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| 1 | Nanosphere molecularly imprinted polymers doped with gold nanoparticles for high selectivity molecular sensors显示文摘我们报导分子地使用的第一次尝试在为散布的提高的拉曼(重量的单位) 基于分子的种类察觉到的表面与金 nanoparticles (AuNPs ) 被做的 nanoparticles 的形状印了聚合物(MIP ) 。明确地,分子地做的 AuNPs 印了 nano 范围(AuNPs@nanoMIPs ) 被一个壶降水聚合为察觉到的 SERS 作为模板用苏丹 IV 综合。AuNPs@nanoMIPs 被扫描在 MIP 粒子内显示出 AuNPs 的准确地点的传播电子显微镜学(茎) 的各种各样的模式描绘。Au 集中和在形状和粒子的多分散性上激动人心的答案的效果被学习。仅仅当 MIP 粒子与 AuNPs 被做时,拉曼信号的重要改进被观察。重量的单位信号在 AuNPs@nanoMIPs 内随 Au 集中的增加显著地改善了。印的 AuNPs@nanoMIPs 与不同苏丹衍生物执行了的苏丹 IV 的选择大小显示出做 AuNPs 的 MIP 粒子的高选择。 | Tehila Shahar Tama Sicron Daniel Mandler | 2017 | Nano Research2017，10，3： | 3 |
| 2 | Electrodeposited Sulfur and CoxS Electrocatalyst on Buckypaper as High-Performance Cathode for Li-S Batteries显示文摘Lithium-sulfur batteries(LSBs)are considered as the next generation of advanced rechargeable batteries because of their high energy density.In this study,sulfur and CoxS electrocatalyst are deposited on carbon nanotube buckypaper(S/CoxS/BP)by a facile electrodeposition method and are used as a binder-free high-performance cathode for LSBs.Elemental sulfur is deposited on buckypaper by electrooxidation of a polysulfide solution(-S6^2-).This approach substantially increased the current and time efficiency of sulfur electrochemical deposition on conductive material for LSBs.S/CoxS/BP cathode could deliver an initial discharge capacity as high as 1650 mAh g^-1 at 0.1 C,which is close to the theoretical capacity of sulfur.At current rate of 0.5 C,the S/CoxS/BP has a capacity of 1420 mAh g^-1 at the first cycle and 715 mAh g^-1 after 500 cycles with a fading rate of 0.099%per cycle.The high capacity of S/CoxS/BP is attributed to both the homogeneous dispersion of nanosized sulfur within BP and the presence of CoxS catalyst.The sodium dodecyl sulfate(SDS)pretreatment of BP renders it polarity to bind polysulfides and thus facilitates the good dispersibility of nanosized sulfur within BP.CoxS catalyst accelerates the kinetics of polysulfide conversion and reduces the presence of polysulfide in the cathode,which suppresses the polysulfide diffusion to anode,i.e.,the shuttle effect.The mitigation of the active material loss improves not only the capacity but also the cyclability of S/CoxS/BP. | Yi Zhan Andrea Buffa Linghui Yu Zhichuan JXu Daniel Mandler | 2020 | Nano-Micro Letters2020，12，10： | 2 |
| 3 | Electrodeposition of sol-gel films on Al for corrosion protection显示文摘 | Mari Sheffer Alec Groysman Daniel Mandler | 2003 | Corrosion Science2003，45，12： | 1 |
| 4 | Microelectrochemistry on Surfaces with the Scanning Electrochemical Microscope (SECM)显示文摘 | Daniel Mandler Sheffer Meltzer Ilan Shohat | 2013 | Isr J Chem2013，，1： | 1 |
| 5 | Methanol electro-oxidation to formate on iron-substituted lanthanum cobaltite perovskite oxides显示文摘Electrochemically producing formate by oxidizing methanol is a promising way to add value to methanol.Noble metal-based electrocatalysts,which have been extensively studied for the methanol oxidation reaction,can catalyze the complete oxidation of methanol to carbon dioxide,but not the mild oxidation to formate.As a result,exploring efficient and earth-abundant electrocatalysts for formate production from methanol is of interest.Herein,we present the electro-oxidation of methanol to formate,catalyzed by iron-substituted lanthanum cobaltite(LaCo_(1-x)Fe_(x)O_(3)).The Fe/Co ratio in the oxides greatly influences the activity and selectivity.This effect is attributed to the higher affinity of Fe and Co to the two reactants:CH3OH and OH,respectively.Because a balance between these affinities is favored,LaCo_(0.5)Fe_(0.5)O_(3) shows the highest formate production rate,at 24.5 mmol h^(-1) g_(oxide)^(-1),and a relatively high Faradaic efficiency of 44.4%in a series of(LaCo_(1-x)Fe_(x)O_(3))samples(x=0.00,0.25,0.50,0.75,1.00)at 1.6 V versus a reversible hydrogen electrode. | Fanxu Meng Chencheng Dai Zheng Liu Songzhu Luo Jingjie Ge Yan Duan Gao Chen Chao Wei Riccardo Ruixi Chen Jiarui Wang Daniel Mandler Zhichuan J.Xu | 2022 | eScience2022，2，1： | 1 |
| 6 | Selective determination of Cr(VI) by a self-assembled monolayer-based electrode显示文摘 | lva Turyan Daniel Mandler | 1997 | Anal Chem1997，69，5： | 1 |
| 7 | Self-assembled monolayers in electroanalytical chemistry application of ω-mercapto carboxylic acid monolayers for the electrochemical detection of dopamine in the presence of a high condentration of ascorbic acid显示文摘 | Franck Malemm Daniel Mandler | 1993 | Anal Chem1993，65，： | 1 |
| 8 | Effect of matrix-nanoparticle interactions on recognition of aryldiazonium nanoparticle-imprinted matrices显示文摘The selective recognition of nanoparticles (NPs) can be achieved by nanoparticle-imprinted matrices (NAIMs),where NPs are imprinted in a matrix followed by their removal to form voids that can reuptake the original NPs.The recognition depends on supramolecular interactions between the matrix and the shell of the NPs,as well as on the geometrical suitability of the imprinted voids to accommodate the NPs.Here,gold NPs stabilized with citrate (AuNPs-cit) were preadsorbed onto a conductive surface followed by electrografting of p-aryldiazonium salts (ADS) with different functional groups.The thickness of the matrix was carefully controlled by altering the scan number.The AuNPs-cit were removed by electrochemical dissolution.The recognition of the NAIMs was determined by the reuptake of the original AuNPs-cit by the imprinted voids.We found that the recognition efficiency is a function of the thickness of the NAIM layer and is sensitive to the chemical structure of the matrix.Specifically,a subtle change of the functional group of the p-aryldiazonium building block,which was varied from an ether to an ester,significantly affected the recognition of the NPs. | Netta Bruchiel-Spanier Linoy Dery Noam Tal Shahar Dery Elad Gross Daniel Mandler | 2019 | Nano Research2019，12，2： | 0 |
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