| 1 | Study on attrition of spherical-shaped Mo/HZSM-5 catalyst for methane dehydro-aromatization in a gas–solid fluidized bed显示文摘As a potential methane efficient conversion process,non-oxidative aromatization of methane in fluidized bed requires a catalyst with good attrition resistance,especially in the states of high temperature,longtime rapid movement and chemical reaction.Existing evaluation methods for attrition resistance,such as ASTM D5757 and Jet Cup test,are targeted for fresh catalysts at ambient temperature,which cannot well reflect the real process.In this study,spherical-shaped Mo/HZSM-5 catalyst prepared by dipping and spray drying was placed in a self-made apparatus for attrition testing,in which the catalyst attrition under different system temperatures,running time and process factors was investigated with percent mass loss(PML),particle size-mass distribution(PSMD)and scanning electron microscope(SEM).Carbon deposition on the catalyst before and after activation,aromatization and regeneration was analyzed by thermogravimetry(TG),and the attrited catalysts were evaluated for methane dehydro-aromatization(MDA).The results show that the surface abrasion and body breakage of catalyst particles occur continuously,with the increase of system temperature and running time,and make the PML rise gradually.The process factors of activation,aromatization and regeneration can cause the catalyst attrition and carbon deposits,which broaden the PSMD in varying degrees,and the carbon-substances on catalysts greatly improve their attrition resistance at high temperature.Catalyst attrition has a certain influence on its catalytic performance,and the main reasons point to particle breakage and fine powder escape. | Xinzhuang Zhang Yunda Han Dapeng Li Zhanguo Zhang Xiaoxun Ma | 2021 | Chinese Journal of Chemical Engineering2021，34，10： | 1 |
| 2 | Electrically-pumped compact topological bulk lasers driven by band-inverted bound states in the continuum显示文摘One of the most exciting breakthroughs in physics is the concept of topology that was recently introduced to photonics,achieving robust functionalities,as manifested in the recently demonstrated topological lasers.However,so far almost all attention was focused on lasing from topological edge states.Bulk bands that reflect the topological bulk-edge correspondence have been largely missed.Here,we demonstrate an electrically pumped topological bulk quantum cascade laser(QCL)operating in the terahertz(THz)frequency range.In addition to the band-inversion induced in-plane reflection due to topological nontrivial cavity surrounded by a trivial domain,we further illustrate the band edges of such topological bulk lasers are recognized as the bound states in the continuum(BiCs)due to their nonradiative characteristics and robust topological polarization charges in the momentum space.Therefore,the lasing modes show both in-plane and out-of-plane tight confinements in a compact laser cavity(lateral size~3λ_(laser)).Experimentally,we realize a miniaturized THz QCL that shows single-mode lasing with a side-mode suppression ratio(SMSR)around 20 dB.We also observe a cylindrical vector beam for the far-field emission,which is evidence for topological bulk BIC lasers.Our demonstration on miniaturization of single-mode beam-engineered THz lasers is promising for many applications including imaging,sensing,and communications. | Song Han Jieyuan Cui Yunda Chua Yongquan Zeng Liangxing Hu Mingjin Dai Fakun Wang Fangyuan Sun Song Zhu Lianhe Li Alexander Giles Davies Edmund Harold Linfield Chuan Seng Tan Yuri kivshar Qi Jie Wang | 2023 | Light(Science & Applications)2023，12，7： | 0 |
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