|
|
|
题名
|
作者
|
年代
|
出处
|
被引量
|
| 1 | Ternary Ni-Co-Fe oxyhydroxide oxygen evolution catalysts:Intrinsic activity trends,electrical conductivity,and electronic band structure显示文摘Nickel-,cobalt-,and iron-based(oxy)hydroxides comprise the most-commonly studied electrocatalysts for the oxygen-evolution reaction(OER)in alkaline solution.A fundamental understanding of composition-structure-activity relationships for mixed-metal Ni-Co and Ni-Co-Fe(oxy)hydroxides is important to guide the design of advanced OER catalysts.Here we use cyclic voltammetry,chronopotentiometry,inductively-coupled plasma-optical emission spectroscopy,and in situ electrical conductivity measurements to characterize the properties and activity of various compositions of Ni-Co-Fe(oxy)hydroxides prepared by cathodic co-electrodeposition.Consistent with previous studies,we find Fe is essential for the mixed-metal(oxy)hydroxides to achieve high OER activity.In the rigorous absence of Fe(achieved by using specially cleaned electrolytes),the most-active Ni-Co(oxy)hydroxide composition has an OER turn-over frequency only twice that ofpure Co(oxy)hydroxide,suggesting minimal synergism between the two metals.The addition of Co to Ni-Fe(oxy)hydroxides shifts the onset of electrical conductivity to lower potentials,but has little effect on the intrinsic OER activity,with the most-active Ni-Co-Fe(oxy)hydroxide having an OER turn-over frequency only -1.5 times that of the Ni-Fe(oxy)hydroxides.The magnitudes of the electrical conductivities are similar for all the compositions measured.Density-functional-theory-calculated projected density of states show a significant contribution of all chemical elements at the valence band edge of the mixed-metal oxyhydroxide electronic structure,demonstrating significant electronic hybridization between the elements.The calculations suggest the involvement of all the elements in modulating the electronic structure at putative Fe-based active sites that are probably located at edges or defects in the two-dimensional oxyhydroxide sheets. | Michaela Burke Stevens Lisa J. Enman Ester Hamal Korkus Jeremie Zaffran Christina D. M. Trang James Asbury Matthew G. Kast Maytal Caspary Toroker Shannon W. Boettcher | 2019 | Nano Research2019，12，9： | 5 |
| 2 | Transmission of hepatitis B, hepatitis Cand human immunodefiency viruses thraegh unsafe injeltions in the developing world; model-based regional esti- mates显示文摘 | Kane A Lloyd J Zaffran M | 1999 | Bull World Health Organ1999，77，10： | 1 |
| 3 | Congenital heart defects in Fgfr2-Ⅲb and Fgf10 mutant mice显示文摘 | Marguerie A Bajolle F Zaffran S | 2006 | Cardiovasc Res2006，71，1： | 1 |
| 4 | Building the mammalian heart from two sources of myocardial cells显示文摘 | Buckingham M Meilhac S Zaffran S | 2005 | Nat Rev Genet2005，6，： | 1 |
| 5 | Right ventricular myocardium derives from the anterior heart field 显示文摘 | Zaffran S Kelly R G Meilhae S M | 2004 | Circ Res2004，95，3： | 1 |
| 6 | Pax3 and pax7 have distinct and overlapping functions in adult muscle progenitor cells显示文摘 | Relaix F Montarras D Zaffran S | 2006 | J Cell Biol2006，172，1： | 1 |
| 7 | Genetics and embryologi- cal mechanisms of congenital heart diseases 显示文摘 | Bajolle F Zaffran S Bonnet D | 2009 | Arch Cardiovasc Dis2009，102，1： | 1 |
| 8 | Atrial myocardium derives from the posterior region of the second heart field, which acquires left-right identity as Pitx2c is expressed 显示文摘 | Galli D Dominguez J N Zaffran S | 2008 | Development2008，135，11： | 1 |
| 9 | Pax3 and Pax7 have distinct and overlapping function in adult muscle progenitor cells显示文摘 | RELAIX F MONTARRAS D ZAFFRAN S | | 0，，01： | 1 |
| 10 | Transmission of hepatitis B, hepatitis C and human immunodeficiency viruses trough unsafe in- jections in the developing world: model-based regional estimates 显示文摘 | Kane A Lloyd J Zaffran M | 1999 | Bulletin WHO1999，77，10： | 1 |
| 11 | A drosophila RNA hellcase gene,pitchoune,is required for cell growth and proliferation and is a potential target of c-myc显示文摘 | Chartier A Gallant P | 1998 | Development1998，125，18： | 1 |
| 12 | Building the mammalian heart from two sources of myocardial cells 显示文摘 | Buckingham M Meilhac S Zaffran S | 2005 | Nat Rev Genet2005，6，： | 1 |
| 13 | Cardioblast-intrinsic Tinman Activity Controls Proper Diversification and Differentiation of Myocardial Cells in Drosophila 显示文摘 | ZAFFRAN S REIM I QIAN L | 2006 | Development2006，20，： | 1 |
| 14 | CD46/CD3 costimulation induces morphological changes of human T cells and activation of Vac, Rac and extracellular signal regulated kinase mitogen activated protein kinase显示文摘 | ZAFFRAN Y DESTAING O ROUX A | 2001 | J Immunol2001，167，12： | 1 |
| 15 | Rotation of the myocardial wall of the outflow tract is implicated in the normal positioning of the great arteries显示文摘 | Bajolle F Zaffran S Kelly RG | 2006 | Circ Res2006，98，3： | 1 |
| 16 | Building the mammalian heart from two sources of myocardial cells显示文摘 | Buckingham M Meilhac S Zaffran S | | 0，，11： | 1 |
| 17 | Genetics and embryological mechanisms of congenital heart diseases显示文摘 | Fanny Bajolle Stéphane Zaffran Damien Bonnet | 2008 | Archives of Cardiovascular Diseases2008，，1： | 1 |
| 18 | Transmission of hepatilis B, hepatitis C and human immunodeficiency viruses through unsafe injections in the developing world: model-based regional estimales显示文摘 | Kane A Lloyd J Zaffran M | 1999 | Bulletin of the World Heath Organization1999，77，10： | 1 |
| 19 | Transmission of hepatitis B,hepatitis C and human immunodeficiency viruses through unsafe injections in the developing world:model-based regional estimates显示文摘 | Kane A Lloyd J Zaffran M | 1999 | Bulletin of the World Health Organization1999，77，10： | 1 |
| 20 | A drosophila RNA helicase gene,pitchoune,is required for cell growth and proliferation and is a potential target of c-myc 显示文摘 | Chartier A Gallant P | 1998 | Development1998，125，18： | 1 |
您所在的机构暂未开通此部分的功能，请联系管理员