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| 1 | Chemical Fixation of CO_2 with Highly Efficient ZnCl_2/[BMIm]Br Catalyst System显示文摘 | Li Fuwei Xia Chungu | 2004 | 合成化学2004，12，z1： | 27 |
| 2 | Porphyrin-like Fe-N4 sites with sulfur adjustment on hierarchical porous carbon for different rate-determining steps in oxygen reduction reaction显示文摘We developed a strategy based on coordination polymer to synthesize singleatom site Fe/N and S-codoped hierarchical porous carbon (Fe1/N,S-PC).The as-obtained Fe1/N,S-PC exhibited superior oxygen reduction reaction (ORR) performance with a half-wave potential (Ev2,0.904 V vs.RHE) that was better than that of commercial Pt/C (E1/2,0.86 V vs.RHE),single-atom site Fe/N-doped hierarchical porous carbon (Fe1/N-PC) without S-doped (E1/2,0.85 V vs.RHE),and many other nonprecious metal catalysts in alkaline medium.Moreover,the Fe1/N,S-PC revealed high methanol tolerance and firm stability.The excellent electrocatalytic activity of Fe1/N,S-PC is attributed to the synergistic effects from the atomically dispersed porphyrin-like Fe-N4 active sites,the heteroatom codoping (N and S),and the hierarchical porous structure in the carbon materials.The calculation based on density functional theory further indicates that the catalytic performance of Fe1/N,S-PC is better than that of Fe1/N-PC owing to the sulfur doping that yielded different rate-determining steps. | Konglin Wu Xin Chen Shoujie Liu Yuan Pan Weng-Chon Cheong Wei Zhu Xing Cao Rongan Shen Wenxing Chen Jun LUO Wensheng Yan Lirong Zheng Zheng Chen Dingsheng Wang Qing Peng Chen Chen Yadong Li | 2018 | Nano Research2018，11，12： | 18 |
| 3 | Ni/Al_2O_3 catalysts for CO methanation: Effect of Al_2O_3 supports calcined at different temperatures显示文摘The correlation between phase structures and surface acidity of Al2O3 supports calcined at different temperatures and the catalytic performance of Ni/Al2O3 catalysts in the production of synthetic natural gas(SNG) via CO methanation was systematically investigated. A series of 10 wt% NiO/Al2O3 catalysts were prepared by the conventional impregnation method, and the phase structures and surface acidity of Al2O3 supports were adjusted by calcining the commercial γ-Al2O3 at different temperatures(600–1200 C). CO methanation reaction was carried out in the temperature range of 300–600 C at different weight hourly space velocities(WHSV = 30000 and 120000 mL·g-1h-1) and pressures(0.1 and 3.0 MPa). It was found that high calcination temperature not only led to the growth in Ni particle size, but also weakened the interaction between Ni nanoparticles and Al2O3 supports due to the rapid decrease of the specific surface area and acidity of Al2O3 supports. Interestingly, Ni catalysts supported on Al2O3 calcined at 1200 C(Ni/Al2O3-1200) exhibited the best catalytic activity for CO methanation under different reaction conditions. Lifetime reaction tests also indicated that Ni/Al2O3-1200 was the most active and stable catalyst compared with the other three catalysts, whose supports were calcined at lower temperatures(600, 800 and 1000 C). These findings would therefore be helpful to develop Ni/Al2O3 methanation catalyst for SNG production. | Jiajian Gao Chunmiao Jia Jing Li Meiju Zhang Fangna Gu Guangwen Xu Ziyi Zhong Fabing Su | 2013 | Journal of Energy Chemistry2013，22，6： | 16 |
| 4 | CATALYSTS FOR SYNTHESIS OF N-VINYLPYRROLIDONE显示文摘 | 崔英德 易国斌 廖列文 康正 | 2000 | 化工学报2000，51，4： | 15 |
| 5 | Insight of the stability and activity of platinum single atoms on ceria显示文摘Single-atom catalysts (SACs) have recently attracted broad attention in the catalysis field due to their maximized atom efficiency and unique catalytic properties.An atomic-level understanding of the interaction between the metal atoms and support is vital for developing stable and high-performance SACs.In this work,Pt1 single atoms with Ioadings up to 4 wt.% were fabricated on ceria nanorods using the atomic layer deposition technique.To understand the Pt-O-Ce bond interfacial interactions,the stability of Pt1 single atoms in the hydrogen reducing environment was extensively investigated by using in situ diffuse reflectance infrared Fourier transform spectroscopy CO chemisorption measurements.It was found that ceria defect sites,metal Ioadings and high-temperature calcination are effective ways to tune the stability of Pt1 single atoms in the hydrogen environment.X-ray photoemission spectroscopy further showed that Pt1 single atoms on ceria are dominantly at a +2 valence state at the defect and step edge sites,while those on terrace sites are at a +4 state.The above tailored stability and electronic properties of Pt1 single atoms are found to be strongly correlated with the catalytic activity in the dry and water-mediated CO oxidation reactions. | Xuxu Ye Hengwei Wang Yue Lin Xinyu Liu Lina Cao Jian Gu Junling Lu | 2019 | Nano Research2019，12，6： | 13 |
| 6 | 支持科研和学术发现的语义网应用实例研究显示文摘针对当前语义网技术在支持科研创新方面的发展,比较两个支持科学研究和学术发现的工具——哈佛大学信息搜索引擎Harvard Catalyst和语义网探索的科学家网络VIVO,包括两者在信息组织方式、系统架构、系统实现关键技术、数据来源、实现的功能等方面的差异,分析VIVO所具有的特色以及存在的问题,讨论当前语义网应用在支持科学研究上具有的特点。 | 黄金霞 | 2011 | 图书情报工作2011，55，11： | 12 |
| 7 | Encapsulating soluble active species into hollow crystalline porous capsules beyond integration of homogeneous and heterogeneous catalysis显示文摘Homogeneous molecular catalysts and heterogeneous catalysts possess complementary strengths,and are of great importance in laboratory/commercial procedures.While various porous hosts,such as polymers,carbons,silica,metal oxides and zeolites,have been used in an attempt to heterogenize homogeneous catalysts,realizing the integration of both functions at the expense of discounting their respective advantages,it remains a significant challenge to truly combine their intrinsic strengths in a single catalyst without compromise.Here,we describe a general template-assisted approach to incorporating soluble molecular catalysts into the hollow porous capsule,which prevents their leaching due to the absence of large intergranular space.In the resultant yolk(soluble)–shell(crystalline)capsules,the soluble yolks can perform their intrinsic activity in a mimetic homogeneous environment,and the crystalline porous shells endow the former with selective permeability,substrate enrichment,size-selective and heterogeneous cascade catalysis,beyond the integration of the respective advantages of homogeneous and heterogeneous catalysts. | Guorui Cai Meili Ding Qianye Wu Hai-Long Jiang | 2020 | National Science Review2020，7，1： | 12 |
| 8 | Highly selective catalytic reduction of NO_x by MnO_x–CeO_2–Al_2O_3 catalysts prepared by self-propagating high-temperature synthesis显示文摘We first present preparation of MnOx–CeO_2–Al_2O_3 catalysts with varying Mn contents through a self-propagating high-temperature synthesis(SHS) method, and studied the application of these catalysts to the selective catalytic reduction of NOxwith NH3(NH_3-SCR).Using the catalyst with 18 wt.% Mn(18 MnCe1Al2), 100% NO conversion was achieved at 200°C and a gas hourly space velocity of 15384 hr-1, and the high-efficiency SCR temperature window, where NO conversion is greater than 90%, was widened to a temperature range of 150–300°C. 18 MnCe1Al2 showed great resistance to SO_2(100 ppm)and H_2O(5%) at 200°C. The catalysts were characterized using X-ray diffraction, X-ray photoelectron spectroscopy, Brunauer–Emmett–Teller(BET) analysis, scanning electron microscopy, Fourier transform infrared spectroscopy, and H_2 temperature programmed reduction. The characterization results showed that the surface atomic concentration of Mn increased with increasing Mn content, which led to synergism between Mn and Ce and improved the activity in the SCR reaction. 18 MnCe1Al2 has an extensive pore structure,with a BET surface area of approximately 135.4 m^2/g, a pore volume of approximately 0.16 cm^3/g, and an average pore diameter of approximately 4.6 nm. The SCR reaction on 18 MnCe1Al2 mainly followed the Eley-Rideal mechanism. The performances of the MnOx–CeO_2–Al_2O_3 catalysts were good, and because of the simplicity of the preparation process,the SHS method is applicable to their industrial-scale manufacture. | Chao Wang Feng Yu Mingyuan Zhu Changjin Tang Ke Zhang Dan Zhao Lin Dong Bin Dai | 2019 | Journal of Environmental Sciences2019，31，1： | 11 |
| 9 | gt-C3N4 coordinated single atom as an efficient electrocatalyst for nitrogen reduction reaction显示文摘The electrochemical reduction of nitrogen to ammonia is a promising way to produce ammonia at mild condition.The design and preparation of an efficient catalyst with high ammonia selectivity is critical for the real applications.In this work,a series of transition metal (TM =Sc,Ti,V,Cr,Mn,Fe,Co,Ni,Cu,Zn,Y,Zr,Nb,Mo,Tc,Ru,Rh,Pd,Ag,and Cd) atoms supported by gt-C3N4 (TM/gt-C3N4) are investigated as electrocatalysts for the nitrogen reduction reaction (NRR) based on density functional calculations.It is found that Mo/gt-C3N4 with a limiting potential of-0.82 V is the best catalyst for standing-on adsorbed N2 cases.While for lying-on adsorbed N2 cases,V/gt-C3N4 with a limiting potential of-0.79 V is berer than other materials.It is believed that this work provides several promising candidates for the non-noble metal electrocatalysts for NRR at mild condition. | Lifu Zhang Wanghui Zhao Wenhua Zhang Jing Chen Zhenpeng Hu | 2019 | Nano Research2019，12，5： | 11 |
| 10 | Commercial Application of the Second Generation RHT Catalysts for Hydroprocessing the Residue with Low Sulfur and High Nitrogen Contents显示文摘The RHT technology and the second generation RHT catalysts were applied in design of an 1.7Mt/a VRDS unit at the SINOPEC Changling Branch Co. The commercial application result demonstrated that the RHT catalysts showed good activity and stability in processing low-sulfur and high-nitrogen residue. The first long period run of unit for processing high Fe and high Ca content residue was achieved. The reasons for excessive pressure drop of R-101 were ascribed to Fe and Ca deposition as well as coke formation. | Shao Zhicai Zhao Xinqiang Liu Tao Dai Lishun Nie Hong | 2014 | China Petroleum Processing & Petrochemical Technology2014，16，1： | 11 |
| 11 | Palladium Nanoparticle-Graphene Hybrids as Active Catalysts for the Suzuki Reaction显示文摘Graphene has been successfully modified with palladium nanoparticles in a facile manner by reducing palladium acetate [Pd(OAc)2] in the present of sodium dodecyl sulfate (SDS), which is used as both surfactant and the reducing agent. The palladium nanoparticle-graphene hybrids (Pd-graphene hybrids) are characterized by high- resolution transmission electron microscopy, atomic force microscopy, Raman spectroscopy, X-ray photoelectron spectroscopy, X-ray diffraction, and energy dispersive X-ray spectroscopy. We demonstrate that the Pd-graphene hybrids can act as an efficient catalyst for the Suzuki reaction under aqueous and aerobic conditions, with the reaction reaching completion in as little as 5 min. The influence of the preparation conditions on the catalytic activities of the hybrids is also investigated. | Yang Li Xiaobin Fan Junjie Qi Junyi Ji Shulan Wang Guoliang Zhang Fengbao Zhang | 2010 | Nano Research2010，3，6： | 10 |
| 12 | Enhanced aromatic selectivity by the sheet-like ZSM-5 in syngas conversion显示文摘Aromatics are important basic chemicals. However, direct conversion of syngas via the conventional Fischer-Tropsch synthesis produces little aromatics. We presented herein that a bifunctional composite of ZSM-5 in combination with Zn Cr Oxcatalyzes syngas conversion to aromatics. Particularly, ZSM-5 crystals with a sheet-like morphology can enhance significantly the aromatization activity. The lower length ratio of the b/a axes of the crystals, the more aromatics form but without influencing the selectivity of small molecules such as CH4 and C2–C4. Since the acid properties and the Al chemical environment were not altered while the morphology changed, the enhanced aromatic selectivity is likely attributed to the favored diffusion of aromatics in these sheet-like crystals. | Junhao Yang Ke Gong Dengyun Miao Feng Jiao Xiulian Pan Xiangju Meng Fengshou Xiao Xinhe Bao | 2019 | Journal of Energy Chemistry2019，28，8： | 10 |
| 13 | Alkaline polymer electrolyte fuel cells: Principle, challenges, and recent progress显示文摘Polymer electrolyte membrane fuel cells (PEMFC) have been recognized as a significant power source in future energy systems based on hydrogen. The current PEMFC technology features the employment of acidic polymer electrolytes which, albeit superior to electrolyte solutions, have intrinsically limited the catalysts to noble metals, fundamentally preventing PEMFC from widespread deployment. An effective solution to this problem is to develop fuel cells based on alkaline polymer electrolytes (APEFC), which not only enable the use of non-precious metal catalysts but also avoid the carbonate-precipitate issue which has been troubling the conventional alkaline fuel cells (AFC). This feature article introduces the principle of APEFC, the challenges, and our research progress, and focuses on strategies for developing key materials, including high-performance alkaline polyelectrolytes and stable non-precious metal catalysts. For alkaline polymer electrolytes, high ionic conductivity and satisfactory mechanical property are difficult to be balanced, therefore polymer cross-linking is an ultimate strategy. For non-precious metal catalysts, it is urgent to improve the catalytic activity and stability. New materials, such as transition-metal complexes, nitrogen-doped carbon nanotubes, and metal carbides, would become applicable in APEFC. | TANG DaoPing, PAN Jing, LU ShanFu, ZHUANG Lin* & LU JunTao Hubei Key Lab of Electrochemical Power Sources College of Chemistry and Molecular Sciences, Wuhan University, Wuhan 430072, China | 2010 | Science China Chemistry2010，53，2： | 9 |
| 14 | Catalytic Reduction of CO2 to CO via Reverse Water Gas Shift Reaction:Recent Advances in the Design of Active and Selective Supported Metal Catalysts显示文摘The catalytic conversion of CO2 to CO via a reverse water gas shift(RWGS)reaction followed by well-established synthesis gas conversion technologies may provide a potential approach to convert CO2 to valuable chemicals and fuels.However,this reaction is mildly endothermic and competed by a strongly exothermic CO2 methanation reaction at low temperatures.Therefore,the improvement in the low-temperature activities and selectivity of the RWGS reaction is a key challenge for catalyst designs.We reviewed recent advances in the design strategies of supported metal catalysts for enhancing the activity of CO2 conversion and its selectivity to CO.These strategies include varying support,tuning metal–support interactions,adding reducible transition metal oxide promoters,forming bimetallic alloys,adding alkali metals,and enveloping metal particles.These advances suggest that enhancing CO2 adsorption and facilitating CO desorption are key factors to enhance CO2 conversion and CO selectivity.This short review may provide insights into future RWGS catalyst designs and optimization. | Min Zhu Qingfeng Ge Xinli Zhu | 2020 | Transactions of Tianjin University2020，26，3： | 9 |
| 15 | Metal oxide and hydroxide nanoarrays: Hydrothermal synthesis and applications as supercapacitors and nanocatalysts显示文摘The development of nanotechnology in recent decades has brought new opportunities in the exploration of new materials for solving the issues of fossil fuel consumption and environment pollution.Materials with nano-array architecture are emerging as the key due to their structure advantages,which offer the possibility to fabricate high-performance electrochemical electrodes and catalysts for both energy storage and effcient use of energy.The main challenges in this feld remain as rational structure design and corresponding controllable synthesis.This article reviews recent progress in our laboratory related to the hydrothermal synthesis of metal oxide and hydroxide nanoarrays,whose structures are designed aiming to the application on supercapacitors and catalysts.The strategies for developing advanced materials of metal oxide and hydroxide nanoarrays,including NiO,Ni(OH)2,Co3O4,Co3O4@Ni–Co–O,cobalt carbonate hydroxide array,and mixed metal oxide arrays like Co3 xFex O4and Znx Co3 xO4,are discussed.The different kinds of structure designs such as 1D nanorod,2D nanowall and hierarchical arrays were involved to meet the needs of the high performance materials.Finally,the future trends and perspectives in the development of advanced nanoarrays materials are highlighted. | Qiu Yang Zhiyi Lu Junfeng Liu Xiaodong Lei Zheng Chang Liang Luo Xiaoming Sun | 2013 | Progress in Natural Science:Materials International2013，23，4： | 9 |
| 16 | Isolation and identification of the thermophilic alkaline desulphuricant strain显示文摘A desulfurization strain that belongs to the thermophilic alkaline desulphuricant is designated as strain GDJ-3 and isolated from Inner Mongolia, China. The colony of the strain shows tiny, yellow, or white-yellow, and it becomes henna with the protracting of cultivated time. The cells are bacilliform (0.3 -0.6 × 1.0-1.2 μm), motive, and Gram negative. The strain GDJ-3 is able to utilize respectively the thiosulphate, sulfate, sulfite, or sulfide as sulfur source, utilize the carbon dioxide as the carbon source, and utilize the ammonium or nitrate as the nitrogen source. According to GenBank data, 16s RNA results of GDJ-3 are in good agreement with Alpha proteobacterrium sp. (97%) and Ochrobactrum sp. (98%). For GDJ-3, the optimum growth temperature is at 45℃, the optimum pH is at 8.5-8.8, and the optimum rocking speed of sorting table is at 150 r/min. Under the optimum culture condition, the cells of the strain can live for about 18 h. In the desulfurization solution, which is prepared according to the composition of DDS solution, the objectionable constituents of sodium thiosulphate and sodium sulfide were added factitiously, and the bacterial cell concentration was set at 107/mL. After the regeneration of the above desulfurization solution by the strain cells, the concentration of sodium thiosulphate was decreased by 14.75 g/L (percentage loss of content 13.21%), the concentration of sodium sulfide was decreased by 0.76 g/L (percentage loss of content 87.36%) in the desulfurization solution in 9.5 hours, and sulfur appeared. Maybe, this kind of strain can be used as the regeneration's bacterial source of DDS solution. | ZHANG JianBin ZHANG Tong MA Kai CHEN GuoHua ZHANG DongYan WEI XiongHui | 2008 | Science China Chemistry2008，51，2： | 9 |
| 17 | Immobilization of functional nano-objects in living engineered bacterial biofilms for catalytic applications显示文摘Nanoscale objects feature very large surface-area-to-volume ratios and are now understood as powerful tools for catalysis,but their nature as nanomaterials brings challenges including toxicity and nanomaterial pollution.Immobilization is considered a feasible strategy for addressing these limitations.Here,as a proof-of-concept for the immobilization of nanoscale catalysts in the extracellular matrix of bacterial biofilms,we genetically engineered amyloid monomers of the Escherichia coli curli nanofiber system that are secreted and can self-assemble and anchor nano-objects in a spatially precise manner.We demonstrated three scalable,tunable and reusable catalysis systems:biofilm-anchored gold nanoparticles to reduce nitro aromatic compounds such as the pollutant p-nitrophenol,biofilm-anchored hybrid Cd0.9Zn0.1S quantum dots and gold nanoparticles to degrade organic dyes and biofilm-anchored CdSeS@ZnS quantum dots in a semi-artificial photosynthesis system for hydrogen production.Our work demonstrates how the ability of biofilms to grow in scalable and complex spatial arrangements can be exploited for catalytic applications and clearly illustrates the design utility of segregating high-energy nano-objects from injury-prone cellular components by engineering anchoring points in an extracellular matrix. | Xinyu Wang Jiahua Pu Yi Liu Fang Ba Mengkui Cui Ke Li Yu Xie Yan Nie Qixi Mi Tao Li Lingli Liu Manzhou Zhu Chao Zhong | 2019 | National Science Review2019，6，5： | 9 |
| 18 | 表面光学系统Catalyst在宫颈癌放疗中的临床应用显示文摘目的评估Catalyst在宫颈癌患者放疗摆位中的应用,并分析其与膀胱容积(BV )、体质量指数(BM1)的相关性方法2017年7-12月收治的33例宫颈癌患者,首次治疗时常规摆位(室内激光+体膜标记)后进行CBCT验证,再利用Catalyst分别获取有膜与无膜时患者影像.并将其作为参考影像;非首次时常规摆位后利用Catalyst辅助摆位,并进行每周2次CBCT验证:记录BV和BM1,以及两系统在腹背(AP)、头脚(SI)、左右(LR)的摆位误差。结果两系统摆位误差在SI和LR方向不同,Catalyst 较 CBCT 受 BV 和 BMI 影响显著(P<0.05), BV 在 200-300 ml时,Catalyst 无膜误差与BV在SI方向R值为-0. 316(P<0. 05);BV>300 ml时,有膜误差与BV在AP方向R值为-0. 493(P<0. 05),无膜误差与 BV 在 SI、LR 方向 R 值分别为 0. 335( P<0. 05),-0. 348( P<0. 05)。BMI<25kg/m^2 时 Catalyst 有膜误差与 BMI 在 LR 方向 R 值为 0. 197( P<0. 05), M25 kg/m^2 时 AP、SI 方向 R值分别为 0. 818(P<0.05)、-0. 498(P<0.05);无膜误差在 BMI>25 kg/m^2 时与 BMI 在 AP、LR 方向 R值分别为0.652(P<0.05)、-0. 558(P<0. 05);结论 Catalyst与CBCT相比摆位误差在SI、LR有显著差异,基于Catalyst的摆位易受宫颈癌患者BV与BMI的影响。 | 彭海燕 罗焕丽 毛开金 何阳 王登彦 彭立峰 朱羿羽 王雪纯 闵庆宏 靳富 王颖 | 2019 | 中华放射肿瘤学杂志2019，28，3： | 9 |
| 19 | Low-temperature selective catalytic reduction of NO_(x) with NH_(3) over zeolite catalysts:A review显示文摘The selective catalytic reduction(SCR)of NO_(x) by NH3 is one of the most mature technologies for NO_(x) treatment.Catalysts are the main factors affecting denitrification efficiency.Zeolites as low-tempe rature NH3-SCR catalysts have been extensively studied in the past few years.In this work,the mechanism of zeolites for NH3-SCR reaction was reviewed and the denitrification performances of zeolite catalysts prepared by different methods were compared.The effects of sulfur and water poisoning on zeolite catalysts in NH3-SCR reaction were also analyzed.Several ways to address the problems in lowtemperature NH3-SCR reaction were discussed.Hopefully,this review could provide a fundamental understanding of SCR reaction on zeolite catalysts and pave the way toward similar studies to realize its commercial applications. | Yijuan Pu Xinyu Xie Wenju Jiang Lin Yang Xia Jiang Lu Yao | 2020 | Chinese Chemical Letters2020，31，10： | 9 |
| 20 | Electrospinning of ceramic nanofibers:Fabrication,assembly and applications显示文摘This paper provides a brief review of current research activities that focus on the synthesis and controlled assembly of inorganic nano-bers by electrospinning,their electrical,optical and magnetic properties,as well as their applications in various areas including sensors,catalysts,batteries,filters and separators.We begin with a brief introduction to electrospinning technology and a brief method to produce ceramic nanofibers from electrospinning.We then discuss approaches to the controlled assembly and patterning of electrospun ceramic nanofibers.We continue with a highlight of some recent applications enabled by electrospun ceramic nano-bers,with a focus on the physical properties of functional ceramic nanofibers as well as their applications in energy and environmental technologies.In the end,we conclude this review with some perspectives on the future directions and implications for this new class of functional nanomaterials.It is expected that this review paper can help the readers quickly become acquainted with the basic principles and particularly the experimental procedure for preparing and assembly of 1D ceramic nanofiber and its arrays. | Hui WU Wei PAN Dandan LIN Heping LI | 2012 | Journal of Advanced Ceramics2012，1，1： | 9 |
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