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1Discovery of Paleoproterozoic rapakivi granite on the northern margin of the Yangtze block and its geological significance显示文摘The Huashanguan rapakivi pluton in Zhongxiang,Hubei Province,China,is the first discovered Proterozoic rapakivi pluton in the Yangtze block.Based on field and petrographical observations,a typical rapakivi texture was found in the northern portion of the Huashanguan granitic pluton.Almost all the K-feldspar phenocrysts were round to oval in shape and most had plagioclase coatings known as rapakivi phenocrysts.Alkali feldspars and quartz had two or more generations.Petrochemically,the Huashanguan rapakivi granites were characterized as having high values of Si,K,Fe,Th,U,La,Ga,Ce,Sm and LREE,low values of Ca,Mg,Sr,Nb,Y and HREE,and a negative Eu anomaly.These geochemical characteristics of the Huashanguan granites were concordant with typical rapakivi granites,and had an affinity to A-type granites.LA-ICP-MS U-Pb zircon dating also was conducted.The dating yielded a 207Pb/206Pb weighted mean age of 1851±18 Ma (MSWD =1.2),which represents the age of the pluton emplacement.The age of 803±170 Ma at the lower intercept in the concordia diagram corresponds to the age of a later deformation event which affected the pluton,and suggests that the Huashanguan pluton was influenced by Neoproterozoic thermo-tectonic events after its formation.The discovery of Paleoproterozoic Huashanguan rapakivi granites indicates continental rifting or a post-orogenic extensional event that took place in the Paleoproterozoic in the Yangtze block.These events may be related to the breakup of the Paleoproterozoic Columbia supercontinent.ZHANG LiJuan MA ChangQian WANG LianXun SHE ZhenBing WANG ShiMing 2011Chinese Science Bulletin2011,56,3:37
2Genesis of Highly Fractionated I-Type Granites from Fengshun Complex:Implications to Tectonic Evolutions of South China显示文摘The South China Block is characterized by the large-scale emplacement of felsic magmas and giant ore deposits during the Yanshanian. We present zircon Hf isotopic compositions, whole-rock major and trace element compositions of the Fengshun complex, located in eastern Guangdong Province, South China. The Fengshun complex is a multi-stage magmatic intrusion. It is composed of two main units, i.e., the Mantoushan(MTS) syeno-monzogranites, alkali feldspar granites and the Hulutian(HLT) alkali feldspar granites. LA-ICPMS zircon dating shows that the complex emplaced in 166–161 and 139±2 Ma, respectively. Geochemically, the MTS granites show relatively various geochemical compositions with low REE contents(87.76×10^(-6)–249.71×10^(-6)), Rb/Sr ratios(1.19–58.93), pronounced Eu negative anomaly(0.01–0.37) and low Nb/Ta ratios(2.40–6.82). In contrast, the HLT granites exhibit relatively stable geochemical characteristics with high REE contents(147.35×10^(-6)– 282.17×10^(-6)), Rb/Sr ratios(2.05–10.30) and relatively high Nb/Ta ratios(4.45–13.00). The isotopic data of the MTS granites display relatively enriched values, with I_(Sr) varying from 0.708 2 to 0.709 7, εNd(t) from-7.8 to-6.9 and εHf(t) from-7.4 to-3.2, in comparison with those of the HLT which are I_(Sr)=0.703 05–0.704 77, εNd(t)=-5–-3.4 and εHf(t)=-0.7–1.8). The two-stage model ages of the MTS granites(T_(2DM)(Nd)=1.51–1.59 Ga and T_(2DM)(Hf)=1.26–1.48 Ga) are also higher than those of the HLT granites(T_(2DM)(Nd)=1.21–1.34 Ga and T_(2DM)(Hf)=0.96–1.10 Ga). Thus the MTS and HLT granites might originate from different sources. The former is more likely derived from partial melting of Meso-Proterozoic basement triggered by upwelling of asthenosphere and/or underplate of the basaltic magma and then extensive fractional crystallisation, similar to the genesis of Early Yanshanian granitoids of the EW-trending tectono-magmatism belt in the Nanling range. In comparison, the latter might have involved with asthenosphere component, similar to the Early Cretaceous granitoids of NE-NNE-trending granitoid-volcanic belt in coastal region, southeastern China. We propose that the MTS granites were mainly formed in Paleo-Tethyan post-orogenic extensional tectonic setting whereas the HLT granites were formed in the back-arc extensional tectonic setting. The period at 139 Ma represents the initial time of roll-back of the paleo-Pacific Plate in SE-trending.Zuomin Zhou Changqian Ma Caifu Xie Lianxun Wang Yuanyuan Liu Wei Liu 2016Journal of Earth Science2016,27,3:11
3Petrogenesis and Tectonic Implications of Peralkaline A-Type Granites and Syenites from the Suizhou-Zaoyang Region,Central China显示文摘In this study, we present systematic petrological, geochemical, LA-ICP-MS zircon U-Pb ages and Nd isotopic data for the A-type granites and syenites from Suizhou-Zaoyang region. The results show that the peralkaline A-type granites and syenites were episodically emplaced in Suizhou-Zaoyang region between 450±3 and 441±7 Ma which corresponds to Late Ordovician and Early Silurian periods, respectively. Petrologically, the syenite-peralkaline granite association comprises of nepheline normative-syenite and alkaline granite in Guanzishan and quartz normative syenite and alkaline granite in Huangyangshan. The syenite-granite associations are ferroan to alkali in composition. They depict characteristics of typical OIB(oceanic island basalts) derived A-type granites in multi-elements primitive normalized diagram and Yb/Ta vs. Y/Nb as well as Ce/Nb vs. Y/Nb binary plots. Significant depletion in Ba, Sr, P, Ti and Eu indicates fractionation of feldspars, biotite, amphiboles and Ti-rich augite. The values of ?Nd(t) in Guanzishan nepheline syenite and alkaline granite are +1.81 and +2.26, respectively and the calculated two-stage model age for these rocks are 1 040 and 1 003 Ma, respectively. On the other hand, the Huangyangshan alkaline granite has ?Nd(t) values ranging from +2.61 to +3.46 and a relatively younger two-stage Nd model age values ranging from 906 to 975 Ma, respectively. Based on these data, we inferred that the Guanzishan nepheline syenites and granites were formed from fractional crystallization of OIB-like basic magmas derived from upwelling of metasomatized lithospheric mantle. The Huangyangshan quartz syenite and granite on the other hand, were formed from similar magmas through fractional crystallization with low input from the ancient crustal rocks. Typically, the rocks exhibit A1-type granite affinity and classified as within plate granites associated with the Ordovician crustal extension and the Silurian rifting.Hafizullah Abba Ahmed Changqian Ma Lianxun Wang Ladislav A.Palinkas Musa Bala Girei Yuxiang Zhu Mukhtar Habib 2018Journal of Earth Science2018,29,5:5
4Geochronology,Geochemistry and Sr-Nd-Pb Isotopic Study of the Wulong Flower-Like Glomerophyric Diorite Porphyry(Central China):Implications for Tectonic Evolution of Eastern Qinling显示文摘The Wulong diorite porphyry displays a very unusual flower-like glomerophyric texture and is thus well-known as a gemstone type of 'Luoyang peony stone' for non-geologists. Hereby, we present a comprehensive study in terms of petrography, zircon U-Pb geochronology, geochemistry and Sr-Nd-Pb isotope. The rock exposed as small-scale dykes in the field, intruding in the Archean migmatized biotiteplagioclase genesis at the southern margin of the North China Craton. It exhibits typical porphyrite texture with plagioclase and amphibole as dominant and subdominant phenocrysts, respectively. The diorite porphyry rocks contain 51 wt.%–59 wt.% SiO_2, belonging to medium-K calc-alkaline rock series. They are characterized by enrichment of large ion lithophile elements(LILEs, e.g., Ba) and depletion of high field-strength elements(HFSEs, e.g., Nb, Ta, Zr and Hf), resembling island arc magmatic rocks. They show high initial Sr isotopic ratios(0.710 7–0.715 8), low ε_(Nd)(t) values(-9.9 to-13.3) and variable initial Pb isotopic ratios(^(206)Pb/^(204)Pb vary from 17.3 to 19.3), similar to the coeval intermediate and mafic magmatic rocks of adjacent region. These geochemical features indicate that the Wulong diorite porphyry is likely to originate from an enriched mantle with contamination of crustal materials. Zircon U-Pb dating results reveal a magma crystallization age of 480±3 Ma, consistent with the summit of the magmatic events of the Qinling orogenic belt and reflecting the northernmost Paleozoic magmatic activity of the belt. This may indicate the influence of northward subduction of Paleotethyan oceanic slab can extend a distance of ca. 200 km to the north and reach Luoyang-Songshan region in the East Qinling Orogen.Yuxiang Zhu Lianxun Wang Changqian Ma Chao Zhang Ke Wang 2018Journal of Earth Science2018,29,5:2
5Synthesis and properties of polyimides from isomeric bis (dicarboxylpenylthio) diphenyl sulfone dianhydrides显示文摘Yan Jingling Wang Zhen Gao Lianxun Ding Mengxian 2005Polymer2005,46,:1
6Polyirnides derived from 3, 3'-bis (N arninophthalimide) 显示文摘Yan Jingling Wang Zhen Gao Lianxun Ding Mengxian 2006Macromolecules2006,39,:1
7Coronas around Olivine in the Miaowan Olivine Norite, Yangtze Craton, South China显示文摘Coronitic microstructures have been used to interpret the late-stage solidification history of igneous rocks and to constrain the corresponding chemical and/or physical changes. Coronas with three shells were also recognized in the Miaowan olivine norite, Yangtze Craton, South China. In our study, orthopyroxene intergrowth with vermicular magnetite in the inner shell is in optical continuity with magnetite-free orthopyroxene in the middle shell. In the outer shell of brown amphibole remaining magnetite-free orthopyroxene inclusions sporadically occur. Meanwhile Mg# values of orthopyroxene(76–80) in the inner and middle shells are basically consistent with olivine(78–81). In this paper, we propose a multi-stage genetic model for the formation of coronas in the Miaowan olivine norite. In the first stage, the magnetite-free orthopyroxene shell formed through reaction between primocrystal olivine with the residual Si-rich melt at 990–1 053 ℃ and 6.2–6.5 kbar. In the second stage, the orthopyroxene-magnetite symplectite shell formed when primocrystal olivine reacted with the late-stage residual Fe-rich melt promoted by high oxygen fugacity condition at 927–1 035 ℃ and 6.0–6.5 kbar. In the third stage, the brown amphibole shell formed as the presence of residual hydrous melt and replaced the middle shell at 821–900 ℃ and 5.5–6.0 kbar.Shuhua Fan Zhaochong Zhang Changqian Ma Qiuhong Xie Lianxun Wang Yanjie Li Yuzhe Zhang 2019Journal of Earth Science2019,30,5:0
8Experiments on the Saturation of Fluorite in Magmatic Systems: Implications for Maximum F Concentration and Fluorine-Cation Bonding in Silicate Melt显示文摘The effects of melt composition,temperature and pressure on the solubility of fluorite(CaF2),i.e.,fluorine concentration in silicate melts in equilibrium with fluorite,are summarized in this paper.The authors present a statistic study based on experimental data in literature and propose a predictive model to estimate F concentration in melt at the saturation of fluorite(CFin melt^Fl-sat).The modeling indicates that the compositional effect of melt cations on the variation in can be expressed quantitatively as one parameter FSI(fluorite saturation index):FSI=(3Al^NM+Fe^2++6Mg+Ca+1.5Na-K)/(Si+Ti+Al^NF+Fe^3+),in which all cations are in mole,and Al^NF and Al^NM are A1 as network-forming and network-modifying cations,respectively.The dependence of CFin melt^Fl-sat on FSI is regressed as:CFin melt^Fl-sat=1.130-2.014·exp(1000/T)+2.747·exp(P/T)+0.111·CmeltH2O+17.641·FSI,in which T is temperature in Kelvin,P is pressure in MPa,CmeltH2O is melt H2O content in wt.%,and CFin melt^Fl-sat is in wt.%(normalized to anhydrous basis).The reference dataset used to establish the expression for conditions within 540-1010℃,50-500 MPa,0-7 wt.%melt H2O content,0.4 to 1.7 for A/CNK,0.3 wt.%-7.0 wt.%for CFin melt^Fl-sat.The discrepancy of CFin melt^Fl-sat between calculated and measured values is less than±0.62 wt.%with a confidence interval of 95%.The expression of FSI and its effect on CFin melt^Fl-sat indicate that fluorine incorporation in silicate melts is largely controlled by bonding with network-modifying cations,favorably with Mg,Al^NM,Na,Ca and Fe^2+in a decreasing order.The proposed model for predicting CFin melt^Fl-sat is also supported by our new experiments saturated with magmatic fluorite performed at 100-200 MPa and 800-900℃.The modeling of magma fractional crystallization emphasizes that the saturation of fluorite is dependent on both the compositions of primary magmas and their initial F contents.Xiaoyan Li Chao Zhang Lianxun Wang Harald Behrens Francois Holtz 2020Journal of Earth Science2020,31,3:0
9NDI-induced Topological Conversion of Human Telomeric G-Quadruplexes from Hybrid-2 to Parallel Form显示文摘G-Quadruplexes(GQs),which are formed by G-rich DNA sequences in human telomeres,have become an attractive target for cancer treatment.The ligands to stabilize the conformation of human telomeric GQs in vivo are particularly important for structure-based ligand design and drug development targeting the noncanonical DNA structure.Here we report the conformational conversion of Tel26 induced by a naphthalene diimide(NDI)ligand in K^(+)buffer,even at cellular physiological temperature(37℃)and under mimetic cellular crowding conditions created by Ficoll 70.We provide an insight into the dynamic conversion from initial hybrid-2 GQ topology to final parallel GQ topology.These results are helpful for the design of ligands with GQ conformation regulation.HAO Xueyu LI Chunjie WANG Yu ZHANG Feng HOU Jingwei KANG Chunqing GAO Lianxun 2021Chemical Research in Chinese Universities2021,37,3:0
10Petrogenesis and Significance of the Jebel Dumbier Alkaline-Carbonatite Complex from North Margin of Nuba Mountains, Sudan显示文摘1 Introduction Scientific study of the geology and mineral resources in Sudan is rather limited.Jebel Dumbier is the first identified carbonatite-bearing alkaline complex in Sudanby El Sharkawi&El Raba’a in 1973.It is located in Northern Kordofan Province on the northeastern margin of the Nuba Mountains.The complex exposed asWANG Lianxun MA Changqian MUSA A.S. Mushaal ABDALLSAMED I.M. Mohammmed 2017Acta Geologica Sinica(English Edition)2017,91,S1:0
11An Unique Glomerophyric Diorite Porphyry from the Southern Margin of North China Craton:Geochronology,Geochemical and Quantitative Textural Analysis Constraints显示文摘1 Introduction The Wulong glomerophyric diorite porphyry has an extremely peculiar texture with plagioclase phenocrysts clustered as flower-like glomerocrysts(Figs.1a&b),which is never discovered elsewhere of the world.ZHU Yuxiang WANG Lianxun MA Changqian 2017Acta Geologica Sinica(English Edition)2017,91,S1:0
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