|
|
|
题名
|
作者
|
年代
|
出处
|
被引量
|
| 1 | A mechanism for enhanced photocatalytic activity of nano-size silver particle modified titanium dioxide thin films显示文摘Ag-TiO2 nanostructured thin films with silver volume fraction of 0–20% were deposited on silicon and quartz substrates by RF magnetron sputtering and annealed in ambient air at 950°C for 1 h. The phase structure and surface topography of the films were characterized by X-ray diffractometer and transmission electron microscope. Photocatalytic activity of the films was evaluated by light induced degradation of methyl orange (C14H14N3NaO3S) solution using a high pressure mercury lamp as lamp-house. The relation of photocatalytic activity and silver content was studied in detail. It was found that silver content influences phase structure of TiO2 thin films, and silver in the films is metallic Ag (Ag0). With increasing silver content from 0 to 20 vol%, photocatalytic activity of the films increases first and then decreases. A suitable amount (2.5–5 vol%) silver addition can significantly enhance the photocatalytic activity of TiO2 films. The enhanced photocatalytic activity was mainly attributed to the extension of visible light absorption region of the films, the presence of anatase phase, the increase of oxy-gen anion radicals O2? and reactive center of surface Ti3+, and the better separation between electrons and holes on the films surface. | MENG FanMing1,2,3*, LU Fei1,3, SUN ZhaoQi1,3 & Lü JianGuo1,2,4 1 School of Physics and Materials Science, Anhui University, Hefei 230039, China 2 Key Laboratory of Materials Modification by Laser, Ion and Electron Beams (Dalian University of Technology), Ministry of Education, Dalian 116024, China 3 Anhui Key Laboratory of Information Materials and Devices, Anhui University, Hefei 230039, China 4 Department of Physics and Electronic Engineering, Hefei Normal University, Hefei 230061, China | 2010 | Science China(Technological Sciences)2010，53，11： | 4 |
| 2 | Synthesis of a nitrogen-doped titanium dioxide-reduced graphene oxide nanocomposite for photocatalysis under visible light irradiation显示文摘A nitrogen-doped titanium dioxide-reduced graphene oxide (N-TiO2-RGO)nanocomposite has been synthesized by the combination of a hydrothermal method and a thermal treatment under a NH3/N2 atmosphere.The resulting composites are characterized by Fourier transform infrared spectroscopy, scanning electron microscopy,transmission electron microscopy,diffuse reflectance absorption spectroscopy,energy-dispersive X-ray spectroscopy,and Raman characterization techniques.The sequence of the thermal treatment and hydrothermal treatment processes is shown to influence the photocatalytic activity of nitrogen-doped composites.The composites synthesized by using this method show better photocatalytic activities toward the degradation of acetaldehyde under visible light irradiation compared with P25,N-TiO2,and TiO2-RGO.By applying the thermal treatment process after the hydrothermal pro- cess,nitrogen atoms can be simultaneously doped in the lattice ofTiO2nanoparticles and on the surface of reduced graphene oxide sheets.The conversion of acetaldehyde,as the model molecule of volatile organic compounds,is measured in a continuous stirred-tank reactor until the steady state condition is reached. The conversion of 50 ppm acetaldehyde,in an air flow under illumination from an 80W Hg lamp with a UV cut-off filter,reaches 62% after a 1-h reaction using a 0.07g N-TiO2-RGO sample with an optimum loading of 2wt% graphene oxide.In comparison,the photocatalytic activity of P25 for the degradation of acetaldehyde under visible light irradiation is only 8% under the same reaction conditions.The reaction rates for acetaldehyde degradation are calculated and predicted with pseudo-first-order reaction kinetics,and the activity result of the best N-TiO2-RGO sample is 12.3times higher than for P25. | Ehsan Vahidzadeh Shohreh Fatemi Amideddin Nouralishahi | 2018 | Particuology2018，16，6： | 2 |
| 3 | Hybrid solar cells based on poly(3-hexylthiophene) and electrospun TiO_2 nanofibers modified with CdS nanoparticles显示文摘Organic–inorganic hybrid solar cells based on poly(3-hexylthiophene) and electrospun TiO2 nano bers were fabricated by solution process.The ef ciency of the device was improved by modifying CdS nanoparticles on the surface of TiO2 by electrochemical method.The CdS layer can lead to the increase of both open circuit voltage and short circuit current of the device,which are attributed to enhanced exciton dissociation and light absorption and suppressed carrier recombination by CdS at the heterojunction.However,too thick CdS layer led to increased series resistance and decreased ef ciency of the device.Therefore,the optimum condition of the CdS deposition was obtained,which increased the power conversion ef ciency of the device for about 50%.Our results indicate that the surface modi cation on the inorganic semiconductor layer is an effect way to improve the performance of the hybrid solar cells. | Shingchung Lo Zhike Liu Jinhua Li Helen Laiwa Chan Feng Yan | 2013 | Progress in Natural Science:Materials International2013，23，5： | 0 |
| 4 | Mixed-phase Mesoporous TiO2 Film for High Efficiency Perovskite Solar Cells显示文摘Mesoporous scaffold structures have played great roles in halide perovskite solar cells(PSCs),due to the excellent photovoltaic performance and commercial perspective of mesoporous PSCs.Here,we reported a mixed-phase TiO2 mesoporous film as an efficient electron transport layer(ETL)for mesoporous perovskite solar cells.Due to the improved crystal phase,fihn thickness and nanopartMe size of TiO2 layer,which were controlled by varying the one-step hydrothermal reaction time and annealing time,the PSCs exhibited an outstanding short circuit photocurrent density of 25.27 mA/cm^2,and a maximum power conversion efficiency(PCE)of 19.87%.It is found that the ultra-high Jsc attributes to the excellent film quality,light capturing and excellent electron transport ability of mixed-phase TiO2 mesoporous film.The results indicate that mix-phase mesoporous metal oxide fihns could be a promising candidate for producing effective ETLs and high efficiency PSCs. | XIANG Yan ZHUANG Jia MA Zhu LU Honglin XIA Haoran ZHOU Weiya ZHANG Tao LI Haimin | 2019 | Chemical Research in Chinese Universities2019，35，1： | 0 |
您所在的机构暂未开通此部分的功能，请联系管理员