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| 1 | Crystalline and amorphous Mn0_(2)cathodes with open framework enable high-performance aqueous zinc-ion batteries显示文摘Currently,δ-Mn0_(2)is one of the popularly studied cathode materials for aqueous zinc-ion batteries(ZIBs)but impeded by the sluggish kinetics of Zn^(2+)and the Mn cathode dissolution.Here,we report our discovery in the study of crystalline/amorphous Mn0_(2)(disordered Mn0_(2)),prepared by a simple redox reaction in the order/disorder engineering.This disordered Mn0_(2)cathode material,having open framework with more active sites and more stable structure,shows improved electrochemical performance in 2 mol L^(-1)ZnSO_(4)/0.1 mol L^(-1)MnS0_(4)aqueous electrolyte.It delivers an ultrahigh discharge specific capacity of 636 mA·h·g^(-1)at 0.1 A·g^(-1)and remains a large discharge capacity of 216 mA·h·g^(-1)even at a high current density of 1 A·g^(-1)after 400 cycles.Hence disordered Mn0_(2)could be a promising cathode material for aqueous ZIBs.The storage mechanism of the disordered Mn0_(2)electrode is also systematically investigated by structural and morphological examinations of ex situ,ultimately proving that the mechanism is the same as that of the δ-Mn0_(2)electrode.This work may pave the way for the possibility of using the order/disorder engineering to introduce novel properties in electrode materials for high-performance aqueous ZIBs. | Chunfu HUANG Cong WU Zilu ZHANG Yunyun XIE Yang LI Caihong YANG Hai WANG | 2021 | Frontiers of Materials Science2021，15，2： | 0 |
| 2 | Countermeasures for Development and Present Situation of Chives in Xiaogang Town, Xiaogan City, Hubei Province显示文摘Through the overview of main problems existing in chives production, its current situation and history, the thesis puts forward countermeasures for developing chives industrialization in Xiaogang Town, Xiaogan City. | Yue CHEN Chunfu XIE Hongping LIU Huashu LIU Jian WANG Ming ZHENG Ju YUE Changbing LIU Dan LIU Hanhua TANG Yuchao PENG Yonggang NIU Ke HU | 2013 | Asian Agricultural Research2013，5，5： | 0 |
| 3 | Amorphous nickel-cobalt bimetal-organic framework nanosheets with crystalline motifs enable efficient oxygen evolution reaction: Ligands hybridization engineering显示文摘Development of high-efficiency and low-cost electrocatalyst for oxygen evolution reaction(OER) is very important for use at alkaline water electrolysis.Metal-organic frameworks(MOF) provide a rich platform for designing multi-functional materials due to their controllable composition and ultra-high surface area.Herein,we report our findings in the development of amorphous nickel-cobalt bimetal-organic framework nanosheets with crystalline motifs via a simple 'ligands hybridization engineering' strategy.These complexes' ligands contain inorganic ligands(H_2 O and NO_3) and organic ones,hexamethylenetetramine(HMT).Further,we investigated a series of mixed-metal with multi-ligands materials as OER catalysts to explore their possible advantages and features.It is found that the Ni doping is an effective approach for optimizing the electronic configuration,changing lattice ordering degree,and thus enhancing activities of HMT-based electrocatalysts.Also,the crystalline-amorphous boundaries of various HMTbased electrocatalyst can be easily controlled by simply changing amounts of Ni-precursor added.As a result,the optimized ultrathin(Co,0.3 Ni)-HMT nanosheets can reach a current density of 10 mA cm^(-2)at low overpotential of 330 mV with a small Tafel slope of 66 mV dec^(-1).Our findings show that the electronic structure changes induced by Ni doping,2 D nanosheet structure,and MOF frameworks with multiligands compositions play critical roles in the enhancement of the kinetically sluggish electrocatalytic OER.The present study emphasizes the importance of ligands and active metals via hybridization for exploring novel efficient electrocatalysts. | Yang Li Zhonggui Gao Huiming Bao Binghui Zhang Cong Wu Chunfu Huang Zilu Zhang Yunyun Xie Hai Wanga | 2021 | Journal of Energy Chemistry2021，30，2： | 0 |
| 4 | Exergy as an ecological application used in the recovery process of benthic communities显示文摘Exergy,the thermodynamic function that represents the distance of an open system from equilibrium,is proposed as an ecological indicator for summarizing the complex dynamics occurring in a disturbed community during its recovery processes.These complex dynamics can be difficult to capture by using classical indices.In this study,we sampled macrobenthos using the BACI scheme(before versus after;control versus impact)in tidal wetlands of west Chongming Island,China,an area that has been disturbed by ecological engineering measures.Exergy storage is estimated for benthic communities.The control area is proposed as dynamic reference for estimating local exergy storage of the benthic community.Three different methods were used for estimating exergy on the basis of coefficients:(a)taken for taxa groups;(b)estimated from coding genes given for broad taxonomic groups;and(c)estimated from genome size taken as close as possible to the taxonomic level of the species,providing a basis for inferring similarities.We found a decrease of local exergy content in the disturbed area 9 days after the disturbance.Subsequently,the reference exergy of the benthic community increased(i.e.in the surrounding control area)in accordance with the proposed hypothesis regarding the dynamics of exergy storage during a system’s development.Estimates of local exergy arrived at using the three methods provided comparable results.Based on this,we then discuss the feasibility of using the more readily available genome size data for estimating exergy.This result may have important implications for broader application of this indicator to biological systems.Moreover,the adjacent control samples seem to represent an appropriate dynamic reference for estimating the local exergy of disturbed communities.We found that exergy was a useful indicator that integrates the processes underlying the recovery of the benthic community after disturbance. | Feijun ZHANG Chunfu TONG Zhifa XIE Jianjian LU | 2007 | Integrative Zoology2007，2，1： | 0 |
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