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| 1 | Chemical vapor deposition growth of phase-selective inorganic lead halide perovskite films for sensitive photodetectors显示文摘Inorganic lead halide perovskites are attractive optoelectronic materials owing to their relative stability compared to organic cation alternatives.The chemical vapor deposition(CVD) method offers potential for high quality perovskite film growth.The deposition temperature is a critical parameter determining the film quality owing to the melting difference between the precursors.Here,perovskite films were deposited by the CVD method at various temperatures between 500-800℃.The perovskite phase converts from CsPb_(2)Br_(5) to CsPbBr_(3) gradually as the deposition temperature is increased.The grain size of the perovskite films also increases with temperature.The phase transition mechanism was clarified.The photoexcited state dynamics were investigated by spatially and temporally resolved fluorescence measurements.The perovskite film deposited under 750℃ condition is of the CsPbBr_(3) phase,showing low trap-state density and large crystalline grain size.A photodetector based on perovskite films shows high photocurrent and an on/off ratio of ~2.5×10^(4). | Weilong Xu Mengsi Niu Xiaoyu Yang Haiyue Chen Xiaohong Cai Trevor A.Smith Kenneth PGhiggino Xiaotao Hao | 2021 | Chinese Chemical Letters2021，32，1： | 2 |
| 2 | Optimum Anti-erosion Structures and Anti-erosion Mechanism for Rotatory Samples Inspired by Scorpion Armor of Parabuthus transvaalicus显示文摘Solid particle erosion on the material surfaces is a very common phenomenon in the industrial field,which greatly affects the efficiency,service life,and even poses a great threat to life safety.However,current research on erosion resistance is not only inefficient,but also limited to the improvement of hardness and toughness of materials.Inspired by typical scorpion(Parabuthus transvaalicus),biomimetic functional samples with exquisite anti-rosion structures were manufactured.Macroscopic morphology and structure of the biological prototype were analyzed and measured.According to above analysis,combined with response surface methodology,a set of biomimetic samples with different structural parameters were fabricated by using 3D printing technology.The anti-crosion performance of these biomimetic samples was investigated using a blasting jet machine.Based on the results of blasting jet test,as well as regression analysis and fiting,the optimal structural parameters were obtained.In addition to the static test conditions,the optimal biomimetic sample was also eroded in rotating condition and showed excellent erosion resistance property.The presence of bump and groove structures,on the one hand,reduced the croded area of biominetic sample surface.On the other hand,they made the airlow turbulent and consequently reduced the impact cnergy of solid particles,which significantly improved the erosion resistance of biomimetic materials.This study provides a new strategy to improvethe service life of components easily affected by erosion in the aviation,energy and military fields. | Shuaijun Zhang Wenna Chen Bo Li Shichao Niu Haiyue Yu Yahua Liu Xiao Yang Junqiu Zhang Zhiwu Han Luquan Ren | 2021 | Journal of Bionic Engineering2021，18，1： | 0 |
| 3 | A high-resolution transcriptomic atlas depicting nitrogen fixation and nodule development in soybean显示文摘Although root nodules are essential for biological nitrogen fixation in legumes,the cell types and molecular regulatory mechanisms contributing to nodule development and nitrogen fixation in determinate nodule legumes,such as soybean(Glycine max),remain incompletely understood.Here,we generated a single-nucleus resolution transcriptomic atlas of soybean roots and nodules at 14 days post inoculation(dpi)and annotated 17 major cell types,including six that are specific to nodules.We identified the specific cell types responsible for each step in the ureides synthesis pathway,which enables spatial compartmentalization of biochemical reactions during soybean nitrogen fixation.By utilizing RNA velocity analysis,we reconstructed the differentiation dynamics of soybean nodules,which differs from those of indeterminate nodules in Medicago truncatula.Moreover,we identified several putative regulators of soybean nodulation and two of these genes,GmbHLH93 and GmSCL1,were as-yet uncharacterized in soybean.Overexpression of each gene in soybean hairy root systems validated their respective roles in nodulation.Notably,enrichment for cytokinin-related genes in soybean nodules led to identification of the cytokinin receptor,GmCRE1,as a prominent component of the nodulation pathway.GmCRE1 knockout in soybean resulted in a striking nodule phenotype with decreased nitrogen fixation zone and depletion of leghemoglobins,accompanied by downregulation of nodule-specific gene expression,as well as almost complete abrogation of biological nitrogen fixation.In summary,this study provides a comprehensive perspective of the cellular landscape during soybean nodulation,shedding light on the underlying metabolic and developmental mechanisms of soybean nodule formation. | Baocheng Sun Yu Wang Qun Yang Han Gao Haiyu Niu Yansong Li Qun Ma Qing Huan Wenfeng Qian Bo Ren | 2023 | Journal of Integrative Plant Biology2023，65，6： | 0 |
| 4 | A density functional theory study of methane activation on MgO supported Ni_(9)M_(1) cluster:role of M on C-H activation显示文摘Methane activation is a pivotal step in the application of natural gas converting into high-value added chemicals via methane steam/dry reforming reactions.Ni element was found to be the most widely used catalyst.In present work,methane activation on MgO supported Ni–M(M=Fe,Co,Cu,Pd,Pt)cluster was explored through detailed density functional theory calculations,compared to pure Ni cluster.CH_(4)adsorption on Cu promoted Ni cluster requires overcoming an energy of 0.07 eV,indicating that it is slightly endothermic and unfavored to occur,while the adsorption energies of other promoters M(M=Fe,Co,Pd and Pt)are all higher than that of pure Ni cluster.The role of M on the first C–H bond cleavage of CH_(4)was investigated.Doping elements of the same period in Ni cluster,such as Fe,Co and Cu,for C–H bond activation follows the trend of the decrease of metal atom radius.As a result,Ni–Fe shows the best ability for C–H bond cleavage.In addition,doping the elements of the same family,like Pd and Pt,for CH_(4)activation is according to the increase of metal atom radius.Consequently,C–H bond activation demands a lower energy barrier on Ni–Pt cluster.To illustrate the adsorptive dissociation behaviors of CH_(4)at different Ni–M clusters,the Mulliken atomic charge was analyzed.In general,the electron gain of CH_(4)binding at different Ni–M clusters follows the sequence of Ni–Cu(–0.02 e) | Juntian Niu Haiyu Liu Yan Jin Baoguo Fan Wenjie Qi Jingyu Ran | 2022 | Frontiers of Chemical Science and Engineering2022，16，10： | 0 |
| 5 | Enhanced performance of oxygen vacancies on CO_(2) adsorption and activation over different phases of ZrO_(2)显示文摘The effect of oxygen vacancies on the adsorption and activation of CO_(2) on the surface of different phases of ZrO_(2) is investigated by density functional theory(DFT)calculations.The calculations show that the oxygen vacancies contribute greatly to both the adsorption and activation of CO_(2).The adsorption energy of CO_(2) on the c-ZrO_(2),t-ZrO_(2) and,m-ZrO_(2) surfaces is enhanced to 5,4,and 3 folds with the help of oxygen vacancies,respectively.Moreover,the energy barrier of CO_(2) dissociation on the defective surfaces of c-ZrO_(2),t-ZrO_(2),and m-ZrO_(2) is reduced to 1/2,1/4,and 1/5 of the perfect surface with the assistance of oxygen vacancies.Furthermore,the activation of CO_(2) on the ZrO_(2) surface where oxygen vacancies are present,and changes from an endothermic reaction to an exothermic reaction.This finding demonstrates that the presence of oxygen vacancies promotes the activation of CO_(2) both kinetically and thermodynamically.These results could provide guidance for the high-efficient utilization of CO_(2) at an atomic scale. | Juntian NIU Cunxin ZHANG Haiyu LIU Yan JIN Riguang ZHANG | 2023 | Frontiers in Energy2023，17，4： | 0 |
| 6 | Single-cell RNA sequencing reveals abnormal transcriptome signature of erythroid progenitors in pure red cell aplasia显示文摘Pure red cell aplasia(PRCA)is a bone marrow failure syndrome characterized by severe anemia,reticulocytopenia,selective reduction,and even the absence of bone marrow erythroid precursors,while leukocyte and platelet counts are normal.1 Acquired PRCA can be divided into primary and secondary.Both are mediated by immune responses.Reduction in the quantity and dysfunction of committed erythroid progenitors(EPs),including burst forming uniterythroid(BFU-E)and colony forming unit-erythroid(CFU-E),may be the source of reduced erythropoiesis and needs to be elucidated. | Yumei Liu Haiyue Niu Jie Ren Zhiqin Wang Li Yan Limin Xing Zonghong Shao Rong Fu Zhigang Cai Huaquan Wang | 2024 | Genes & Diseases2024，11，1： | 0 |
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