| 1 | Low-Carbon and Nanosheathed ZnCo_(2)O_(4) Spheroids with Porous Architecture for Boosted Lithium Storage Properties显示文摘Multielectronic reaction electrode materials for high energy density lithium-ion batteries(LIBs)are severely hindered by their inherent sluggish kinetics and large volume variations,leading to rapid capacity fade.Here,a simple method is developed to construct low-carbon and nanosheathed ZnCo_(2)O_(4) porous spheroids(ZCO@C-5).In this micro/nanostructure,an ultrathin amorphous carbon layer(∼2 nm in thickness)is distributed all over the primary nanosized ZCO particles(∼20 nm in diameter),which fnally self-assembles into porous core(ZCO)-shell(carbon)micron spheroids.Te nanoencapsulation and macro/mesoporous architecture can not only provide facile electrolyte penetration and rapid ion/electron transfer but also better alleviate volumetric expansion efect to avoid pulverization of ZCO@C-5 spheroids during repeat charge/discharge processes.As expected,the three-dimensional porous ZCO@C-5 composites exhibit high reversible capacity of 1240 mAh g^(−1) cycle at 500 mA g^(−1),as well as excellent long-term cycling stability and rate capability.Te low-carbon and nanoencapsulation strategy in this study is simple and efective,exhibiting great potential for high-performance LIBs. | Yudi Mo Junchen Liu Shuanjin Wang Min Xiao Shan Ren Dongmei Han Yuezhong Meng | 2019 | Research2019，，1： | 3 |
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