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| 1 | 蜂蜜中羟甲基糠醛的研究进展显示文摘蜂蜜中羟甲基糠醛(HMF)的含量是评价蜂蜜及其制品的重要指标。本文简要介绍了热加工和贮藏对蜂蜜中HMF含量的影响以及蜂蜜中HMF的脱除方法。 | 刘静 曹炜 | 2011 | 中国蜂业2011，62，1： | 19 |
| 2 | 新型高密度闪烁玻璃研究进展显示文摘人类活动领域的扩大和科学技术水平的提高 ,尤其是在高能物理 ,核物理 ,地球物理 ,核医学 ,工业探测等领域的应用上不断增长的需求 ,极大推动了新型高密度闪烁晶体与玻璃的研究。闪烁玻璃由于具有成本低廉 ,加工方便 ,组成与体积易于调整等优点而引起广大材料及物理研究人员的兴趣和重视。具有高密度 ,透紫外与可见光 ,离子性较弱而可望具有很好闪烁性能的重金属氧化物玻璃是人们所看好的高密度闪烁玻璃的发展方向。 | 陈国荣 Stefania Baccaro1 杜永娟 | 2000 | 硅酸盐通报2000，19，5： | 12 |
| 3 | 木质纤维素催化转化制备DMF和C_5/C_6烷烃显示文摘生物质是一类重要的可再生资源,将其转化为高品质燃料在能源替代、环境保护等方面具有重要意义。在高品质燃料中,2,5-二甲基呋喃(DMF)具有较高的能量密度、高辛烷值和较高的沸点,是一种非常具有应用前景的可再生含氧液体燃料,掺混后可促进汽油的燃烧;C_5/C_6烷烃是现有汽油的重要组分,在提高汽油辛烷值和调节蒸汽压等方面不可或缺。本文以木质纤维素生物质典型组分纤维素为起始原料,系统总结了纤维素转化为5-羟甲基糠醛(HMF),HMF选择性加氢脱氧为DMF以及完全加氢脱氧为C_5/C_6液体烷烃等转化过程的反应介质、催化体系及反应路径。反应介质包括水、离子液体、极性非质子有机溶剂、含水的双相体系;催化体系包括无机酸、金属盐、固体酸及负载型催化剂。本文对DMF和C_5/C_6烷烃液体燃料高效合成的研究前景进行了展望和评述,以期为纤维素类生物质高效转化为高值液体燃料提供思路和参考。 | 杨越 刘琪英 蔡炽柳 谈金 王铁军 马隆龙 | 2016 | 化学进展2016，28，2： | 11 |
| 4 | 加热过程对蜂蜜中羟甲基糠醛含量的影响显示文摘蜂蜜中羟甲基糠醛 (HMF)的含量是重要的蜂蜜产品质量指标。随着加热温度的升高、加热时间的延长 ,蜂蜜中HMF含量有较大变化 ;且相同条件下 ,不同种类蜂蜜中HMF含量的变化情况也有较大不同。为保证蜂蜜中HMF含量满足要求 ,蜂蜜的热加工处理温度应低于 80℃。 | 曾哲灵 叶贞雄 万冬满 熊涛 彭珊珊 | 2002 | 南昌大学学报(理科版)2002，26，1： | 10 |
| 5 | Dehydration of glucose into 5-hydroxymethylfurfural in SO_3H-functionalized ionic liquids显示文摘The continuous dehydration of D-glucose into 5-hydroxymethylfurfural(HMF) was carried out under mild conditions,using SO3H-functionalized acidic ionic liquids as catalysts and H2O-4-methyl-2-pentanone(MIBK) biphasic system as solvent.High glucose conversion of 97.4% with HMF yield of 75.1%was obtained at 120 8C for 360 min,also,small amounts of levulinic acid(LA) and formic acid were generated.Generally,the dosage of catalyst and the initial content of glucose influenced the reaction significantly; the HMF selectivity decreased with the excessive elevation of temperature and prolonging of time; and water content in the system had a negative effect on the reaction.The ionic liquid catalyst could be recycled and exhibited constant activity for five successful runs.This paper provided a new strategy for HMF production from glucose. | Fu-Rong Tao Chen Zhuang Yue-Zhi Cui Jing Xu | 2014 | Chinese Chemical Letters2014，25，5： | 7 |
| 6 | 一种基于HMF的火电机组短期负荷预测方法显示文摘以某1000 MW机组为研究对象,通过对机组历史日负荷数据进行聚类分析,得到机组负荷的相似性特征。然后提出了一种适用于火电机组负荷预测的历史匹配预测算法(History matching and forecasting algorithm,HMF),HMF算法将预测时间点之前几个小时的负荷序列与同时段的历史负荷数据进行相似性匹配,利用最相似日的负荷变化趋势对未来负荷做出预测。算例测试表明:HMF算法未来3 h的负荷预测平均误差为4.412%,比传统的自回归滑动平均模型(Autoregressive moving average model,ARMA)具有更高的预测精度,且在变负荷过程中也能取得较好的预测效果。 | 丁伟 任少君 司风琪 郭鼎 | 2020 | 热能动力工程2020，35，1： | 6 |
| 7 | 蜂蜜中有害物质的研究显示文摘蜂蜜是一种良好的营养物质,但是由于各种原因会有一些对人体不利的物质进入蜂蜜中。本文对蜂蜜中的有害物质(微生物污染、金属污染、HMF、农药残留、抗生素)从来源、危害、检测、去除等四个方面进行探讨。 | 罗显来 | 2009 | 中国蜂业2009，60，4： | 6 |
| 8 | A new approach for the aerobic oxidation of 5-hydroxymethylfurfural to 2,5-furandicarboxylic acid without using transition metal catalysts显示文摘The organic compound 2,5-furandicarboxylic acid(FDCA) has been identified by the US Department of Energy(DOE) as a valuable platform chemical for a wide range of industrial applications. Currently, the most popular route for FDCA synthesis is reported to be the oxidation of 5-hydroxymethylfurfural(HMF)by O_2 over the catalysis of noble metals(e.g., Au, Pt, Ru, and Pd). However, the high costs of noble metal catalysts remain a major barrier for producing FDCA at an industrial scale. Herein, we report a transition metal-free synthesis strategy for the oxidation of HMF to FDCA under O_2 or ambient air. A simple but unprecedented process for the aerobic oxidation of HMF was carried out in organic solvents using only bases as the promoters. According to the high performance liquid chromatography(HPLC) analysis, excellent product yield(91%) was obtained in the presence of NaOH in dimethylformamide(DMF) at room temperature(25 ℃). A plausible mechanism for the NaOH-promoted aerobic oxidation of HMF in DMF is also outlined in this paper. After the reaction, the sodium salt of FDCA particles were dispersed in the reaction mixture, making it possible for product separation and solvent reuse. The new HMF oxidation approach is expected to be a practical alternative to current ones, which depend on the use of noble metal catalysts. | Lu Zhang Xiaolan Luo Yebo Li | 2018 | Journal of Energy Chemistry2018，27，1： | 5 |
| 9 | Selective hydrogenolysis of 5-hydroxymethylfurfural to 2,5-dimethylfuran over Co_3O_4 catalyst by controlled reduction显示文摘2,5-dimethyfuran(DMF), which is produced from 5-hydroxymethyfurfural(HMF) by hydrodeoxygenation(HDO), is a high quality fuel due to the high heating value, the high octane number and the suitable boiling point. Selective hydrogenation of HMF into liquid fuel DMF has been widely researched. In this paper, Co_3O_4 catalyst was prepared by co-precipitation and was reduced at different temperatures to form Co–CoO_x catalysts. The characterization of catalysts was tested by XRD, TEM, XPS, TPR, BET and NH3-TPD.Co–CoO_x possessed a high amount of Co metal and CoO_x acidic sites, wherein Co worked as the active hydrogenation sites and CoO_x acted as the acid promoter to facilitate the selective HDO of HMF to DMF.The synergistic effect of Co–CoO_x is the key for HDO of HMF, obtaining 83.3% of DMF yield at 170 °C, 12 h and the reduction temperature of 400 °C. This method not only saves the catalyst cost, but also promotes the utilization of biomass energy. | Dan Li Qiying Liu Changhui Zhu Haiyong Wang Chunhua Cui Chenguang Wang Longlong Ma | 2019 | Journal of Energy Chemistry2019，28，3： | 4 |
| 10 | 减压和常压炼蜜对蜂蜜成分的影响显示文摘本文就常压及减压两种炼蜜方法作了比较。当两种方法炼蜜含水量接近时,绝对粘度对比:常压炼蜜比减压炼蜜略高,但P值显示无明显差异,酸度比较:减压炼蜜酸度无变化,而常压炼蜜则随温度升高,酸度增加;HMF含量亦增大;淀粉酶值测定:减压炼蜜不被破坏;由于常压炼蜜部分果糖被破坏,使葡萄糖比例增高影响质量,而减压炼蜜果糖含量高于常压炼蜜。 | 王凤翔 张凤权 王月凤 蔡金梅 | 1983 | 中成药1983，8，4： | 4 |
| 11 | 色素减退性皮损的蕈样肉芽肿2例报告显示文摘 | 沈宏 王宏雁 | 2000 | 临床皮肤科杂志2000，29，3： | 4 |
| 12 | Rapid conversion of cellulose to 5-hydroxymethylfurfural using single and combined metal chloride catalysts in ionic liquid显示文摘Direct conversion of cellulose into 5-hydroxymethylfurfural(HMF) was performed by using single or combined metal chloride catalysts in 1-ethyl-3-methylimidazolium chloride(Cl) ionic liquid.Our study demonstrated formation of 2-furyl hydroxymethyl ketone(FHMK),and furfural(FF) simultaneously with the formation of HMF.Various reaction parameters were addressed to optimize yields of furan derivatives produced from cellulose by varying reaction temperature,time,and the type of metal chloride catalyst.Catalytic reaction by using FeCl3 resulted in 59.9% total yield of furan derivatives(HMF,FHMK,and FF) from cellulose.CrCl3 was the most effective catalyst for selective conversion of cellulose into HMF(35.6%) with less concentrations of FHMK,and FF.Improving the yields of furans produced from cellulose could be achieved via reactions catalyzed by different combinations of two metal chlorides.Further optimization was carried out to produce total furans yield 75.9% by using FeCl3/CuCl2 combination.CrCl3/CuCl2 was the most selective combination to convert cellulose into HMF(39.9%) with total yield(63.8%) of furans produced from the reaction.The temperature and time of the catalytic reaction played an important role in cellulose conversion,and the yields of products.Increasing the reaction temperature could enhance the cellulose conversion and HMF yield for short reaction time intervals(5~20 min). | Hussein Abou-Yousef El Barbary Hassan Philip Steele | 2013 | 燃料化学学报2013，41，2： | 4 |
| 13 | HPLC法测定四物合剂中5-羟甲基糠醛的含量显示文摘目的:建立四物合剂中5-羟甲基糠醛(HMF)含量测定的反相高效液相色谱法。方法:色谱柱为Kromasil C_(18)(250mm×4.6mmi.d.,5μm),流动相为乙腈-水(5:95),检测波长为284nm,测定了5批四物合剂中HMF的含量.结果:HMF的线性范围分别为0.373~3.73μg·mL^(-1)(r=0.9995),方法平均加样回收率为98.4%(n=9).结论:本法简便、准确、重复性好,为四物合剂中HMF的质量评价提供了方法. | 王丰 谢英新 | 2007 | 黑龙江医药2007，20，5： | 3 |
| 14 | Supercontinuum Generation in Holey Microstructure Fibres with Random Cladding Distribution by Femtosecond Laser Pulses *显示文摘It is reported that supercontinuum spectrum from 440 to 1050 nm can be generated in holey microstructure fibres (HMFs) with random cladding distribution by Ti:sapphire femtosecond laser pulses with central wavelength of 800 nm. Based on the method of the effective refractive index and the analogy of step-index fibre, we have calculated the effective mode area and the group velocity dispersion (GVD). It is found that the HMFs have specifically ability of localizing light and controlling GVD. The mechanism of supercontinuum generation in the HMFs with random cladding distribution is that the balance between the GVD and the self-phase modulation in the anomalous dispersion region leads to formation of solitons and fission of high order solitons. | 李曙光 侯蓝田 冀玉领 周桂耀 | 2003 | Chinese Physics Letters2003，20，8： | 3 |
| 15 | 3种添加物抑制模拟体系中羟甲基糠醛(HMF)的形成显示文摘根据羟甲基糠醛(HMF)形成途径,首先在由其不同反应前体物质构成的模拟反应体系中,研究了碳酸氢钠、碳酸氢铵、食盐、硫酸铝钾和硫酸铝铵对各体系中HMF形成的影响。结果表明:当碳酸氢钠和碳酸氢铵添加量为2.00 mg/mL时,美拉德、果糖反应体系中HMF的生成量均显著下降,分别为5.01、3.02 mg/L和3.30、17.52 mg/L;在美拉德、葡萄糖、果糖和蔗糖反应体系中添加0.60 mg/mL硫酸铝钾时,体系中的HMF均明显增高,分别为80.53、13.02、265.02和310.11 mg/L,最大增幅为对照组的620.26倍;而硫酸铝铵处理组HMF的增幅可高达197.00倍。而后考察了5种添加物对饼干中HMF的影响,证实碳酸氢钠、碳酸氢铵和食盐显著降低了饼干中的HMF含量,最大降幅为35.34%。然而,即使在添加了食盐、碳酸氢钠和碳酸氢铵的情况下,硫酸铝钾和硫酸铝铵(0.10 g/80.00 g面粉)仍使饼干中HMF含量增加62.41%和55.64%。综上所述,碳酸氢钠、碳酸氢铵和食盐在模拟体系和饼干中显著减少HMF形成;硫酸铝钾和硫酸铝铵则大幅增加HMF生成量。结果进一步支持了国家限制含铝膨松剂使用的合理性。 | 欧隽滢 江楷煜 高瑜悦 张延杰 黄才欢 | 2021 | 现代食品科技2021，37，7： | 2 |
| 16 | 辐照对蜂蜜中羟甲基糠醛和其它品质指标的影响研究显示文摘以不同剂量60Co-γ射线照射蜂蜜,比较辐射后蜂蜜中5-HMF含量及其它品质指标的变化情况。结果表明:辐照后蜂蜜中羟甲基糠醛(HMF)含量下降迅速,可达10 mg/kg以下,降解率达到90%以上;辐照后蜂蜜中各种糖含量、酶活性基本不变,还保留了原有的外观、颜色和风味。 | 高夫超 崔长日 吴黎明 | 2014 | 中国蜂业2014，0，Z3： | 2 |
| 17 | 2-氯乙醇促进果糖非催化脱水制备5-羟甲基糠醛显示文摘研究了2-氯乙醇对果糖在离子液体1-丁基-3-甲基咪唑氯盐([C4mim]Cl)中非催化脱水制备5-羟甲基糠醛(HMF)的促进性能。结果表明,2-氯乙醇用量增加、反应温度升高以及反应时间延长均有利于HMF的生成。在适当的反应条件下,果糖可以实现完全转化,HMF的选择性达到95%以上。动力学分析表明,2-氯乙醇的存在可以有效降低果糖脱水转化的活化能,在5 mmol 2-氯乙醇的作用下,活化能为48.3 kJ·mol-1,是果糖在温和条件下形成HMF的关键。此外,根据研究结果,对2-氯乙醇促进果糖在[C4mim]Cl中的非催化脱水转化机理进行初步探讨。 | 陈利利 邝栋铃 黄正宇 马浩 滕俊江 李凝 | 2020 | 广东石油化工学院学报2020，30，3： | 2 |
| 18 | Nitrogen-doped Co_(3)O_(4) nanowires enable high-efficiency electrochemical oxidation of 5-hydroxymethylfurfural显示文摘Developing highly efficient and cost-effective catalysts for electrochemically oxidizing biomass-derived 5-hydroxymethylfurfural(HMF)into value-added 2,5-furandicarboxylic acid(FDCA)is of great importance.Herein,we report a controllable nitrogen doping strategy to significantly improve the catalytic activity of Co_(3)O_(4)nanowires for highly selective electro-oxidation of HMF into FDCA.The nitrogen doping leads to the generation of defects including nitrogen dopants and oxygen vacancies in Co_(3)O_(4)nanowires,which is conducive to the formation of catalytically active sites.As a result,the electro-oxidation potential for HMF is only 1.38 V(vs.RHE)when the current density reaches 50 mA/cm^(2).More importantly,the conversion rate of HMF is as high as 99.5%,and the yield of FDCA is up to 96.4%. | Mengxiao Sun Yue Wang Chunsen Sun Yan Qi Jia Cheng Yumei Song Lixue Zhang | 2022 | Chinese Chemical Letters2022，33，1： | 2 |
| 19 | Dehydration of fructose and glucose to 5-hydroxymethylfurfural over Al-KCC-1 silica显示文摘In this research, the influence of several factors such as reaction time, catalyst weight, temperature and different solvents on dehydration reaction of fructose and glucose to 5-hydroxymethylfurfural(HMF) was surveyed. Nanosphere Al-KCC-1 silica with fibrous morphology was manufactured and used as proficient and recyclable catalyst for this reaction. SEM, TEM, BET, XRD, EDX, elemental mapping, ICP and FT-IR spectroscopy methods were applied for characterization of the Al-KCC-1(molar ratio Si/Al = 5, 40) catalysts. 162 °C and 1 h are the best conditions for the fructose dehydration. Under this situation HMF yield and selectivity are 92.9% and 94.5% respectively and fructose conversion is 98.4%. Also 170 °C and 2 h are the best conditions for the glucose dehydration. In this situation HMF yield and selectivity are 39.0% and39.9% respectively and glucose conversion is 97.8%. | Fereshte Shahangi Alireza Najafi Chermahini Mohammad Saraji | 2018 | Journal of Energy Chemistry2018，27，3： | 2 |
| 20 | 关于降低葡萄糖注射液中5-羟甲基糠醛产生量的体会显示文摘 | 白璞 韦芳 | 2000 | 安徽医药2000，4，3： | 2 |
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