_(2) was served as electrons sink and photons collector.Moreover,ultrathin Ti_(3)C_(2) flake with exposed terminal metal sites as a co-catalyst exhibited higher photocatalytic reactivity in H2 evolution compared to carbon materials(such as reduced graphene oxide).This work not only proposed the mechanism of tubular g-C_(3)N_(4)/Ti_(3)C_(2) Schottky junction in photocatalysis,but also provided a feasible way to load ultrathin Ti_(3)C_(2) as a co-catalyst for designing highly efficient photocatalysts. | Kelei Huang Chunhu Li Xiuli Zhang Liang Wang Wentai Wang Xiangchao Meng | 2023 | Green Energy & Environment2023，8，1： | 2 |
| 2 | The ellipsoidal corrections for boundary value problems of deflection of the vertical with ellipsoid boundary显示文摘The boundary value problem of deflections of vertical with ellipsoid boundary is studied in the paper.Based on spherical harmonic series,the ellipsoidal corrections for the boundary value problem are derived so that it can be well solved.In addition,an imitation arithmetic is given for examining the accuracies of solutions for the boundary value problem as well as its spherical approximation problem,and the computational results illustrate that the boundary value problem has higher accuracy than its spherical approximation problem if deflection of the vertical are measured on geoid. | Xiangchao Meng Jinhai Yu Yongchao Zhu | 2017 | Geodesy and Geodynamics2017，8，4： | 2 |
| 3 | Wellbore stability analysis of layered shale based on the modified Mogi-Coulomb criterion显示文摘Borehole instability was frequently encountered during shale gas drilling.Most conventional models are not applicable to layered formation's wellbore stability analysis on account of anisotropic strength characteristic.In this study,an empirical equation for predicting anisotropic strength was implemented in the Mogi–Coulomb criterion to describe variations of cohesive strength and friction angle of shale formations.A collapse pressure model and its appropriate solution method for layered shale formations were proposed.The impact of different strength criteria and rock anisotropy type on rock strength and collapse pressure was investigated.The analysis indicated that the predicted strength of our modified criterion was usually higher than the weak plane failure criteria.The collapse pressure calculated by the modified Mogi–Coulomb criterion was lower than the weakplane failure criteria.Furthermore,it was more consistent with real mud weight.Additionally,the anisotropy type of rock notably influences wellbore stability.More significant anisotropy coefficients correspond to higher strengths,which results in smaller collapse pressure values.Improper anisotropy coefficients can over-or underpredict the collapse pressure.Reasonable estimates of collapse pressure of anisotropic rocks can be made through the modified Mogi–Coulomb criterion using limited experimental data and the anisotropy rock type. | Xu Yang Xiangchao Shi Yingfeng Meng Xiaoyong Xie | 2020 | Petroleum2020，6，3： | 1 |
| 4 | Confined compressive strength model of rock for drilling optimization显示文摘The confined compressive strength(CCS)plays a vital role in drilling optimization.On the basis of Jizba's experimental results,a new CCS model considering the effects of the porosity and nonlinear characteristics with increasing confining pressure has been developed.Because the confining pressure plays a fundamental role in determining the CCS of bottom-hole rock and because the theory of Terzaghi's effective stress principle is founded upon soil mechanics,which is not suitable for calculating the confining pressure in rock mechanics,the double effective stress theory,which treats the porosity as a weighting factor of the formation pore pressure,is adopted in this study.The new CCS model combined with the mechanical specific energy equation is employed to optimize the drilling parameters in two practical wells located in Sichuan basin,China,and the calculated results show that they can be used to identify the inefficient drilling situations of underbalanced drilling(UBD)and overbalanced drilling(OBD). | Xiangchao Shi Yingfeng Meng Gao Li a Jiaxue Li Zuwen Tao Shandong Wei | 2015 | Petroleum2015，1，1： | 1 |
| 5 | Microstructure formation mechanism of catalyst layer and its effect on fuel cell performance:Effect of dispersion medium composition显示文摘The design of the catalyst layer(CL)offers a feasible way to realize the commercialization of proton exchange membrane fuel cells(PEMFCs).An in-depth understanding of catalyst inks is critical to achieving the optimal CL structure and cell performance.In this work,the effects of the solvent evaporation process during ink drying on the formation of the CL microstructure are particularly considered to reveal the structure-property correlations among the catalyst ink,drying process,CL microstructure and fuel cell performance.An increase in the alcohol content of the catalyst ink increases the amount of free ionomers while allowing the ionomer backbone to be more stretched in the dispersion medium.The higher alcohol content contributes to rapid solvent evaporation and thus inhibits the formation of coffee rings;as a result,a more developed ionomer network with a denser pore structure is obtained.Therefore,the alcohol-rich electrode exhibits better proton conduction capability,but higher oxygen transport resistance.For complex fuel cell operating conditions,a catalyst ink formulation with 50 wt%alcohol content is preferred due to its proper ionomer and pore size distribution,providing satisfactory fuel cell performance. | Hong Ren Xiangchao Meng Yongli Lin Zhigang Shao | 2022 | Journal of Energy Chemistry2022，31，10： | 0 |
| 6 | Verify the Function of a Potential Growth-Regulating Gene in Marine Bivalve Using a Candidate Model Organism Mulinia lateralis显示文摘A better understanding of genetic bases of growth regulation is essential for bivalve breeding,which is helpful to improve the yield of the commercially important bivalves.While previous studies have identified some candidate genes accounting for variation in growth-related traits through genotype-phenotype association analyses,seldom of them have verified the functions of these putative,growth-related genes beyond the genomic level due to the difficulty of culturing commercial bivalves under laboratory conditions.Fortunately,dwarf surf clam Mulinia lateralis can serve as a model organism for studying marine bivalves given its short generation time,the feasibility of being grown under experimental conditions and the availability of genetic and biological information.Using dwarf surf clam as a model bivalve,we characterize E2F3,a gene that has been found to account for variation in growth in scallops by a previous genome-wide association study,and verify its function in growth regulation through RNA interference(RNAi)experiments.For the first time,E2F3 in dwarf surf clam,which is termed as MulE2F3,is characterized.The results reveal that dwarf surf clams with MulE2F3 knocked down exhibit a reduction in both shell size and soft-tissue weight,indicating the functions of MulE2F3 in positively regulating bivalve growth.More importantly,we demonstrate how dwarf surf clam can be used as a model organism to investigate gene functions in commercial bivalves,shedding light on genetic causes for variation in growth to enhance the efficiency of bivalve farming. | WANG Chen KONG Lingling LIAN Shanshan YANG Zujing MENG Deting LI Moli ZHANG Xiangchao BAO Zhenmin HU Xiaoli | 2023 | Journal of Ocean University of China2023，22，4： | 0 |
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