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| 1 | Recent progress in organic solar cells(PartⅠmaterial science)显示文摘During past several years,the photovoltaic performances of organic solar cells(OSCs)have achieved rapid progress with power conversion efficiencies(PCEs)over 18%,demonstrating a great practical application prospect.The development of material science including conjugated polymer donors,oligomer-like organic molecule donors,fused and nonfused ring acceptors,polymer acceptors,single-component organic solar cells and water/alcohol soluble interface materials are the key research topics in OSC field.Herein,the recent progress of these aspects is systematically summarized.Meanwhile,the current problems and future development are also discussed. | Yahui Liu Bowen Liu Chang-Qi Ma Fei Huang Guitao Feng Hongzheng Chen Jianhui Hou Lingpeng Yan Qingya Wei Qun Luo Qinye Bao Wei Ma Wei Liu Weiwei Li Xiangjian Wan Xiaotian Hu Yanchun Han Yaowen Li Yinhua Zhou Yingping Zou Yiwang Chen Yongfang Li Yongsheng Chen Zheng Tang Zhicheng Hu Zhi-Guo Zhang Zhishan Bo | 2022 | Science China Chemistry2022，65，2： | 5 |
| 2 | Molecular crowding agents engineered to make bioinspired electrolytes for high-voltage aqueous supercapacitors显示文摘The development of low-cost and eco-friendly aqueous electrolytes with a wide voltage window is the key to achieving safe high energy density supercapacitors(SCs).In this work,a molecular crowding electrolyte is prepared by simulating the crowded environment in living cells.Ion transport in the molecular crowding electrolyte can be effectively improved via reducing the molecular weight of the crowding agent,polyethylene glycol(PEG).The results show that PEG with a molecular weight of 200(PEG200)can significantly improve ionic conductivity while maintaining a wide voltage window.These advantages enable commercial activated carbon-based SCs to work at 2.5 V with high energy density,outstanding rate performance and good stability for more than 10,000 cycles.On this basis,three series of molecular crowding electrolytes using sodium perchlorate,lithium perchlorate,and sodium trifluoromethanesulfonate as salts are developed,demonstrating the versatility of PEG200 for wide-voltage aqueous electrolytes. | Mengke Peng Li Wang Longbin Li Zhongyou Peng Xiannong Tang Ting Hu Kai Yuan Yiwang Chen | 2021 | eScience2021，1，1： | 5 |
| 3 | Reducing Energy Loss and Morphology Optimization Manipulated by Molecular Geometry Engineering for Hetero-junction Organic Solar Cells显示文摘of main observation and conclusion Molecular geometry engineering is an efective strategy to control the micromorphology and molecularenergy level in organic photovoltaics(OPVs).Two novel copolymers based on alkysilyl-and chloride-functionalied benzodithiophene(BDT)were designed and synthesized for wide bandgap copolymer donor materials in OPVs.It was found that the two copolymers exhited distinctly different proper-ties in active layer when blended with fulerene-fre acceptor T-4.The chloride-functionalited copolymer PBDTCI-TZ2 with deeper molecular energy leveland better coplanar structure induced more ordered aggregation in blend flm.Thus,the device based on PBDTC-TZ exhibits better energy alinmentwith IT-4F and smallr radiative recombination.furthermore,the non-radiative recombination of PBDTCI-TZ.T-4F based device is about 45 mV lowerthan the PBDTS-TZ/T-4F based device,contributing to a lower enery loss(Ein,and a higher open-cicut voltage(Vc).As a resut,the devices based onthe blend of PBDTC-TZ2.IT-4F exhibit a high power conversion efficiency(PCE)of up to 12.2%with a high Vvoe of 0.837 Vv,higher than that of PBDTSi-TZ:IT-4F,of which the PCE is 11.2%with a Voc of 0.781V. | Guodong Xu Huan Rao Xunfan Liao Youdi Zhang Yuming Wang Zhi Xing Ting Hu Licheng Tan Lie Chen Yiwang Chen | 2020 | Chinese Journal of Chemistry2020，38，12： | 4 |
| 4 | Wide Band-gap Two-dimension Conjugated Polymer Donors with Different Amounts of Chlorine Substitution on Alkoxyphenyl Conjugated Side Chains for Non-fullerene Polymer Solar Cells显示文摘In this study,wide bandgap(WBG)two-dimensional(2D)copolymer donors(DZ1,DZ2,and DZ3)based on benzodithiophene(BDT)on alkoxyphenyl conjugated side chains without and with different amounts of chlorine atoms and difluorobenzotriazole(FBTZ)are designed and synthesized successfully for efficient non-fullerene polymer solar cells(PSCs).Three polymer donors DZ1,DZ2,and DZ3 display similar absorption spectra at 300-700 nm range with optional band-gap(Egopt)of 1.84,1.92,and 1.97 eV,respectively.Compared with reported DZ1 without chlorine substitution,it is found that introducing chlorine atoms into the meta-position of the alkoxyphenyl group affords polymer possessing a deeper the highest occupied molecular orbital(HOMO)energy level,which can increase open circuit voltage(Voc)of PSCs,as well as improve hole mobility.Non-fullerene bulk heterojunction PSCs based on DZ2:MelC demonstrate a relatively high power conversion efficiency(PCE)of 10.22%with a Voc of 0.88 V,a short-circuit current density(Jsc)of 17.62 mA/cm^2,and a fill factor(FF)of 68%,compared with PSCs based on DZ1:MelC(a PCE of 8.26%)and DZ3:MelC(a PCE of 6.28%).The results imply that adjusting chlorine atom amount on alkoxyphenyl side chains based on BDT polymer donors is a promising approach of synthesizing electron-rich building block for high performance of PSCs. | Youdi Zhang Yong Wang Ruijie Ma Zhenghui Luo Tao Liu So-Huei Kang He Yan Zhongyi Yuan Changduk Yang Yiwang Chen | 2020 | Chinese Journal of Polymer Science2020，38，8： | 3 |
| 5 | Mechanical and thermal properties of polypeptide modified hydroxyapatite/poly(L-lactide) nanocomposites显示文摘A new type of polypeptide(poly(-benzyl-L-glutamate)(PBLG))modified hydroxyapatite(HA)/poly(L-lactide)(PLLA)nanocomposites(PBLG-g-HA/PLLA)were prepared by the solvent-mixing method,and their mechanical and thermal properties were investigated.The tensile test showed that the mechanical properties of PBLG-g-HA/PLLA nanocomposites were better than that of PLLA,even a 0.3 wt%content of PBLG-g-HA in the nanocomposites could make the tensile strength 12%higher than that of the neat PLLA sample,and the tensile modulus was about 17%higher than that of the PLLA sample.The thermal gravimetric analysis(TGA)showed that the PBLG-g-HA/PLLA composites have better thermal stability than the PLLA sample.The differential scanning calorimetry(DSC)was used to characterize the effect of PBLG-g-HA on the crystallization of PLLA.The isothermal crystallization behavior showed that the half crystallization time(t1/2)of PBLG-g-HA/PLLA was much shorter than that of the PLLA sample.When the PBLG-g-HA content was 10%,t1/2 was only 18.7 min,while t1/2 of the PLLA sample was 61.4 min.The results showed that the PBLG-g-HA worked as a nucleating agent and enhanced the crystallization speed of PLLA. | WEI JunChao DAI YanFeng CHEN YiWang CHEN XueSi | 2011 | Science China Chemistry2011，54，3： | 3 |
| 6 | Recent progress in organic solar cells(PartⅡdevice engineering)显示文摘1 Introduction Organic solar cells(OSCs)belong to a multidisciplinary field composed of chemistry,materials science,physics,engineering,etc.For a better reviewing of this field,we briefly divide the research field of OSCs into two parts:material science and device engineering.In our previous review,the material science part of OSCs,including conjugated polymer donors and acceptors,small molecular donors and acceptors. | Yahui Liu Bowen Liu Chang-Qi Ma Fei Huang Guitao Feng Hongzheng Chen Jianhui Hou Lingpeng Yan Qingya Wei Qun Luo Qinye Bao Wei Ma Wei Liu Weiwei Li Xiangjian Wan Xiaotian Hu Yanchun Han Yaowen Li Yinhua Zhou Yingping Zou Yiwang Chen Yuqiang Liu Lei Meng Yongfang Li Yongsheng Chen Zheng Tang Zhicheng Hu Zhi-Guo Zhang Zhishan Bo | 2022 | Science China Chemistry2022，65，8： | 3 |
| 7 | Additive-free non-fullerene organic solar cells with random copolymers as donors over 9% power conversion efficiency显示文摘In this study, a series of random conjugated polymers (PBDB-TBTn) as donors were designed and synthesized. In these polymers, benzodithiophene unit with thiophene conjugated side chains (BDT) are donor part, and two different content of benzo[1,2-c:4,5-c']dithiophene-4,8-dione (BDD) and difluorobenzothiadizole (BT) linked alkylthiophene are acceptor unit. Polymer solar cells (PSCs) were fabricated with ITIC as an acceptor, and over the power conversion efficiency (PCE) of 9%was obtained, with open circuit voltage (Voc) of 0.86 V, short-circuit current density (Jsc) of 16.84 mA/cm^2, and fill factor (FF) of 62.5%. These random conjugated polymers based solar cells are insensitive to solvent additives and thermal annealing. The performance of the device decreases gradually with the increasing of the proportion of fluorinated acceptor unit. The declining efficiency is due to the excessive fluorinated acceptor unit, which leads to over aggregated topography, destroys the effective charge transport pathways, and affects phase separation domain size between the donor and the acceptor. The phenomena are explained by the charge carrier recombination, atomic force microscope (AFM), and transmission electron microscope (TEM). These results indicate that proper addition of fluorinated acceptor units to build random copolymers can enhance the efficiency of organic photovoltaics toward additive-free and thermal annealing-free PSCs. | Meimei Wu Laitao Shi Yu Hu Lie Chen Ting Hu Youdi Zhang Zhongyi Yuan Yiwang Chen | 2019 | Chinese Chemical Letters2019，30，6： | 3 |
| 8 | Large-area Flexible Organic Solar Cells: Printing Technologies and Modular Design显示文摘Flexibility is the most prominent advantage of organic solar cells(OSCs) compared with traditional photovoltaic devices, showing an irreplaceable commercial potential. Currently, the maximum power conversion efficiencies(PCEs) of single-junction OSCs have been over 19% and 16% upon rigid and flexible substrates, respectively, which meet the criteria for commercial application. Extensive research efforts are under way, such as device configuration design, interface/photosensitive layer synthesis, transparent electrode modification and printing technology innovation, however, the reasonable selection of printing technologies, the huge performance loss of large-area printing process and the structural design of flexible modules are still the bottlenecks, limiting the commercialization of OSCs. This review focuses on the technical challenges and rational modular configuration design for printing preparation of flexible high-efficiency large-area organic devices, from the aspects of the functional layer material selection, printing process research status and large-scale efficiency losses. These will promote the integrated applications of printable organic semiconductor materials for next-generation clean energy and appeal extensive attentions in wearable electronics, building-integrated photovoltaics and Internet of Things, etc. | Xiangchuan Meng Zhi Xing Xiaotian Hu Yiwang Chen | 2022 | Chinese Journal of Polymer Science2022，40，12： | 2 |
| 9 | Disulfide-crosslinked Poly(L-glutamic acid) Grafted Mesoporous Silica Nanoparticles and Their Potential Application in Drug Delivery显示文摘 | WU Huiyong LI Jianhui WEI Junchao DAI Yanfeng PENG Zhiping CHEN Yiwang LIU Tianxi | 2015 | Chemical Research in Chinese Universities2015，31，5： | 2 |
| 10 | Effects of substitution and terminal groups for liquid-crystallinity enhanced luminescence of disubstituted polyacetylenes carrying chromophoric terphenyl pendants显示文摘Liquid-crystalline and light-emitting poly(2-alkyne)s containing terphenyl cores with hexamethyleneoxy spacers,and cyano or n-propoxy tails -[CH3C=C(CH2)6O-terphenyl-R]n-,where R=CN,CH3PA6CN,R=OCH2CH2CH3,CH3PA6OPr,were synthesized.The effects of the substitution and terminal groups on the properties,especially the mesomorphic and optical properties of the polymers,were investigated.The disubstituted acetylene monomers (CH3A6CN,CH3A6OPr) were pre- pared through multistep reaction routes and were polymerized by WCl6-Ph4Sn in good yields (up to 82%).All the monomers and CH3PA6CN exhibited the enantiotropic SmA phase with a monolayer arrangement at elevated temperatures,whereas CH3PA6OPr formed a bilayer SmAd packing arrangement.Upon excitation at 330 nm,strong UV and blue emission peaks at 362 and 411 nm were observed in CH3PA6OPr and CH3PA6CN,respectively.The luminescent properties of CH3PA6CN and CH3PA6OPr have been improved by introducing the methyl substituted group,and the quantum yield of the polymer with cyano tail CH3PA6CN (φ= 74%) was found to be higher than that of CH3PA6OPr (φ= 60%).Compared to polyacety- lene parents,both CH3PA6OPr and CH3PA6CN showed a narrower energy gap.This demonstrated that the electrical con- ductivities of polyacetylenes could be enhanced by attaching appropriate pendants to the conjugated polyene backbones. | ZHOU Dan,CHEN YiWang,CHEN Lie,LI Fan,NIE HuaRong & YAO Kai Institute of Polymers/Department of Chemistry,Nanchang University,Nanchang 330031,China | 2010 | Science China Chemistry2010，53，6： | 2 |
| 11 | Novel polymer acceptors achieving 10.18% efficiency for all-polymer solar cells显示文摘Polymer acceptors based on extended fused ring p skeleton has been proven to be promising candidates for all-polymer solar cells(all-PSCs), due to their remarkable improved light absorption than the traditional imide-based polymer acceptors. To expand structural diversity of the polymer acceptors, herein,two polymer acceptors PSF-IDIC and PSi-IDIC with extended fused ring p skeleton are developed by copolymerization of 2,20-((2 Z,20 Z)-((4,4,9,9-tetrahexadecyl-4,9-dihydro-s-indaceno [1,2-b:5,6-b']dithio phene-2,7-diyl)bis(methanylylidene))bis(3-oxo-2,3-dihydro-1 H-indene-2,1-diylidene))dimalononitrile(IDIC-C16) block with sulfur(S) and fluorine(F) functionalized benzodithiophene(BDT) unit and silicon(Si) atom functionalized BDT unit, respectively. Both polymer acceptors exhibit strong light absorption.The PSF-IDIC exhibits similar energy levels and slightly higher absorption coefficient relative to the PSi-IDIC. After blended with the donor polymer PM6, the functional atoms on the polymer acceptors show quite different effect on the device performance. Both of the acceptors deliver a notably high open circuit voltage(V_(OC)) of the devices, but PSi-IDIC achieves higher V OCthan PSF-IDIC. All-PSC based on PM6:PSi-IDIC attains a power conversion efficiency(PCE) of 8.29%, while PM6:PSF-IDIC-based device achieves a much higher PCE of 10.18%, which is one of the highest values for the all-PSCs reported so far. The superior device performance of PM6:PSF-IDIC is attributed to its higher exciton dissociation and charge transport, decreased charge recombination, and optimized morphology than PM6:PSi-IDIC counterpart. These results suggest that optimizing the functional atoms of the side chain provide an effective strategy to develop high performance polymer acceptors for all-PSCs. | Shaorong Huang Feiyan Wu Zuoji Liu Yongjie Cui Lie Chena Yiwang Chen | 2021 | Journal of Energy Chemistry2021，30，2： | 2 |
| 12 | Highly stable Al-doped ZnO by ligand-free synthesis as general thickness-insensitive interlayers for organic solar cells显示文摘Highly conductive and dispersible Al-doped ZnO(AZO) nanoparticles(NPs) have been successfully prepared by ligand-free colloidal synthesis at low temperature and stabilization by surfactant-aid including ethanolamine(EA), ethylenediamine(EDA),diethylenetriamine(DETA) and triethylenetetramine(TETA). Due to the strong intermolecular hydrogen-bonding interactions between AZO NPs and the amino groups from surfactants, the inevitable aggregation was suppressed and the surface defect sites were passivated obviously. The existence of electron transfer from the nitrogen of the amino groups to the zinc of AZO,led to a dramatic increase in electrical conductivity. A homogeneous current intensity value up to ~2200 pA for AZO tread by DETA was characterized by conductive atomic force microscopy(C-AFM), which was more superior than that of the reported sol-gel synthesized AZO with the assistance of EA surfactant(refer to 170.7 pA). Furthermore, non-fullerenes solar cells based on PBDB-T:ITIC with AZO-DETA(80 nm) yielded a best device efficiency of 10.7% and kept up prominent PCE exceeding 10%even with more thicker interlayer(95 nm). | Yilin Wang Zhongyou Peng Shuqin Xiao Jia Yang Huanyu Zhou Liqiang Huang Lulu Sun Yinhua Zhou Licheng Tan Yiwang Chen | 2018 | Science China Chemistry2018，61，1： | 2 |
| 13 | A non-wetting and conductive polyethylene dioxothiophene hole transport layer for scalable and flexible perovskite solar cells显示文摘The regulated crystallization of perovskite and highly repeatable preparation are decisive challenges for large-scale flexible perovskite solar cells(PSCs).Herein,we synthesize an oil-soluble poly(3,4-ethylenedioxythiophene)(Oil-PEDOT)as a hole transport layer(HTL).The non-wetting Oil-PEDOT HTL can promote the quality of large-area flexible perovskite films because of its optimized crystallinity and printability.The Oil-PEDOT layer also delivers desirable conductivity and charge transport without a complex doping.Consequently,the flexible PSCs with Oil-PEDOT HTL achieve an efficiency of 19.51%and 16.70%based on 1.05 and 22.50 cm^(2),respectively.Moreover,these large-scale flexible PSCs demonstrate remarkable mechanical robustness,and the efficiency exhibits 93%retention after 7,000 bending cycles.These results show that the Oil-PEDOT is a potentially efficient HTL for fabricating efficient large-scale flexible PSCs. | Chenxiang Gong Lin Zhang Xiangchuan Meng Zhi Xing Li Rao Hongyu Wang Zengqi Huang Licheng Tan Ting Hu Xiaotian Hu Yiwang Chen | 2021 | Science China Chemistry2021，64，5： | 1 |
| 14 | Novel Donor-Acceptor Copolymers Based on Dithienosilole and Ketone Modified Thieno[3,4-b]thiophene for Photovoltaic Application显示文摘二新奇施主领受人( D-A )共聚物包含 dithienosilole ( DTS )施主单位和酉同类修改了 thieno [ 3,4-b ] thiophene ( TT )领受人单位,也就是 poly {4,4二度( 2-ethylhexyl ) dithieno [ 3,2-b:2,3-d ]silole-5,5-diyl-alt-1-( thieno [ 3,4-b ] thiophen-2-yl )-2-ethylhexan-1-one}( PDTSTT )并且 poly {4,4二度( 2-ethylhexyl ) dithieno [ 3,2-b:2,3-d ]silole-5,5-diyl-alt-1-(4,6二度( 4-ethylhexylthien-2-yl ) thieno [ 3,4-b ] thiophen-2-yl )-2-ethylhexan-1-one}( PDTSDTTT ),在聚合物太阳能电池为申请被综合( PS 聚合物 PDTSTT 和 PDTSDTTT 分别地有 1.54 和 2.02 eV 的电气化学的 bandgaps,和 5.47 和 5.37 eV 的低人精力层次。分子的几何学模拟结果证明与 PDTSTT 相比,在 PDTSDTTT 的 thiophene 桥牌的插入能很好减轻在 TT 和 DTS 单位之间的位的阻碍者,作为由在 DTS 和 DTTT 单位之间的减少的二面的角度证实了。在 AM 1.5G 的照明下面, 100 mW/cm2, PSC 基于 PDTSDTTT/PC61BM (1:1, w:w ) 证明 1.0% 的力量变换效率,它是显著地基于 PDTSTT/PC61BM 与设备比较改善了(1:2, w:w ) 在一样的试验性的条件下面。这是因为提高的 planarity 和在 PDTSDTTT 的主要的链的增加的有效变化形式为费用交通支持更有利的形态学,尽管 PDTSTT 比 PDTSDTTT 拥有更宽广的吸收乐队。 | Lie Chen Shujiao Cai Xianbo Wang Yiwang Chen | 2013 | Chinese Journal of Chemistry2013，31，11： | 1 |
| 15 | Hydrolytic and enzymatic degradation of liquid-crystalline aromatic aiiphat ic copolyester显示文摘 | Chen Yiwang Jia Zhihong Schaper Andreas | 2004 | Biomacromolecules2004，5，1： | 1 |
| 16 | Novel poly (butylene succinate-co-lactic acid) copolyesters:Synthesis,crystallization,and enzymatic degradation显示文摘 | Licheng Tan Yiwang Chen Weihua Zhou | | 0，，95： | 1 |
| 17 | Enhancement of the Ultraviolet Emission of ZnO Nanorods by Terphenyl Liquid- crystalline Ligands Modification显示文摘 | CHEN Wei LI Fan CHEN Yiwang | 2011 | Applied Surface Science2011，257，21： | 1 |
| 18 | 显示文摘 | Chen Yiwang Deng Qilan Xiao Jichun | 2007 | Polymer2007，48，： | 1 |
| 19 | Alternating Terpolymers Based on Tunable Bi-donors with Manipulating Energy Levels and Molecular Geometry显示文摘Three novel regular acceptor-donorl-acceptor-donor2(A-D1-A-D2) terpolymers were prepared via em-bedding a second donor(D2) unit into the traditional D-A backbone to manipulate the energy levels and moleculargeometry with no complex synthesis or solubility loss. In these A-D1-A-D2 terpolymers, benzodithiophene(BDT, D1)and diketopyrrolopyrrole(DPP, A) were selected as the basic skeleton, and the dithienopyrrole(DTPy), carbazole(CZ)and fluorine(FL) units with different electron donating ability were chosen as the second donor trait(D2). The HOMOenergy levels can be effectively modulated by only varying D2 unit because of the push-pull interaction between do-nor and acceptor units. Versus the D-A bipolymer PDPP-BDT, incorporation of the D2 unit into the copolymers candistinctly lower the highest occupied molecular orbital(HOMO) levels to -5.47 eV for PDDPP-BDT-DTPy, -5.38 eVfor PDDPP-BDT-CZ and -5.23 eV for PDDPP-BDT-FL, which shows the strong dependence on electron-donatingability. Density functional theory(DFT) simulation and X-ray diffraction(XRD) measurements also reveal the effectof the D2 units on the molecular geometry of the terpolymers and their molecular packing. Notably, aPDDPP-BDT-DTPy combined with a thiophene ring and forked tail pendant away from the backbone had less back-bone torsion and more compact packing than the other two counterparts. These results demonstrate that embedding asecond donor(D2) unit into the backbone to construct an A-D1-A-D2 structure can be an effective and direct strategyto manipulate the energy levels and molecular geometry and develop organic semiconducting materials. | CHEN Zhenzhu YANG Jia WU Feiyan CHEN Lie CHEN Yiwang | 2017 | Chemical Research in Chinese Universities2017，33，2： | 1 |
| 20 | Bamboo fibers poly ( ethylene glycol)-reinforced poly ( butylene succinate)biocomposites 显示文摘 | Bao Le Chen Yiwang Zhou Welhua Wu Yang Huang Yulan | 2011 | Journal of Applied Polymer Sci- ence2011，122，4： | 1 |
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