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| 1 | 环戊烷在Silicalite-1上吸附的热力学研究显示文摘 用智能重量分析仪测定了环戊烷在Silicalite-1上的吸附等温线,根据吸附等温线数据计算了热力学参数(吸附热Qst、熵变ΔS、Gibbs自由能变ΔG)。423K时,吸附等温线符合Langmuir方程。254,274K时,吸附等温线出现了滞后环。与分子构型相近的苯与环己烷相比,环戊烷的饱和吸附量超乎寻常,Qst、ΔG、ΔS随吸附量的变化较大,表明环戊烷在Silicalite-1上的吸附机理相当复杂。在吸附过程中,吸附质分子之间、吸附质和Silicalite-1之间的相互作用较强,环戊烷分子发生了重排。当吸附量达到1.5mmol/g时,吸附相开始凝聚,吸附热逐渐达到了凝聚热值。 | 段林海 蒋施 孙兆林 张晓彤 宋丽娟 Rees L V C | 2003 | 石油化工高等学校学报2003，16，3： | 4 |
| 2 | 正己烷在ZnNi/HZSM-5上微波芳构化显示文摘 研究了常规加热和微波辐射两种加热方法对正己烷在ZnNi/HZSM-5催化剂上的芳构化反应的影响。考察了温度、空速对反应性能的影响,并利用XRD对ZnNi/HZSM-5催化剂作了表征。结果表明,金属锌和镍高度分散于HZSM-5沸石中,微波辐射对分子筛结构的影响很小。与常规加热反应相比,要达到相同的芳烃收率,在微波加热条件下能使反应温度降低约100℃左右。在一定程度上提高反应温度可以获得较高的总芳烃收率和BTX收率,亦能明显地改变BTX中各组分的相对选择性。改变空速能显著影响总芳烃收率和BTX收率,在常规加热和微波加热条件下的最佳空速分别为1.5h-1和1.0h-1。讨论了正己烷在微波辐射下ZnNi/HZSM-5上的芳构化反应机理。正己烷首先裂解为C03+C=3,一部分烯烃齐聚、环化生成芳烃,另一部分烯烃则经氢转移或加氢生成烷烃,C03和C04在锌和镍活性中心上直接脱氢二聚环化生成芳烃。 | 许健 张晓彤 桂建舟 罗有训 孙兆林 Rees L V C | 2003 | 石油化工高等学校学报2003，16，2： | 3 |
| 3 | Preparation and Structural Characterization of, and Chemical Vapor Deposition Studies with Certain Yttrium Tris (fl-Diketonate) Compounds 显示文摘 | Luten H A Rees Jr W S Goedken V L | 1996 | Chem Vap Deposition1996，2，： | 1 |
| 4 | Frequency response method for the characterisation of microporous solids显示文摘 | Rees L V C Song L | 2000 | Membrane Scienceand Technology?2000，6，： | 1 |
| 5 | Frequency response characterization of acid sites in zeolite catalgsts using NH3 as the probe molecule显示文摘 | Lovat V C Rees Gyorgy Onyestyak | 1999 | Microporous and Mesoporous Materials1999，28，： | 1 |
| 6 | Formation of zeolite from the system Na2O-Al2O3-H2O in alkaline medium (pH>10) 显示文摘 | Lovat V C Ree s Sathy Chandrasekhar | 1993 | Zeolites1993，13，： | 1 |
| 7 | Electrochemical CO2 se- questration in ionic liquids: a perspective 显示文摘 | REES N V COMPTON R G | 2011 | Energy Environmental Science2011，4，2： | 1 |
| 8 | 1a,20R-Dihydroxyecdysone from Axyris amaranthoides显示文摘 | Sarker S D Sik V Rees H H | 1998 | Phytochemistry1998，49，8： | 1 |
| 9 | Effect of the New York State cigarette fire safety standard on ignition propensity smoke constituents and the consumer market 显示文摘 | Connolly GN Alpert HR Rees V | 2005 | Tob Control2005，14，5： | 1 |
| 10 | Sentinel node bi- opsy in squamous cell cancer of the oral cavity and oral pharynx: a diagnostic meta - analysis 显示文摘 | Paleri V Rees G Arullendran P | 2005 | Head Neck2005，27，： | 1 |
| 11 | Experimental and molecular simulation studies of adsorption and diffusion of cyclic hydrocarbons in silicalite-1显示文摘 | Song L Sun Z L Rees L V C | 2002 | Microporous and Mesoporous Material2002，55，1： | 1 |
| 12 | Origin of extended-chain lamellae in polyethylene 显示文摘 | Rees D V Bassett D C | 1968 | Nature1968，219，5152： | 1 |
| 13 | Are symbiotic Zooxanthellae nutrient deficient显示文摘 | REES T A V | 1991 | Proceedings of the Royal Society of London SeriesB Biological Sciences1991，243，： | 1 |
| 14 | Cooling load dynamics of rooms with cooled ceilings 显示文摘 | Niu J Kooi J v d Ree H v d | 1997 | Building Services Engineering Research & Technology1997，18，4： | 1 |
| 15 | Adsorption and diffusion of cyclic hydrocarbon in MFI-type zeolites studied by gravimetric andfrequency-response techniques显示文摘 | Song L Rees L V C | 2000 | Microporous and Mesoporous Materials2000，35，： | 1 |
| 16 | Design, fabrication, characterization and application of nanoelectrode arrays显示文摘 | COMPTON G R WILDGOOSE G G REES V N | 2008 | Chemical Physics Letter2008，459，16： | 1 |
| 17 | Studies of adsorption,diffusion and molecular simulation of cyclic hydrocarbons inMFI zeolites 显示文摘 | Song L J Sun Z L Rees L V C | 2001 | Studies in Surface Science and Catalysis2001，135，： | 1 |
| 18 | The structure of methane gas hydrate bearing sediments from the Krishna-Godavari Basin as seen from Micro-CT scanning显示文摘 | REES E V L PRIEST J A CLAYTON C R I | 2011 | Marine and Petroleum Geology2011，28，7： | 1 |
| 19 | Potential impact of gas hydrate and its dissociation on the strength of host sediment in the Krishna-Godavari Basin显示文摘 | PRIEST J A CLAYTON C R I REES E V L | 2014 | Marine and Petroleum Geology2014，58，： | 1 |
| 20 | Potential stepchronoamperometry at hemispherical mercury electrodes : Theformation of thallium amalgams and the measurement of thediffusion coefficient of thallium in mercury 显示文摘 | Limon-Petersen J G Rees N V Streeter I | 2008 | Journal of E-lectroanalytical Chemistry2008，623，2： | 1 |
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