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158篇 您的检索式:作者名="LI Huaming"
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1Pathological evidence for residual SARS-CoV-2 in pulmonary tissues of a ready-for-discharge patient显示文摘Dear Editor,SARS-CoV-2,a novel coronavirus and causing COVID-19,has given rise to a worldwide pandemic.1,2 So far,tens of thousands of COVID-19 patients have been clinically cured and discharged,but multiple COVID-19 cases showed SARS-CoV-2 positive again in discharged patients,3 which raises an attention for the discharged patients.Also,there is an urgent need to understand the pathogenesis of SARS-CoV-2 infection.Here,we conducted postmortem pathologic study in a ready-fordischarge COVID-19 patient who succumbed to sudden cardiovascular accident.Pathological examination revealed SARSCoV-2-viruses remaining in pneumocytes and virus-caused pathological changes in the lungs.Our study provided new insights into SARS-CoV-2 pathogenesis and might facilitate the improvement of clinical guideline for virus containment and disease management.Xiao-Hong Yao Zhi-Cheng He Ting-Yuan Li Hua-Rong Zhang Yan Wang Huaming Mou Qiaonan Guo Shi-Cang Yu Yanqing Ding Xindong Liu Yi-Fang Ping Xiu-Wu Bian 2020Cell Research2020,30,6:35
2Microstructures and tensile properties of laser cladded AerMet100 steel coating on 300M steel显示文摘A layer of AerMet100 steel was coated on the surface of forged 300M steel using laser cladding technique.The chemical compositions, microstructures, hardness and tensile properties of this AerMet100/300M material were systematically investigated. Results show that the composition of the AerMet100 clad layer is macroscopically homogeneous, and a compositional transition zone with width of 150m is observed between the clad layer and heat affected zone. Microstructures in transition zone transform from the fine needle-like bainite in 300M steel to the lath tempered martensite in AerMet100 clad layer.Microstructures in heat affected zone also gradually change from the thick plate bainite and blocky retained austenite(unstable heat affected zone) to fine needle-like bainite and film-like austenite(stable heat affected zone) due to different thermal cycle processes. Thick plate bainite together with blocky retained austenite in unstable heat affected zone reduce the strength and ductility of AerMet100/300M material. However, the tensile specimens, consisting of clad layer and stable heat affected zone, show slightly inferior mechanical properties to 300M steel. Ductile fracture exists in AerMet100 clad layer while quasi-cleavage fracture occurs in the stable heat affected zone.Jian Liu Jia Li Xu Cheng Huaming Wang 2018Journal of Materials Science & Technology2018,34,4:11
3Water demand for ecosystem protection in rivers with hyper-concentrated sediment-laden flow显示文摘Sediment transport is one of the main concerns in a river system with hyper-concentrated flows. Therefore, the water use for sediment transport must be considered in study on the water demand for river ecosystem. The conventional methods for calculating the Minimum Water Demand for River Ecosystem (MWDRE) are not appropriate for rivers with high sediment concentration. This paper studied the MWDRE in wet season, dry season and the whole year under different water-and-sediment conditions in the Lower Yellow River, which is regarded as a typical river with sediment-laden flows. The characteristics of MWDRE in the river are analyzed. Firstly, the water demand for sediment transport (WDST) is much larger than the demands for other riverine functions, the WDST accounts for the absolute majority of the MWDRE. Secondly, in wet season when the WDST is satisfied, not only most of the annual incoming sediment can be transported downstream, but also the water demands for other river functions can be satisfied automatically, so that the MWDRE in wet season is identical to the WDST. Thirdly, in dry season, when the WDST is satisfied, the water demands for other river functions can also be satisfied, but the low sediment transport efficiency results in significant waste of water resources. According to these characteristics and aiming at decreasing sediment deposition in the riverbed and improving the utilization efficiency of water resources, hydrological engineering works can be used to regulate or control flow and sediment so that the sediment incoming in dry season can be accumulated and be transported downstream intensively and thus efficiently in wet season.LUO Huaming, LI Tianhong, NI Jinren & WANG Yudong Department of Environmental Engineering, Peking University, Beijing 100871, China The Key Laboratory of Water and Sediment Sciences, Ministry of Education, Beijing 100871, China 2004Science China(Technological Sciences)2004,47,z1:8
4Structural Characteristics and Formation Mechanism in the Micangshan Foreland,South China显示文摘躺在 Dabashan, Longmenshan 和 Qinling 山的连接, Micangshan Orogenic 带结合了盆是双结构和背戳有很少水平排水量,小戳差错和连续沉积盖子的三角形的带。根据 3D 地震数据,并且通过沉积、结构的研究, Micangshan 低岬能被划分成五条潜水艇带,它从北方到向南:地下室推进的、正面的戳,低岬 depression-back-thrust 三角,低岬褶层带或背斜带,和 Tongjiang 消沉。沿着到东方的从西方的罢工的方向, Micangshan 的弓形的结构的带能被划分成西方,中间和东方片断。在在 Qinling 和 Yangtze 盘子之间的碰撞期间, Micangshan Orogenic 带受到三个僵硬岩层的相互作用:Bikou, Foping,和 Fenghuangshan (又名 Ziyang ) 岩层。僵硬岩层的碰撞进程控制了 Micangshan 低岬的结构的开发,它是:(a) 在形成结构的更早的基础的 Micangshan-Hannan 和 Bikou 岩层之间的以前的碰撞;并且(b) 形成结构的带的主要身体的以后的碰撞。Micangshan Orogenic 带的形成过程能被划分成四个阶段:(1 ) 在 Indosinian 运动的早阶段, Micangshan-Hannan 僵硬岩层被连接到 Qinling 板由顺时针方向向 Qinling 板的 Yangtze 板的 subduction;(2 ) 自从晚三叠纪, Tongnanba 和 Jiulongshan 背斜的更早的基础和相应向斜被压缩从 Bikou, Foping 和 Micangshan-Hannan 的不同方向形成岩层;(3 ) 在喜玛拉雅的运动的早阶段, Micangshan-Hannan 岩层形成了 Micangshan 越过水坝落下的水岩山病房低岬盆和压缩压力主要沿着两它的胁腹被集中,而 Micangshan-Hannan 岩层挤了进 Qinling Orogenic,与力量系上带子;(4 ) 在喜玛拉雅的运动的迟了的阶段, Qinling 板的主要碰撞做了岩层的旧地下室岩石快速高举,形成 Micangshan Orogenic 带。Micangshan 低岬弓形的结构由于岩层的非同质被形成运动。XU Huaming LIU Shu QU Guosheng LI Yanfeng SUN Gang LIU Kang 2009Acta Geologica Sinica(English Edition)2009,83,1:8
5Hexagonal boron nitride adsorbent: Synthesis, performance tailoring and applications显示文摘Hexagonal boron nitride(h-BN),with unique structural and properties,has shown enormous potentitoward variety of possible applications.By virtue of partially-ionic character of BN chemical bonds anusually large specific surface area,h-BN-related nanostructures exhibit appealing adsorption propertiewhich can be widely applied for separation and purification towards energy and environment treatmenIn this review,recent progress in designing h-BN micro,nano-structure,controlled synthesis,performancoptimizing as well as energy and environment-related adsorption applications are summarized.Strategieto tailor the h-BN can be classified as morphology control,element doping,defect control and surfacmodification,focusing on how to optimize the adsorption performance.In order to insight the intrinsimechanism of tuning strategies for property optimization,the significant adsorption applications of h-Btowards hydrogen storage,CO2 capture,pollutants removal from water and adsorption desulfurization arpresented.Jun Xiong Jun Di Wenshuai Zhu Huaming Li 2020Journal of Energy Chemistry2020,29,1:7
6Catalytic oxidative desulfurization of fuels in acidic deep eutectic solvents with [(C_6H_(13))_3P(C_(14)H_(29))]_3PMo_(12)O_(40) as a catalyst显示文摘Deep eutectic solvents(DESs) are a new class of green solvents analogous to ionic liquids due to their biodegradable capacity and low cost. However, the direct extractive desulfurization of diesel oil by DESs cannot meet the government's standard. In this work, amphiphilic polyoxometalates were synthesized and characterized by FT-IR and mass spectrometry.The oxidative desulfurization results showed that benzothiophene(BT) could be completely removed by employing a [(C_6H_(13))_3P(C_(14)H_(29))]_3PMo_(12)O_(40), DES(ChCl/2 Ac) and H_2O_2 system. It was also found that the organic cation of catalysts played a positive role in oxidative desulfurization. The reaction conditions, such as reaction temperature and time, the amount of catalyst and DES and H_2O_2/S(O/S) molar ratio, were optimized. Different sulfides were tested to determine the desulfurization selectivity of the optimal reaction system, and it was found that 97.2% of dibenzothiophene(DBT) could be removed followed by 80.7% of 4-MDBT and 76.0% of 4,6-DMDBT. After reaction, the IR spectra showed that the catalyst [(C_6H_(13))_3P(C_(14)H_(29))]_3PMo_(12)O_(40) was stable during the reaction process and the oxidative product was dibenzothiophene sulfone(DBTO_2). Furthermore, the catalyst can be regenerated and recycled for four runs with little loss of activity.Wei Jiang Hao Jia Zhanglong Zheng Linhua Zhu Lei Dong Wei Liu Wenshuai Zhu Huaming Li 2018Petroleum Science2018,15,4:6
7Polyoxometalate-based silica-supported ionic liquids for heterogeneous oxidative desulfurization in fuels显示文摘With the aim of deep desulfurization, silica-supported polyoxometalate-based ionic liquids were successfully prepared by a one-pot hydrothermal process and employed in heterogeneous oxidative desulfurization of various sulfur compounds. The compositions and structures of the hybrid samples were characterized by various methods such as FT-IR, XPS, Raman,UV–Vis, wide-angle XRD and N_2 adsorption–desorption. The experimental results indicated that the hybrid materials presented a high dispersion of tungsten species and excellent catalytic activity for the removal of 4,6-dimethyldibenzothiophene without any organic solvent as extractant, and the sulfur removal could reach 100.0% under mild conditions.The catalytic performance on various substrates was also investigated in detail. After cycling seven cycles, the sulfur removal of the heterogeneous system still reached 93.0%. The GC-MS analysis results demonstrated that the sulfur compound was first adsorbed by the catalyst and subsequently oxidized to its corresponding sulfone.Ming Zhang Miao Wang Jiapeng Yang Hongping Li Jiaqi Liu Xiao Chen Wenshuai Zhu Huaming Li 2018Petroleum Science2018,15,4:5
8A research on the contact stress of roller bearing based on crowning analysis显示文摘According to elastic contact theory,contact model between roller and race is established.Compared with the Hertz results,the results are proved,based on which contact stress distribution of different crowning and initial contact length is given,then the appropriate value is derived.On the basis,inertia force and different radial force is given into consideration.Via analysis,it concludes that under balanced pure radial load condition the largest contact stress between roller and race increases along with crowning value increasing.With the same crowning value,the largest contact stress between roller and race decreases in the first and increases at the end along with initial contact length increasing.Contact stress between roller and outer race increases along with revolution speed increasing.XU Juan NIU Qingbo QI Huaming ZHANG Li GUAN Meng 2012Computer Aided Drafting,Design and Manufacturing2012,22,2:5
9Facile microwave-assisted ionic liquid synthesis of sphere-like BiOBr hollow and porous nanostructures with enhanced photocatalytic performance显示文摘In this work, two kinds of self-assembled hierarchical BiOBr microcrystals were rapidly synthesized through a simple microwave-assisted route in the presence of reactable ionic liquid 1-hexadecyl-3-methylimidazolium bromide([C_(16)mim]Br). These porous and hollow BiOBr microspheres were obtained via a facile solvothermal method with or without polyvinyl pyrrolidone(PVP), respectively. During the synthetic process, ionic liquid [C_(16)mim]Br played as solvent, reactant and template at the same time. Moreover, the BiOBr hollow and porous microspheres exhibited outstanding photocatalytic activities for the degradation of rhodamine B(RhB) under visible light irradiation. A possible photocatalytic mechanism was also discussed in detail. It can be assumed that the higher photocatalytic activities of BiOBr porous microspheres materials could be ascribed to the novel structure, larger specific surface area, narrower band gap structure and smaller particle size.Zhigang Chen Jie Zeng Jun Di Dexiang Zhao Mengxia Ji Jiexiang Xia Huaming Li 2017Green Energy & Environment2017,2,2:5
10Construction of NH2-MIL-125(Ti)/Bi2WO6 composites with accelerated charge separation for degradation of organic contaminants under visible light irradiation显示文摘Photocatalysis is considered as an ideal strategy for water pollution treatment.However,it remains challenging to design a highly efficient photo-catalytic system through regulating the charge flow via a precise approach.In this work,a novel NH2-MIL-125(Ti)/Bi2WO6 composite was constructed via self-assembly growing Bi2WO6 nanosheets on NH2-MIL-125(Ti)material.The characterization results demonstrated that NH2-MIL-125(Ti)was successfully incorporated into Bi2WO6 and the photoexcited carriers could be efficiently separated and transferred between the two components.NH2-MIL-125(Ti)/Bi2WO6 composites displayed enhanced photocatalytic activity for the removal of rhodamine B(RhB)and tetracycline(TC)under visible light irradiation,and the optimal weight ratio of NH2-MIL-125(Ti)was determined to be 7 wt%.The introduction of NH2-MIL-125(Ti)into Bi2WO6 could raise the absorption of visible light,accelerate the separation and transfer of charge carriers,and boost photocatalytic activity.This research presents a wide range of possibilities for the further development of novel composites in the field of environment purification.Sheng Yin Yong Chen Ming Li Qingsong Hu Yi Ding Yifan Shao Jun Di Jiexiang Xia Huaming Li 2020Green Energy & Environment2020,5,2:5
11The Effect of Liposome Encapsulated Daunorubicin on Rabbit Eyes after Extracapsular Lens Extraction显示文摘Purpose: To investigate the effect of liposome encapsulated daunorubicin (DNR) on rabbit eyes when it was used in prevention of posterior capsule opacification (PCO). Methods: The liposome encapsulated DNR was prepared by modified freeze-thawing method. Each eye was injected with 0. 1 ml liposomes (0. 2 mg/ml and 20 μg/ml DNR) into the capsular bag during the extracapsular lens extraction (ECLE) in 10 rabbit eyes respectively. The phosphate buffer solution (PBS) was injected as control. Besides biomicroscope observation and histology examination of all eyes, the concentration of DNR in aqueous humor was also determined by high performance liquid chromatography (HPLC).Results: The morphology of liposome encapsulated DNR were similar to the blank liposome with round or ellipse shape. The encapsulated effeciency of liposome encapsulated DNR was 45. 1%. The inflammatory response was much more severe both in 0. 2 mg/ml and 20μg/ml DNR group than the control after liposome injection. All eyes in DNR groupMingxing Wu, Huaming Li, Shaozhen Li, Junwen ZengZhongshan Ophthalmic Center, Sun Yet-sen University of Medical Sciences, Guangzhou 510060, China 2000眼科学报2000,16,3:4
12Boosting photocatalytic degradation of RhB via interfacial electronic effects between Fe-based ionic liquid and g-C_3N_4显示文摘The Fe-based ionic liquid doped g-C_3N_4(Fee CN) photocatalyst was firstly prepared base on ultrathin g-C_3N_4 obtained by multiple calcination method with a metal-based reactive ionic liquid [Omim]FeCl_4 for the degradation of Rhodamine B(RhB). Experimental results revealed that Fe3+species were doped into the framework of g-C_3N_4. The effect of the amount of Fe-doping on the catalytic activity was performed. The result showed that the Fee CN could effectively degrade RhB under the condition of visible light irradiation. The photocurrent analysis showed that the incorporation of Fe^(3+)into g-C_3N_4 material could accelerate the separation of the photogenerated carriers significantly.At the same time, the reactive species generated during the photodegradation process were tested by radicals trapping experiments and electron spin resonance(ESR). It was proposed that the synergistic effect of■ and ·OH contributed to degrade RhB efficiently.Xiaowei Li Bin Wang Yuhong Huang Jun Di Jiexiang Xia Wenshuai Zhu Huaming Li 2019Green Energy & Environment2019,4,2:4
13Hollow cobalt oxide nanoparticles embedded in nitrogen-doped carbon nanosheets as an efficient bifunctional catalyst for Zn–air battery显示文摘Rational design of low-cost, highly electrocatalytic activity, and stable bifunctional electrocatalysts for oxygen reduction reaction(ORR) and oxygen evolution reaction(OER) has been a great significant for metal–air batteries. Herein, an efficient bifunctional electrocatalyst based on hollow cobalt oxide nanoparticles embedded in nitrogen-doped carbon nanosheets(Co/N-Pg) is fabricated for Zn–air batteries. A lowcost biomass peach gum, consisting of carbon, oxygen, and hydrogen without other heteroatoms, was used as carbon source to form carbon matrix hosting hollow cobalt oxide nanoparticles. Meanwhile, the melamine was applied as nitrogen source and template precursor, which can convert to carbon-based template graphitic carbon nitride by polycondensation process. Owing to the unique structure and synergistic effect between hollow cobalt oxide nanoparticles and Co-N-C species, the proposal Co/N-Pg catalyst displays not only prominent bifunctional electrocatalytic activities for ORR and OER, but also excellent durability. Remarkably, the assembled Zn–air battery with Co/N-Pg air electrode exhibited a low discharge-charge voltage gap(0.81 V at 50 mA cm^-2) and high peak power density(119 mW cm^-2) with long-term cycling stability. This work presents an effective approach for engineering transition metal oxides and nitrogen modified carbon nanosheets to boost the performance of bifunctional electrocatalysts for Zn–air battery.Yuhui Tian Li Xu Jian Bao Junchao Qian Huaneng Su Huaming Li Haidong Gu Cheng Yan Henan Li 2019Journal of Energy Chemistry2019,28,6:4
14Amorphous TiO_2-supported Keggin-type ionic liquid catalyst catalytic oxidation of dibenzothiophene in diesel显示文摘Supported ionic liquid(IL) catalysts [C_nmim]_3PMo_(12)O_(40)/Am TiO_2(amorphous TiO_2) were synthesized through a one-step method for extraction coupled catalytic oxidative desulfurization(ECODS) system. Characterizations such as FTIR, DRS,wide-angle XRD, N_2 adsorption–desorption and XPS were applied to analyze the morphology and Keggin structure of the catalysts. In ECODS with hydrogen peroxide as the oxidant, it was found that ILs with longer alkyl chains in the cationic moiety had a better effect on the removal of dibenzothiophene. The desulfurization could reach 100% under optimal conditions, and GC–MS analysis was employed to detect the oxidized product after the reaction. Factors affecting the desulfurization efficiencies were discussed, and a possible mechanism was proposed. In addition, cyclic experiments were also conducted to investigate the recyclability of the supported catalyst. The catalytic activity of [C_(16)mim]_3 PMo_(12)O_(40)/Am TiO_2 only dropped from 100% to 92.9% after ten cycles, demonstrating the good recycling performance of the catalyst and its potential industrial application.Zhendong Yu Donghui Wang Suhang Xun Minqiang He Ruliang Ma Wei Jiang Hongping Li Wenshuai Zhu Huaming Li 2018Petroleum Science2018,15,4:3
15Hexagonal boron nitride:A metal-free catalyst for deep oxidative desulfurization of fuel oils显示文摘Oxidative desulfurization(ODS)has been proved to be an efficient strategy for the production of clean fuel oil.Numerous metal-based materials have been employed as excellent ODS catalysts,but being hindered by their high-cost and potential secondary pollution.In this work,we employed graphene analogous hexagonal boron nitride(h-BN)as a metal-free catalyst for ODS with hydrogen peroxide(H2O2)as the oxidant.The h-BN catalyst was characterized and proved to be a few-layered structure with relatively high specific surface areas.The h-BN catalyst showed a 99.4%of sulfur removal in fuel oil under the optimized reaction conditions.Besides,the h-BN can be recycled for 8 times without significant decrease in the catalytic performance.Detailed mechanism analysis found that it is the boron radicals in h-BN activated H2O2 to generate·OH species,which can readily oxidize sulfides to corresponding sulfones for separation.This work would provide another choice in choosing metal-free catalysts for ODS.Peiwen Wu Linjie Lu Jing He Linlin Chen Yanhong Chao Minqiang He Fengxia Zhu Xiaozhong Chu Huaming Li Wenshuai Zhu 2020Green Energy & Environment2020,5,2:3
16Construction of 2D/2D Z-scheme MnO_(2-x)/g-C_(3)N_(4) photocatalyst for efficient nitrogen fixation to ammonia显示文摘Reducing nitrogen to ammonia with solar energy has become a wide concern when it comes to photocatalysis research.It is considered to be one of the more promising alternate options for the conventional Haber-Bosch cycle.Herein,2D g-C_(3)N_(4)composites with modifying ultrathin sheet MnO_(2-x)were prepared and used as nitrogen fixation photocatalyst.With the assistance of the nature of MnO_(2-x),the generation rate of NH_(3)reached 225 mmol g^(-1)h^(-1),which is more than twice over the rate of pristine 2D g-C_(3)N_(4)(107 mmol g^(-1)h^(-1)).The presence of ultrathin sheet MnO_(2-x)shortens the gap of the carriers to the surface of photocatalyst.Thus the speed of electron transfer gets increased.Besides,the construction of Z-scheme heterojunction boosts the separation and migration of photogenerated carriers.As a result,the nitrogen reduction reaction(NRR)performance gets enhanced.The work may provide an example of promoting the NRR performance of non-metallic compound.Limin Yu Zhao Mo Xianglin Zhu Jiujun Deng Fan Xu Yanhua Song Yuanbin She Huaming Li Hui Xu 2021Green Energy & Environment2021,6,4:3
17Insights into the efficient charge separation over Nb_(2)O_(5)/2D-C_(3)N_(4) heterostructure for exceptional visible-light driven H_(2) evolution显示文摘Two-dimensional carbon nitride(2 D-C_(3) N_(4))nanosheets are promising materials in photocatalytic water splitting,but still suffer from easy agglomeration and fast photogene rated electron-hole pairs recombination.To tackle this issue,herein,a hierarchical Nb_(2) O_(5)/2 D-C_(3) N_(4) heterostructure is precisely constructed and the built-in electric field between Nb_(2)O_(5) and 2 D-C_(3) N_(4) can provide the driving force to separate/transfer the charge carriers efficiently.Moreover,the strongly Lewis acidic Nb_(2)O_(5) can adsorb TEOA molecules on its surface at locally high concentrations to facilitate the oxidation reaction kinetics under irradiation,resulting in efficient photogene rated electrons-holes separation and exceptional photocatalytic hydrogen evolution.As expected,the champion Nb_(2)O_(5)/2 D-C_(3)N_(4) heterostructure achieves an exceptional H2 evolution rate of 31.6 mmol g^(-1) h^(-1),which is 213.6 times and 4.3 times higher than that of pristine Nb_(2)O_(5) and2 D-C_(3)N_(4),respectively.Moreover,the champion heterostructure possesses a high apparent quantum efficiency(AQE)of 45.08%atλ=405 nm and superior cycling stability.Furthermore,a possible photocatalytic mechanism of the energy band alignment at the hetero-interface is proposed based on the systematical characterizations accompanied by density functional theory(DFT)calculations.This work paves the way for the precise construction of a high-quality heterostructured photocatalyst with efficient charge separation to boost hydrogen production.Jia Yan Ting Wang Siyao Qiu Zhilong Song Wangqin Zhu Xianhu Liu Jiabiao Lian Chenghua Sun Huaming Li 2022Journal of Energy Chemistry2022,31,2:3
18Surface physical properties and its effects on the wetting behaviors of respirable coal mine dust显示文摘Qingzhao Li Baiquan Lin Shuai Zhao Huaming Dai 2013Powder Technology2013,,:3
19Understanding divergent domestication traits from the whole-genome sequencing of swamp-and river-buffalo populations显示文摘Domesticated buffaloes have been integral to rice-paddy agro-ecosystems formillennia,yet relatively little is known about the buffalo genomics.Here,we sequenced and assembled reference genomes for both swamp and river buffaloes and we re-sequenced 230 individuals(132 swamp buffaloes and 98 river buffaloes)sampled from across Asia and Europe.Beyond the many actionable insights that our study revealed about the domestication,basic physiology and breeding of buffalo,we made the striking discovery that the divergent domestication traits between swamp and river buffaloes can be explained with recent selections of genes on social behavior,digestion metabolism,strengths and milk production.Xier Luo Yu Zhou Bing Zhang Yi Zhang Xiaobo Wang Tong Feng Zhipeng Li Kuiqing Cui Zhiqiang Wang Chan Luo Hui Li Yanfei Deng Fenghua Lu Jianlin Han Yongwang Miao Huaming Mao Xiaoyan Yi Cheng Ai Shigang Wu Alun Li Zhichao Wu Zijun Zhuo Do Da Giang Bikash Mitra Mohammad Farhad Vahidi Shahid Mansoor Sahar Ahmed Al-Bayatti Eka Meutia Sari Neena Amatya Gorkhali Sigit Prastowo Laiba Shafique Guoyou Ye Qian Qian Baoshan Chen Deshun Shi Jue Ruan Qingyou Liu 2020National Science Review2020,7,3:3
20A comparative study of the extractive desulfurization mechanism by Cu(Ⅱ)and Zn-based imidazolium ionic liquids显示文摘A comparative study of the extractive desulfurization(EDS) mechanism by Cu(Ⅱ) and Zn-based ILs([C_4mim]_2[MCl_4], M ? Cu(Ⅱ) or Zn)has been performed. It is found that the p–p interaction and C-H/p interaction play important roles in EDS for both Cu(Ⅱ) and Zn-based ILs,which is different from Al, Fe-based ILs. In the gas phase models, the interaction energy between Zn-based ILs and dibenzothiophene(DBT) is stronger than the interaction energy of Cu(Ⅱ)-based ILs. In order to consider the solvent effect, a generic ionic liquid of solvation model has been implemented, which is few considered in the previous calculations of EDS. It is interesting to find that the gap of interaction energies between Cu(Ⅱ), Zn-based ILs and DBT are reduced when the solvent effect is considered. In addition, by combined discussion of currently theoretical and experimental evidences for metal-based ILs with different compositions, we firstly propose that the EDS performance should be influenced by the balance of the contribution of cation, metal-based anion, metal chlorides and the viscosity.Hongping Li Beibei Zhang Wei Jiang Wenshuai Zhu Ming Zhang Chao Wang Jingyu Pang Huaming Li 2019Green Energy & Environment2019,4,1:2
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