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3篇 您的检索式:作者名="Yingyi Han"
    题名 作者 年代 出处 被引量
1Inhibition of microRNA-17/20a suppresses cell proliferation in gastriccancer by modulating UBE2C expression显示文摘Yingyi Zhang Ting Han Guo Wei Yajie Wang 2015Oncology Reports2015,,5:1
2Unravelling the role of boron dopant in borocarbonitirde catalytic dehydrogenation reaction显示文摘Borocarbonitride(BCN) materials are newly developed metal-free catalytic materials exhibiting high selectivity in oxidative dehydrogenation(ODH) of alkanes. However, the in-depth understandings on the role of boron(B) dopants and the intrinsic activities of –C=O and –B–OH still remain unknown.Herein, we report a series of BCN materials with regulable B content and surface oxygen functional groups via self-assembly and pyrolysis of guanine and boric acid. We found that the B/C ratio is the key parameter to determine the activity of ODH and product distribution. Among them, the high ethylbenzene conversion(~57%) and styrene selectivity(~83%) are achieved in ODH for B_(1)CN. The styrene selectivity can be improved by increasing of B/C ratio and this value reaches near 100% for B_5CN.Structural characterizations and kinetic measurements indicate that –C=O and –B–OH dual sites on BCN are real active sites of ODH reaction. The intrinsic activity of –C=O(5.556 × 10^(-4)s^(-1)) is found to be 23.7 times higher than –B–OH(0.234 × 10^(-4)s^(-1)) site. More importantly, we reveal that the deep oxidation to undesirable CO_(2) occurs on –C=O rather than –B–OH site, and B dopant in BCN materials can reduce the nucleophilicity of –C=O site to eliminate the CO_(2) emission. Overall, the present work provides a new insight on the structure–function relationship of the BCN catalytic systems.Xuefei Zhang Yanbing Lu Yingyi Han Runping Feng Zailai Xie 2023Journal of Energy Chemistry2023,,10:0
3An integrated flexible self-healing Zn-ion battery using dendrite-suppressible hydrogel electrolyte and free-standing electrodes for wearable electronics显示文摘Among many aqueous batteries,flexible zinc-ion(Zn-ion)battery becomes the focus owing to the merits of low cost,non-toxicity,and safety.Here,a Zn dendrite-suppressible hydrogel electrolyte with both flexible and self-healing properties is developed via photoinitiated polymerization.The cross-linked structure of the polyacrylamide-N,N'-methylenebisacrylamide(PAM-MBA)-Zn/Mn hydrogel endows an enlarged chemical stable window,high ionic conductivity,and low polarization potential.After cycling at the current density of 0.5 mA·cm^(−2)for 250 h,Zn‖Zn symmetrical cell based on PAM-MBA-Zn/Mn electrolyte delivers a low polarization of 40 mV.The suppressed dendrite growth is ascribed to the uniform Zn deposition/stripping on anode.The galvanostatic intermittent titration technique curves display that the Zn-ion battery constructed by the PAM-MBA-Zn/Mn hydrogel electrolyte,free-standing FeVO_(4)/carbon cloth cathode,and Zn nanosheets/carbon cloth anode presents low reaction resistance and fast diffusion coefficient,indicating good endurance of cycling at high current densities.The battery with PAM-MBA-Zn/Mn hydrogel electrolyte presents a good flexible and self-healing performance.After bending 0°,60°,90°,and 180°for 30 times,batteries deliver stable capacities.Even cutting into ten pieces,the battery could self-heal and display a potential retention of 93.7%compared to the fresh cell.A good rate-performance is also achieved.After cutting/healing three times during cycling,capacity recovers well compared to the first-time cutting/healing.Moreover,the battery exhibits good flexibility using in an electric watch,indicating a promising potential for wearable electronics.Jiawei Long Tianli Han Xirong Lin Yajun Zhu Yingyi Ding Jinyun Liu Huigang Zhang 2023Nano Research2023,16,8:0
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