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| 1 | Transition Metal Aluminum Boride as a New Candidate for Ambient-Condition Electrochemical Ammonia Synthesis显示文摘Achieving more meaningful N2 conversion by reducing the energy input and carbon footprint is now being investigated through a method of N2 fixation instead of the Haber-Bosch process.Unfortunately,the electrochemical N2 reduction reaction(NRR)method as a rising approach currently still shows low selectivity(Faradaic efficiency<10%)and high-energy consumption[applied potential at least-0.2 V versus the reversible hydrogen electrode(RHE)].Here,the role of molybdenum aluminum boride single crystals,belonging to a family of ternary transition metal aluminum borides known as MAB phases,is reported for the electrochemical NRR for the first time,at a low applied potential(-0.05 V versus RHE)under ambient conditions and in alkaline media.Due to the unique nano-laminated crystal structure of the MAB phase,these inexpensive materials have been found to exhibit excellent electrocatalytic performances(NH3 yield:9.2μg h^-1cm^-2mgcat^-1.,Faradaic efficiency:30.1%)at the low overpotential,and to display a high chemical stability and sustained catalytic performance.In conjunction,further mechanism studies indicate B and Al as main-group metals show a highly selective affinity to N2 due to the strong interaction between the B 2p/Al 3p band and the N 2p orbitals,while Mo exhibits specific catalytic activity toward the subsequent reduction reaction.Overall,the MAB-phase catalyst under the synergy of the elements within ternary compound can suppress the hydrogen evolution reaction and achieve enhanced NRR performance.The significance of this work is to provide a promising candidate in the future synthesis of ammonia. | Yang Fu Peter Richardson Kangkang Li Hai Yu Bing Yu Scott Donne Erich Kisi Tianyi Ma | 2020 | Nano-Micro Letters2020，12，5： | 3 |
| 2 | A solid solution pumping mechanism for the nitrogenation of titanium during mechanical deformation in air 显示文摘 | ZHANG H KISI E H MYHRA S | 1996 | J Phys D: Appl Phys1996，29，5： | 1 |
| 3 | Myocyte apoptosis: programming ventricular re- modeling显示文摘 | Mani K Kisis RN | 2003 | J Am Coil Cardiol2003，41，5： | 1 |
| 4 | The hydrogen acti- vation of LaNi5 显示文摘 | Kisi E H Buckley C E Gray E M | 1992 | J Alloys and Comp1992，185，2： | 1 |
| 5 | In-situ neutron diffraction of titanium silicide TisSi3 during self-propagating high-temperature synthesis显示文摘 | Riley D P Oliver C P Kisi E H | 2006 | Intermetallic2006，，14： | 1 |
| 6 | SVM, ANFIS, regression and climate based models for reference evapotranspiration modeling using limited climatic data in a semi-arid highland environment显示文摘 | Hossein Tabari Ozgur Kisi Azadeh Ezani P. Hosseinzadeh Talaee | 2012 | Journal of Hydrology2012，，： | 1 |
| 7 | Daily reference evapotranspi-ration modeling by using genetic programming approach in theBasque Country (Northern Spain)显示文摘 | Shiri J Kisi O Landeras G | 2012 | Journal of Hydrology2012，，： | 1 |
| 8 | Ti3SiC2-A Layered Ceramic Echibiting Ultra-low Friction显示文摘 | Summers J W B Kisi E H | 1999 | Materials Letters1999，39，1： | 1 |
| 9 | Ti3SiC2-A lay- ered ceramic exhibiting ultra-low friction显示文摘 | MYHRA S SUMMERS J W B KISI E H | 1999 | Mater Lett1999，39，1： | 1 |
| 10 | The effect of rare earth on the trace elements of some organ in rat 显示文摘 | Ogawa Y Kisi Y Chiba M | 1991 | Biomed Res Trace Elem1991，2，2： | 1 |
| 11 | Modeling of dissolved oxygen concentration using different neural network techniques in foundation creek, E1 Paso County, Colorado 显示文摘 | Ay M Kisi O | 2012 | Journal of Environmental Engineering2012，138，6： | 1 |
| 12 | Wavelet regression model as an alternative toneural networks for river stage forecasting 显示文摘 | Kisi 0 | 2011 | WaterResource Management2011，25，2： | 1 |
| 13 | Evapotranspiration Modelling from Climatic Data Using a Neural Computing Technique显示文摘 | Kisi Ozgur | 2007 | Hydrological Processes2007，21，14： | 1 |
| 14 | A Combined Generalized Regression Neural Network Wavelet Model for Monthly Streamflow Prediction 显示文摘 | Kisi O | 2011 | Journal of Civil Engineering2011，15，8： | 1 |
| 15 | Daily pan evaporation modeling using a neuro-fuzzy computing technique 显示文摘 | Kisi O | 2006 | Journal of Hydrolo-gy2006，329，34： | 1 |
| 16 | Suspended sediment concentration estimation by an adaptive neuro-fuzzy and neural network approaches using hydro- meteorological data显示文摘 | Cobaner M Unal B Kisi O | 2009 | Journal of Hydrology2009，367，： | 1 |
| 17 | A probe into the chaotic nature of daily stream flow time series by correlation dimension and largest Lyapunov method显示文摘 | Ghorbani M A Kisi O Aalinezhad M | 2010 | Applied Mathematical Model- ing2010，34，12： | 1 |
| 18 | Sesquiterpenoids and phenolics from Crepisrnollis 显示文摘 | Kisie W Zielifiska K Joshi S P | 2000 | Phytochemistry2000，54，8： | 1 |
| 19 | Intestinal - type and liver - type fatty acid - binding protein in the intestine Tissue distribution and clinical utility 显示文摘 | Pe|sers MM Nmniot Z Kisie|ewski W | 2003 | Clin Biochemi2003，36，7： | 1 |
| 20 | Ultra - lowfriction for a layered carbide - derived ceramic, Ti3SiC2,investigated by lateral force microscopy ( LFM) 显示文摘 | Crossley A Kisi E H Bennett Summers J W | 1999 | Journal ofPhysics D - Applied Physics1999，32，： | 1 |
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