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2篇 您的检索式:作者名="Shaoning Lv"
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1Unlocking efficient energy storage via regulating ion and electron-active subunits:an(SbS)_(1.15)TiS_(2)superlattice for large and fast Na^(+)storage显示文摘Alloying-type metal sulfides with high sodiation activity and theoretical capacity are promising anode materials for high energy density sodium ion batteries.However,the large volume change and the migratory and aggregation behavior of metal atoms will cause severe capacity decay during the charge/discharge process.Herein,a robust and conductive TiS_(2)framework is integrated with a high-capacity SbS layer to construct a single phase(SbS)_(1.15)TiS_(2)superlattice for both high-capacity and fast Na^(+)storage.The metallic TiS_(2)sublayer with high electron activity acts as a robust and conductive skeleton to buffer the volume expansion caused by conversion and alloying reaction between Na+and SbS sublayer.Hence,high capacity and high rate capability can be synergistically realized in a single phase(SbS)_(1.15)TiS_(2)superlattice.The novel(SbS)_(1.15)TiS_(2)anode has a high charge capacity of 618 mAh g^(-1)at 0.2 C and superior rate performance and cycling stability(205 mAh g^(-1)at 35 C after 2,000 cycles).Furthermore,in situ and ex situ characterizations are applied to get an insight into the multi-step reaction mechanism.The integrity of robust Na-Ti-S skeleton during(dis)charge process can be confirmed.This superlattice construction idea to integrate the Na^(+)-active unit and electron-active unit would provide a new avenue for exploring high-performance anode materials for advanced sodium-ion batteries.Baixin Peng Tianxun Cai Shaoning Zhang Yuqiang Fang Zhuoran Lv Yusha Gao Fuqiang Huang 2024Science China Chemistry2024,67,1:0
2The Simulation of L-Band Microwave Emission of Frozen Soil during the Thawing Period with the Community Microwave Emission Model(CMEM)显示文摘One-third of the Earth’s land surface experiences seasonal freezing and thawing.Freezing-thawing transitions strongly impact land-atmosphere interactions and,thus,also the lower atmosphere above such areas.Observations of two L-band satellites,the Soil Moisture Active Passive(SMAP)and Soil Moisture and Ocean Salinity(SMOS)missions,provide flags that characterize surfaces as either frozen or not frozen.However,both state transitions—freezing and thawing(FT)—are continuous and complex processes in space and time.Especially in the L-band,which has penetration depths of up to tens of centimeters,the brightness temperature(T_(B))may be generated by a vertically-mixed profile of different FT states,which cannot be described by the current version of the Community Microwave Emission Model(CMEM).To model such complex state transitions,we extended CMEM in Fresnel mode with an FT component by allowing for(1)a varying fraction of an open water surface on top of the soil,and(2)by implementing a temporal FT phase transition delay based on the difference between the soil surface temperature and the soil temperature at 2.5 cm depth.The extended CMEM(CMEM-FT)can capture the T_(B)progression from a completely frozen to a thawed state of the contributing layer as observed by the L-band microwave radiometer ELBARA-III installed at the Maqu station at the northeastern margin of the Tibetan Plateau.The extended model improves the correlation between the observations and CMEM simulations from 0.53/0.45 to 0.85/0.85 and its root-mean-square-error from 32/25 K to 20/15 K for H/V-polarization during thawing conditions.Yet,CMEM-FT does still not simulate the freezing transition sufficiently.Shaoning Lv Clemens Simmer Yijian Zeng Jun Wen and Zhongbo Su 2022Journal of Remote Sensing2022,,1:0
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