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1Experiment of the ^(40)Ar/^(39)Ar dating of diagenetic illite in gas reservoirs显示文摘40Ar/39Ar dating of diagenetic illite has been performed to investigate gas reservoirs in the Sulige Gas Field of the northern Ordos Basin. A series of technical challenges were confronted, including illite purification, Ar recoil loss, and separation of diagenetic illite from detrital illite. Mineral growth ages for diagenetic illite were obtained by this experiment, from which the age of gas emplacement was deduced to be later than 169 Ma.WANG Longzhang, DAI Tongmo & PENG Ping’an State Key Laboratory of Organic Geochemistry, Guangzhou Institute of Geochemistry, CAS, Guangzhou 510640, China Faculty of Resources, Chinese University of Geosciences, Wuhan 430074, China 2004Chinese Science Bulletin2004,49,S1:7
2Polymerase chain reaction of Au nanoparticle-bound primers显示文摘Polymerase chain reaction (PCR) is a useful technique for in vitro amplification of a DNA fragment. In this paper, a PCR procedure using Au nanoparticle (AuNP) -bound primers was systemically studied. The 5′-SH- (CH2)6-modified primers were covalently attached to the AuNP surface via Au-S bonds, and plasmid pBluescript SK was used as a template. The effects of the concentration of AuNP-bound primers, annealing temperature and PCR cy-cles were evaluated, respectively. The results indicate that PCR can proceed successfully under optimized condition, with either forward or reverse primers bound to the AuNP surface or with both the two primers bound to the AuNP surface. Development of PCR procedure based on AuNPs not only makes the isolation of PCR products very convenient, but also provides novel methods to prepare AuNP-bound ssDNA and nanostructured material.SHEN Hebai HU Min YANG Zhongnan WANG Chen ZHU Longzhang 2005Chinese Science Bulletin2005,50,18:4
3A Thermal Event in the Ordos Basin:Insights from Illite ^40Ar-^39Ar Dating with Regression Analysis显示文摘Four samples from a Permian reservoir in the Ordos Basin of North China were separated into twelve fractions in grain sizes of <0.5, 0.5–1 and 1–2 μm. Using the ^(40)Ar-^(39)Ar step-heating method, all of the fractions essentially yielded plateau ages ranging from 172.5 to 217.1 Ma. These scattered plateau ages might not have been obtained from pure diagenetic illites but from mixed clay minerals, although the samples were disaggregated using a gentle freeze-thaw cycle to free them of non-clay minerals. A regional thermal event, as suggested by several proxies, led to intensive illitization as a distinct diagenetic process when the Yanshanian Movement triggered magmatism around the entire North China Block during the Jurassic to Cretaceous. Thermal illites formed during a short time period, whereas detrital illites came from various sources. The scattered plateau ages could have resulted from mixed degassing of thermal and detrital illites. Within one sample, the plateau ages decrease with the diminution of grain sizes, but it is difficult to extrapolate to the detrital-illite-free ages. Because the plateau age is a mixture of ages for thermal and detrital illites, this regression analysis studies the dependence of the plateau ages on the synthetic values of contents and ages of detrital illites instead of on the grain sizes. Comparing the samples to one another, the plateau ages show the same trend among the different grain sizes. Weighted by the contents and ages of detrital illites, linear regression analysis revealed the relationship between the plateau ages and the relative weight proportions. Based on iterated calculations, a thermal event age and a set of weight proportions were derived. The regressed thermal event age is 163.3±1.6 Ma, which coincides with regional thermal activities and links to gas accumulation.Longzhang Wang Liyun Wang Ping'an Peng Tongmo Dai Dayong Liu 2018Journal of Earth Science2018,29,3:3
4Silencing of pkm2 increases the efficacy of docetaxel in human lung cancer xenografts in mice显示文摘Hua‐shanShi DanLi JingZhang Yong‐shengWang LiYang Hai‐longZhang Xian‐huoWang BoMu WeiWang YuMa Fu‐chunGuo Yu‐quanWei 2010Cancer Science2010,,6:2
5Chitosan-coated magnetic nanoparticles as carriers of 5-Fluorouracil:Preparation,characterization and cytotoxicity studies显示文摘Longzhang Zhu Jingwei Ma Nengqin Jia 2009Colloids and Surfaces B:Biointerfaces2009,68,:1
6Electrochemical properties of ordered mesoporous carbon and its electroanalytical application for selective determination of dopamine显示文摘Nengqin Jia Zhiyong Wang Guofeng Yang Hebai Shen Longzhang Zhu 2006Electrochemistry Communications2006,,2:1
7Ginsenoside Rg1 modulation on thrombospondin‐1 and vascular endothelial growth factor expression in early renal fibrogenesis in unilateral obstruction显示文摘Xi‐ShengXie Heng‐ChuanLiu Feng‐PingWang Cheng‐LongZhang ChuanZuo YaoDeng Jun‐MingFan 2010Phytother Res2010,,11:1
8DRAWING PREDOMINANCE DIAGRAM OF M_1—M_2—x—y SYSTEM AND ITS APPLICATION显示文摘Discussions were made of the principle,method and computer program for drawing the pre-dominance diagrams of the bi-metal co-existed system M1-M2-x-y in which the multi-me-tallic compounds may be produced by interaction between compounds of both metals.Theformation of zinc ferrite and its stable region have been analyzed through drawingZn-Fe-S-O system predominance diagrams.The availability of the diagram is given the di-rection to roast the zinc sulfide ore as well.WANG Longzhang HUANG Kexiong LUO Rutie YAO Yu YE Dalu CHEN Xinmin Central South University of Technology,Changsha,China 1990Acta Metallurgica Sinica(English Letters)1990,3,12:0
9MIL-101(Cr)-decorated Ti/TiO_(2) anode for electrochemical oxidation of aromatic pollutants from water显示文摘Hydroxyl radicals(·OH) generated on anode play a vital role in electrochemical oxidation(EO) of organic pollutants for water treatment. Inspired by the four-electron oxygen evolution reaction(OER), we supposed an anode-selection strategy to stabilize deeply oxidized states(*O and*OOH) which are beneficial to generating·OH. To verify the hypothesis, a candidate anode component(MIL-101(Cr), a well-known metal-organic framework with active variable-valence transition metal centers) was used to coat Ti/TiO_(2)plate to fabricate anodes. Compared to TiO_(2)(101) plane on undecorated anode surface, fast and complete removal of aniline and phenol, and improved energy utilization were achieved on MIL-101(Cr)-coatedTi/TiO_(2)anode. Mechanism investigation, including pollutant degradation pathways, showed the predominate contribution(69.60%–75.13%) of·OH in pollutant mineralization. Density functional theory(DFT)computations indicated Cr site in MIL-101(Cr) was more conducive to stabilizing*O and*OOH, leading to thermodynamical spontaneous generation of·OH. This work opens up an exciting avenue to explore·OH production, and supplies a useful guidance to the development of anode materials for EO process.Zepeng Zhang Yunyun Li Longzhang Dong Zhonglong Yin Ziqi Tian Weiben Yang Zhen Yang 2023Chinese Chemical Letters2023,34,2:0
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