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| 1 | Photocatalytic Reduction of Cr^Ⅵ by Natural Sphalerite Suspensions under Visible Light Irradiation显示文摘The photocatalytic reductive capability of a natural semiconducting mineral, sphalerite has been studied for the first time. The sphalerite from the Huangshaping deposit of Hunan Province performed great photoreductive capability that 91.95% of the Cr6+ was reduced under 9 h visible light irradiation, higher than the 70.58% under 9.5 h UV light irradiation. The highly reductive ability results from its super negative potential of electrons in the conduction band. Furthermore, Fe substitution for Zn introduces donor states, and the oxidation process of Fe2+ to Fe3+ makes it an effective hole-scavenger. Cd and Cu substitute for Zn also reduce the bandgap and help broaden the absorbing edge towards the visible light. These substituting metal ions in natural sphalerite make it a hyper-active photocatalyst and very attractive for solar energy utilization. | LI Yan LU Anhuai WANG Changqiu | 2006 | Acta Geologica Sinica(English Edition)2006，80，2： | 14 |
| 2 | The fluid inclusions in jadeitite from Pharkant area, Myanmar显示文摘A lot of liquid-gas and liquid-gas-solid inclusions were found in Pharkant jadeitites, northwestern Myanmar and their characteristics, geological setting and porphyroclastic jadeites with inclusions in them were described in detail. The results analyzed by Raman spectrometer showed that the component of liquid-gas phase and solid phase (daughter minerals) in fluid inclusions is H2O + CH4 and jadeite separately. The results indicated that Pharkant jadeitites were crystallized from H2O + CH4 bearing jadeitic melt which may originate from mantle. The P-T conditions in which the jadeitites were crystallized were speculated to be T>650℃, P>1.5 GPa. | SHI Guanghai CUI Wenyuan WANG Changqiu ZHANG Wenhuai | 2000 | Chinese Science Bulletin2000，45，20： | 9 |
| 3 | Geometry,kinematics and evolution of the Tongbai orogenic belt显示文摘The Tongbai orogenic belt (TOB) is composed of six tectonic units. From south to north these units are: Tongbai gneiss rise (TGR); Hongyihe-Luozhuang eclogite belt (HLE); Ma- opo-Hujiazhai igneous rock belt (MHI); Zhoujiawan flysch belt (ZFB); Yangzhuang greenschist belt (YGB); and Dongjiazhuang marble belt (DMB).The geometry and kinematic images of the TOB in- clude: the antiformal structures caused by a later uplift process, the top-to-north ductile shear struc- ture that related to a process that the ultrahigh pressure rocks are brought to surface, the top-to-south ductile shear thrust and the sinistrial shear structures related to a south-north direction compression, and the east-west direction fold structures in the upper crust. In the view of the multistage subduc- tion-collision orogenic belt, according to the characters of petrology and its distribution, geometry, kinematics and structural chronology in these tectonic units, tectonic evolution of the TOB can be divided into four stages: oceanic crust subduction during 400―300 Ma, continental collision during 270―250 Ma, continental deep subduction and uplift during 250―205 Ma and doming deformation during 200―185 Ma. | HUANG Shaoying XU Bei WANG Changqiu ZHAN Sheng DENG Rongjing | 2006 | Science China Earth Sciences2006，49，8： | 9 |
| 4 | Experimental Study on Formation Conditions of Ammoniojarosite and Its Environmental Significance显示文摘在 systemFe_2 (SO_4 ) 的 ammoniojarosite 的形成条件 _3-(NH_4 )_2SO_4-H_2O 在这篇论文被调查。结果证明 ammoniojarositecan 被控制合适的 pH andFe_2 (SO_4 ) 在标准温度和压力下面很快形成 _3 并且(NH_4 )_2SO_4 集中。pH,温度和集中 ofFe_2 (SO_4 )_3 媒介是影响 ammoniojarosite 的形成的关键因素。在标准温度下面, ammoniojarosite 的降水能在在 2.6 -3.1, 之间的 pH 在 24 个小时以内被看见, ammoniojarosite 的大数量在 48 个小时以内被形成。在大约 90 deg C,形成 ammoniojarosite 的 pHvalue 范围延长到 1.2 - 3.1,并且在这个范围以内, pH 的上升对 ammoniojarosite 的形成有益,高 Fe_2 (SO_4 )_3 集中也是有益的。相对纯 ammoniojarosite 在高 Fe_2 (SO_4 )_3 集中(>=0.05 M ) 和包含非结晶的氢氧化物讽刺 IronIs 在低 Fe_2 (SO_4 )_3 集中形成了的 melanterite 和胶体的 ammoniojarosite 下面被综合。ammoniojarosite 的免职过程能被用来从矿和另外的工业利用废水并且移开 S, Fe 和另外的有毒、有害的元素,例如作为, Cr, Hg,水里的 Pb。在标准温度和压力下面的 ammoniojarosite 和另外的 jarositeanalogs 的快速的形成为借助于黄钾铁矾和它的类似物的降水利用酸废水有好潜在的前景。 | WANG Changqiu MA Shengfeng LU Anhuai ZHOU Jiangong | 2006 | Acta Geologica Sinica(English Edition)2006，80，2： | 7 |
| 5 | Mineral photoelectrons and their implications for the origin and early evolution of life on Earth显示文摘Energy is the key issue of all life activities.The energy source and energy yielding pathway are the key scientific issues of the origin and early evolution of life on Earth.Current researches indicate that the utilization of solar energy in large scale by life was an important breaking point of the early evolution of life on Earth and afterwards life gradually developed and flourished.However,in the widespread biochemical electron transfer of life activities,it is still not clear whether the electron source is sun or how electrons originated from sun.For billions of years,the ubiquitous semiconducting minerals in epigeosphere absorb solar energy,forming photoelectrons and photoholes.In reductive and weak acidic environment of early Earth,when photoholes were easily scavenged by reducing matters,photoelectrons were separated.Photoelectrons could effectively reduce carbon dioxide to organic matters,possibly providing organic matter foundation for the origin of life.Photoelectrons participated in photoelectron transfer chains driven by potential difference and transfer into primitive cells to maintain metabolisms.Semiconducting minerals,by absorbing ultraviolet,also protected primitive cells from being damaged by ultraviolet in the origin of life.Due to the continuous photoelectrons generation in semiconducting minerals and utilization by primitive cells,photoelectrons from semiconducting minerals’photocatalysis played multiple roles in the origin of life on early Earth,such as organic synthesis,cell protection,and energy supply.This mechanism still plays important roles in modern Earth surface systems. | LU AnHuai WANG Xin LI Yan DING HongRui WANG ChangQiu ZENG CuiPing HAO RuiXia YANG XiaoXue | 2014 | Science China Earth Sciences2014，57，5： | 5 |
| 6 | Pollination and seed dispersal of Aquilaria sinensis(Lour.)Gilg(Thymelaeaceae):An economic plant species with extremely small populations in China显示文摘Pollination and seed dispersal in angiosperms have long been investigated in order to understand the coevolution of plants and animals.However,the signals from flowers and/or seeds to attract pollinators and/or seed dispersers have received comparatively little attention.In this study,the pollination biology and seed dispersal of the vulnerable agarwood plant Aquilaria sinensis(Lour.) Gilg,a traditional medicinal plant in China,was studied in its natural distribution range.The reproductive tactics of A.sinensis were studied in detail by employing various tests dealing with fruit set and also seed dispersal.Dynamic headspace extraction followed by GC-MS analysis was also performed in order to reveal the composition of floral scent.The results showed that noctuids and pyralids are the most effective pollinators of pollinator-dependent A.sinensis.The main compounds of the floral scent were(E,E)-α-Farnesene(61.9 ± 3.2%),trans-Ocimene(16.6 ± 1.2%),and Benzyl salicylate(4.6 ± 1.1%).The results obtained from seed dispersal experiments indicate that hornets are effective seed dispersers and they may play an important role in long-distance seed dispersal of A.sinensis.Based on our findings,we recommend several protection methods for this threatened agarwood plant in China. | Gao Chen Changqiu Liu Weibang Sun | 2016 | Plant Diversity2016，38，5： | 5 |
| 7 | Semiconducting Mineralogical Characteristics of Natural Sphalerite Gestating Visible-light Photocatalysis显示文摘自然划算的光催化剂被描绘的自然闪锌矿和它的可见轻相片催化活动以代替离子,杂质阶段和表面缺点被调查。为 Zn 2+ 的金属离子的替换在可见轻反应改变乐队结构和结果。在自然闪锌矿的杂质半导体和 nanosized 粒子的共存取样帮助延长电子洞对的一生。劈开飞机和破裂表面改进由比完成式提供更活跃的地点的自然闪锌矿的催化活动面对的相片。两个都,否定费用从非等电子的替换和表面元素背叛,可变化学原子价压制了由他们捕获后象的可能的角色的电子洞对的再结合评估了洞。 | LI Yan LU Anhuai WANG Changqiu | 2009 | Acta Geologica Sinica(English Edition)2009，83，3： | 4 |
| 8 | Experimental Study on Treatment of High-concentrated Sulfur Wastewater by Process of Depositing Natrojarosite and Its Environmental Significance显示文摘摘要:有直到从一家化学工厂的 26000 mg/L 的钠和货到付款(化学的氧需求) 的集中高度的硫废水,中国的江苏省被 natrojarosite 的免职在实验室对待。结果显示废水的 COD 从 26000 mg/L 严厉地被减少到 1001 mg/L,与直到 96% 的货到付款由的移动率两次 natrojarosite 并且两次的猛冲 H2O2 的氧化。对待的硫废水到达了随后的生物化学的处理的要求浇质量。最佳的运作的参数应该在在固体每公升废水加在一起的 2.50 和 3.20 和 50 g FeCl36H2O 之间的 pH 价值上被控制。学习为集中高度的硫废水的预告的处理提供了一个试验性的基础并且在另外的废水的处理上建议了一个新矿物学的方法。扔 jarosite 和它的类似物的过程应该能被用来从我的和另外的工业对待废水移开 S, Fe 和有毒的其它和有害元素,例如作为, Cr, Hg, Pb,水里的等等。 | MA Shengfeng WANG Changqiu LU Anhuai GUO Yanjun HE Hongliao | 2007 | Acta Geologica Sinica(English Edition)2007，81，2： | 3 |
| 9 | Photoelectrochemical performance of birnessite films and photoelectrocatalytic activity toward oxidation of phenol显示文摘Birnessite films on fluorine-doped tin oxide(FTO) coated glass were prepared by cathodic reduction of aqueous KMnO_4. The deposited birnessite films were characterized with X-ray diffraction, Raman spectroscopy, scanning electron microscopy and atomic force microscopy.The photoelectrochemical activity of birnessite films was investigated and a remarkable photocurrent in response to visible light was observed in the presence of phenol, resulting from localized manganese d–d transitions. Based on this result, the photoelectrocatalytic oxidation of phenol was investigated. Compared with phenol degradation by the electrochemical oxidation process or photocatalysis separately, a synergetic photoelectrocatalytic degradation effect was observed in the presence of the birnessite film coated FTO electrode.Photoelectrocatalytic degradation ratios were influenced by film thickness and initial phenol concentrations. Phenol degradation with the thinnest birnessite film and initial phenol concentration of 10 mg/L showed the highest efficiency of 91.4% after 8 hr. Meanwhile, the kinetics of phenol removal was fit well by the pseudofirst-order kinetic model. | Huiqin Zhang Hongrui Ding Xin Wang Cuiping Zeng Anhuai Lu Yan Li Changqiu Wang | 2017 | Journal of Environmental Sciences2017，29，2： | 3 |
| 10 | Porous Properties of Nano-fibriform Silica from Natural Chrysotile显示文摘与 TEM 和物理煤气的吸附技术,多孔的性质 ofnano 纤维状的硅石(MLD:92.73%) 从天赋,纤蛇纹石在这篇论文被学习。Theresults 显示那多孔的 nano 纤维状的硅石源于 naturechrysotile 的八面的表完全溶解了的水镁石和有四面的表由酸的沥滤折叠的 Si-O。它的长度在微米或纳米规模。有毛孔的二种类型:在附近的纤维之中的毛孔和在 nanofiber 的毛孔。这些毛孔(在直径的不到 6.5 nm,主要 2.1 nm 和 3.8 nm ) 都属于中央毛孔。在纤维的毛孔在 SiO_2 粒子之中由那些组成,那些在总数,残余 nanotubes 和毛状的试管之中。Nano 纤维状的硅石作为 catalyzer 和填料的一个搬运人证明比传统的硅石好为增强橡胶和塑料。 | WANG Lijuan LU Anhuai WANG Changqiu LI Xuejun ZHENG Xishen ZHAO Dongjun LIU Rui | 2006 | Acta Geologica Sinica(English Edition)2006，80，2： | 2 |
| 11 | Semiconducting Mineral Photocatalytic Regeneration of Fe^(2+) Promotes Carbon Dioxide Acquisition by Acidithiobacillus ferrooxidans显示文摘Chemoautotrophic organisms have once been excluded from the development of universally applicable CO2 fixation technology due to its low production yields of biomass. In this study, we used Acidithiobacillus ferrooxidans (A.f.) as a model chemoautotrophic microorganism to test the hypothesis that exogenetic photoelectrons from semiconducting mineral photocatalysis can enable the regeneration of Fe2+ that could be then used by A.f. and support its growth. In a simulated electrochemical system, where exogenetic electrons were provided by an electrochemical approach, an accelerated growth rate of A.f. was observed as compared with that in traditional batch cultivation. In a coupled system, where light-irradiated natural rutile provided the primary electron source to feed A.f., the bacterial growth rate as well as the subsequent CO2 fixation rate was demonstrated to be in a light-dependent manner. The sustaining flow of photogenerated electrons from semiconducting mineral to bacteria provided an inexhaustible electron source for chemoautotrophic bacteria growth and CO2 fixation. This finding might contribute to the development of novel effective CO2 fixation technology. | LI Yan LU Anhuai WANG Xin DING Hongrui WANG Changqiu | 2013 | Acta Geologica Sinica(English Edition)2013，87，3： | 2 |
| 12 | Psammoma Bodies in Two Types of Human Ovarian Tumours: A Mineralogical Study显示文摘Mineralization in tumours is a complex dynamic process regulated by cancerization process, organic matter, mineral crystal growth mechanism, external environment, human body environment and other aspects. Differences between mineral crystals may imply different cancerization process and tumorous types. Therefore, the study on mineralization progress in human tumours can help to provide some important information on the occurrence and development of the diseases. | MENG Fanlu WANG Changqiu LI Yan LU Anhuai MEI Fang LIU Jianying | 2013 | 矿物学报2013，33，S1： | 1 |
| 13 | Nano-fibriform production of silica from natural chrysotile显示文摘 | Lu Anhuai Wang Changqiu | 2006 | Journal of Colloid and Interface Science2006，295，2： | 1 |
| 14 | Nano-fibriform production of silica from natural chrysotile显示文摘 | Lu Anhuai Wang Changqiu | 2006 | Journal of Colloid and Interface Science2006，295，2： | 1 |
| 15 | Study of the interaction between daunorubicin and human serum albumin and the determination of daunorubicin in blood serum samples 显示文摘 | Jiang Changqiu Gao Mingxa Meng Xianzhe | 2003 | Spectrochim Acta A2003，59，7： | 1 |
| 16 | New evidence from stable isotope for the uplift of mountains in northern edge of the Qinghai-Tibetan Plateau显示文摘 | Zhengle Chen Xiaofeng Wang Xiahong Feng Changqiu Wang Jian Liu | 2002 | Science in China Series B: Chemistry2002，，1： | 1 |
| 17 | The localization research of the traveling image in Henan显示文摘 | Li Changqiu | 2004 | North China water conservation and electricity in- stitute journal2004，，： | 1 |
| 18 | An adaptive grid method for two-dimensional viscous flows显示文摘 | Changqiu Jin Kun Xu | 2006 | Journal of Computational Physics2006，，1： | 1 |
| 19 | New evidence from stable isotope for the uplift of mountains in northern edge of the Qinghai-Tibetan Plateau显示文摘 | Zhengle Chen Xiaofeng Wang Xiahong Feng Changqiu Wang Jian Liu | 2002 | Science in China Series B: Chemistry2002，，1： | 1 |
| 20 | Nano-fibriform production of silica from natural chrysotile显示文摘 | Lijuan Wang Anhuai Lu Changqiu Wang Xishen Zheng Dongjun Zhao Rui Liu | 2005 | Journal of Colloid And Interface Science2005，，2： | 1 |
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