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| 1 | Reactive mesoporous silica nanoparticles loaded with limonene for improving physical and mental health of mice at simulated microgravity condition显示文摘Astronauts are under high stress for a long time because of the microgravity condition,which leads to anxiety,affects their learning and memory abilities,and seriously impairs the health of astronauts.Aromatherapy can improve the physical and mental health of astronauts in a way that moisturizes them softly and silently.However,the strong volatility of fragrances and inconvenience of aroma treatment greatly limit their application in the field of spaceflight.In this study,reactive mesoporous silica nanoparticles were prepared to encapsulate and slowly release limonene.The limonene loaded nanoparticles were named limonene@mesoporous silica nanoparticles-cyanuric chloride(LE@MSNs-CYC).LE@MSNs-CYC were then applied to wallpaper to improve the convenience of aromatherapy.LE@MSNs-CYC could chemically react with the wallpaper,thus firmly adsorbed on the wallpaper.In the following,the mice were treated with hindlimb unloading(HU)to simulate a microgravity environment.The results showed that 28-day HU led to an increase in the level of anxiety and declines in learning,memory,and physical health in mice.LE@MSNs-CYC showed significant relief effects on anxiety,learning,memory,and physical health of HU treated mice.Subsequently,the molecular mechanisms were explored by hypothalamic-pituitary-adrenal axis related hormones,immune-related cytokines,learning,and memory-related neurotransmitters and proteins. | Zhiguo Lu Jianze Wang Lina Qu Guanghan Kan Tianlu Zhang Jie Shen Yan Li Jun Yang Yunwei Niu Zuobing Xiao Yinghui Li Xin Zhang | 2020 | Bioactive Materials2020，5，4： | 5 |
| 2 | Dynamic apertures with diffusion-regulatory functionality in soft porous crystals:A key to solving the century puzzle on isotopologues separation显示文摘The separation of water isotopologues has been a“century-old”challenge,also known as“the Holy Grail”in separation science.Heavy water(D2O)is a stable non-radioactive water isotopologue that plays a critical role in scientific research,military,nuclear energy,and medical fields.Heavy water was first reported in 1931 when H.C.Urey discovered D2 and D2O,for which he was awarded the Nobel Prize in Chemistry in 1934.Then in 1933,G.N.Lewis et al.obtained 0.5μL of heavy water at a concentration of around 65.7%when electrolyzing 10 liters of water.In 1935,the world's first heavy water plant was built in Norway,producing 2 tons of heavy water by electrolysis,but the separation factor was merely 1.05,which was extremely energy-consuming.In 1943,the first heavy water plant employing the distillation method was built in the United States. | Yanhong Li Jianze Xiao Yangyang Guo Ning Han Fangli Yuan Yunfa Chen Ming-Shui Yao | 2023 | Nano Research2023，16，2： | 1 |
| 3 | 显示文摘 | Jianz C B Liang T Xu H B | 2002 | ADDI Phvs Lett2002，81，： | 1 |
| 4 | Increase ofmacrophage migration inhibitory factor (MIF) expression in cardiomyocytes during chronic hypoxia显示文摘 | JIANZ LIJB MARY | | 0，，1： | 1 |
| 5 | The deubiquitinating gene Usp29 is dispensable for fertility in male mice显示文摘The balanced actions between ubiquitination and deubiquitination precisely control the levels of various proteins vital for spermatogenesis. Ubiquitin-specific processing proteases(USPs) are the largest family of deubiquitinatingenzymes(DUBs),containing more than 50 members. So far, the functions of only a few USPs in male fertility have been studied, the roles of the majority are yet unknown. The present study aimed to explore the function of Usp29(ubiquitin-specific protease 29) in male fertility. We found that Usp29 showed predominant expression in mouse testis, and its m RNA expression started to increase at 14 days postpartum(dpp), with a peak at 28 and 35 dpp. Using CRISPR/Cas9 technology, we generated Usp29 knockout mice(Usp29^(–/–)). Usp29^(–/–)mice exhibited no overt developmental anomalies. Further examination revealed that Usp29^(–/–)mice had normal fertility and showed no detectable difference in the testis/body weight ratio, testicular and epididymal histology as well as epididymal sperm count from the wild-type littermates. Moreover, Usp29 is not a pseudogene in mice. Taken together, our study first reported that though Usp29 is predominantly expressed in the testis, it is not essential for male fertility in mice. | Zhu Huang Manan Khan Jianze Xu Teka Khan Hui Ma Ranjha Khan Hafiz Muhammad Jafar Hussain Xiaohua Jiang Qinghua Shi | 2019 | Science China(Life Sciences)2019，62，4： | 1 |
| 6 | Manipulating fluid with vibrating 3D-printed paddles for applications in micropump显示文摘This paper presents a novel working mechanism of a micropump using micropaddles(MPs)to actively manipulate fluid based on 3 D printing technology.The novel working principle is systematically discussed using analysis,computation and experiment methods.A theoretical model is established to research the working mechanism and crucial parameters for driving ability,such as MPs shape,size,vibration amplitude and frequency.Two different 3 D printing techniques that simplify the multi-step process into only one step are introduced to manufacture the prototype pump for investigating the principle experimentally.A testing system is designed to evaluate the flow rate of pumps with eight different vibrating paddles.A maximum flux of 127.9 mL/min is obtained at an applied voltage of 9 V.These experiments show that the active-type mechanical pump could not only freely control flow direction but also change flux by adopting different shapes or distribution ways.The advantage of the novel micropump is the application of the MP structure into the micropump system to actively manipulate fluid with flexibility and high driving ability at fairly low power. | Zhiyong Tang Xiufeng Shao Jianze Huang Jinyuan Yao Guifu Ding | 2019 | Nanotechnology and Precision Engineering2019，2，3： | 0 |
| 7 | Preparation of hollow mesoporous silica nanorods for encapsulating and slowly releasing eugenol显示文摘Fragrances are widely used in many aspects of our lives.They cannot only make people happy,but also treat many diseases.However,excessively fast evaporation rate is one of the main obstacles to the use of spices.In this study,mesoporous silica nanorods(MSNRs)and hollow mesoporous silica nanorods(HMSNRs)were prepared to encapsulate eugenol.These two nano-fragrances were named eugenol@MSNRs and eugenol@HMSNRs,respectively.The morphologies,size,interior structures and pore performances of MSNRs and HMSNRs.Besides,the performances of encapsulation and fragrance release of eugenol@MSNRs and eugenol@HMSNRs were compared and analyzed.The results showed that eugenol@HMSNRs encapsulated more fragrance and were faster to encapsulate compared with eugenol@MSNRs.Both the release rates of eugenol from eugenol@MSNRs and eugenol@HMSNRs were slow.But the eugenol was released from eugenol@MSNRs more slowly. | Tianlu Zhang Zhiguo Lu Luyao Zhang Yan Li Jun Yang Jie Shen Jianze Wang Yunwei Niu Zuobing Xiao Lei Chen Xin Zhang | 2020 | Chinese Chemical Letters2020，31，12： | 0 |
| 8 | Cationic and temperature-sensitive liposomes loaded with eugenol for the application to silk显示文摘Silk has been widely used in the clothing industry due to their soft and smooth features,good biocompatibility,good heat dissipation,warmth and ultraviolet resistance.The application of fragrance to silk can significantly improve the performance of silk.However,there are two key scientific problems that need to be solved:slowing down the release rate of fragrances and increasing the scent lasting time of silk.In this study,cationic and temperature-sensitive liposomes were designed and prepared to encapsulate eugenol.These fragrance-loaded liposomes significantly slowed down the release rate of the fragrance and controlled the release rate of the fragrance in a thermo-sensitive manner.The liposomes adhered to the silk through electrostatic adsorption interaction.The positive charge on the fragranceloaded liposomes neutralized much negative charge on silk and thereby increasing the adhesion efficiency. | Zhiguo Lu Xiangyu Wang Tianlu Zhang Luyao Zhang Jun Yang Yan Li Jie Shen Jianze Wang Yunwei Niu Zuobing Xiao Guiying Liu Xin Zhang | 2020 | Chinese Chemical Letters2020，31，12： | 0 |
| 9 | Reactive nano-essential oils for sustained release of essential oils and application to wallpaper显示文摘Essential oils are a volatile and aromatic substance with a variety of active biological activities.However,the excessive volatility and inconvenience of the use of essential oils limit their applications.In this study,we developed a reactive mesoporous silica nanoparticle(rMSNs)based on cyanuric chloride modification for essential oil encapsulation and commodity adhesion.The large pore volume and specific surface area of rMSNs facilitate the nanoparticles adhering to a large amount of essential oil and achieve the sustained release of essential oil,thus prolonging the fragrance retention time of essential oils.The reactive nanoessential oils can form covalent bonds with the wallpaper,thereby remarkably improving the adhesion of the reactive nano-essential oils on the wallpaper and preventing the reactive nano-essential oil from deadhering from the wallpaper.The active nano essential oil simultaneously overcomes the intense volatility of the essential oil and inconvenience in use,has a simple preparation process and low cost,and has great application potential. | Qiulian Hao Huan Peng Ruichen Zhao Jianze Wang Zhiguo Lu Jingwen Wang Jie Shen Yunwei Niu Zuobing Xiao Guiying Liu Jifu Hao Xin Zhang | 2022 | Chinese Chemical Letters2022，33，1： | 0 |
| 10 | Possibly non-unital operator system structures on a possibly non-unital function system显示文摘在这份报纸,我们首先给定义可能 non-unital 功能系统,它是在有导致的顺序和标准结构的一个紧缩的 Hausdorff 空格的连续功能的空间的自我伴随 subspace 的描述。类似于操作符系统大小写,我们定义 unitalization 一可能 non-unital 函数系统。然后,我们可能构造二 non-unital 操作符系统结构在上一可能给 non-unital 函数系统,它是在一个 normed 空格的最小、最大的操作符空格的类似物。这二结构在一个给定的功能系统上与最小、最大的操作员系统结构有许多有趣的关系。 | Jianze LI | 2012 | Frontiers of Mathematics in China2012，7，5： | 0 |
| 11 | Atomically Thin 2D TiO_(2) Nanosheets with Ligand Modified Surface for Ultra-sensitive Humidity Sensor显示文摘As a kind of two-dimensional(2D)nanostructured materials,metal oxide nanosheets(MONS)are attractive and promising humidity sensing materials due to their considerable surface area,good charge carrier transportation,and designable surface functional groups properties.Nevertheless,the ultra-thin MONS modified with active functional groups for humidity sensing are still rare.As a proof of concept,the atomically thin TiO_(2)nanosheets with high surface area and electron-donating amino groups are prepared by a structure-maintained post-ligand modification strategy.The fabricated TiO_(2)-based sensors demonstrate superior humidity sensing performance with high response,short response time,narrow hysteresis,and ultra-low theoretical limit of detection of about 15 ppm.Additionally,the possible mechanism is proposed from the AC complex impedance measurements and DC instantaneous reverse polarity experiments.This work provides a possible path for developing the high-performance 2D nanostructured metal oxides-based humidity materials through the surface chemical method. | Jianze Xiao Zhihua Fu Guane Wang Xiaoliang Ye Gang Xu | 2022 | Chinese Journal of Structural Chemistry2022，41，4： | 0 |
| 12 | Preparation of mesoporous silica nanoparticle with tunable pore diameters for encapsulating and slowly releasing eugenol显示文摘Fragrances are frequently added to a variety of products,including food,cosmetics and health products.However,the high volatility and instability of essence limit its application in some fields.In this study,mesoporous silica nanoparticles(MSNs) were prepared to encapsulate eugenol,which could reduce the volatilization of the fragrance molecules.A facile approach was presented to synthesize MSNs with three different pore diameters for encapsulating eugenol.In addition,the properties of MSNs including mean particle size,morphology,encapsulating efficiency and release tendency were charac terized.Results showed that the larger the pore diameters of MSNs,the more aromatic molecules were adsorbed.Furthermore,the release mechanism was described as the smaller the pore diameters of MSNs,the slower the release of eugenol. | Tianlu Zhang Zhiguo Lu Jianze Wang Jie Shen Qiulian Hao Yan Li Jun Yang Yunwei Niu Zuobing Xiao Lei Chen Xin Zhang | 2021 | Chinese Chemical Letters2021，32，5： | 0 |
| 13 | Diastereoselective 2,3-diazidation of indoles via copper(Ⅱ)-catalyzed dearomatization显示文摘The copper-catalyzed directed dearomatization of indoles with the assistance of directing groups has been developed for the synthesis of 2,3-diazido indolines with good yields and excellent diastereoselectivities in aqueous solution.The resultant 2,3-diazides can be smoothly converted to other functional groups,including vicinal diamines,triazoles and benzotriazoles,in a single step. | Jiang Liu Zhongjin Fang Xin Liu Yandong Dou Jianze Jiang Fangfang Zhang Jiaojiao Qu Qing Zhu | 2020 | Chinese Chemical Letters2020，31，5： | 0 |
| 14 | Zwitterionic comb-like lipid polymers encapsulating linalool for increasing the fragrance retention time显示文摘Fragrances are widely used in cosmetics,apparel and detergents.However,the rapid evaporation of the aro ma shortens the useful life of the aromatic product.Therefore,improving the fragrance retention time of aromatic products and prolonging the service life of aromatic products are the key scientific problems that need to be solved in current aromatic products.In this study,zwitterionic comb-like lipid polymers were synthesized to encapsulate the fragrance molecule linalool.The results showed that the zwitterionic comb lipid molecules were capable of encapsulating more linalool than linear lipid molecules.At the same time,the zwitterionic comb-like lipid molecules also limited the slow release rate of the aroma,thereby increasing the fragrance retention time of the nano-fragrance. | Tianlu Zhang Zhiguo Lu Xiangyu Wang Jie Shen Jianze Wang Yunwei Niu Zuobing Xiao Xin Zhang | 2021 | Chinese Chemical Letters2021，32，1： | 0 |
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